A novel fluorene-based conjugated copolymer containing cyclobutenedione unit was synthesized by Suzuki reaction. Its structure and properties were characterized by FTIR, 1HNMR, elemental analysis, PL spectroscopy, DSC...A novel fluorene-based conjugated copolymer containing cyclobutenedione unit was synthesized by Suzuki reaction. Its structure and properties were characterized by FTIR, 1HNMR, elemental analysis, PL spectroscopy, DSC, TGA and cyclic voltammetry. The resulting polymer shows strong yellow PL emission (561 nm) and good solubility in polar aprotic solvents, i.e. THF, DMF, DMAC, DMSO, etc. DSC and TGA studies reveal that the novel polymer possesses excellent thermal stability with high glass transition temperature of 127℃ and onset decomposition temperature of 411℃. Cyclic voltammetry measurement demonstrated that the polymer has both hole and electron-transporting property.展开更多
文摘A novel fluorene-based conjugated copolymer containing cyclobutenedione unit was synthesized by Suzuki reaction. Its structure and properties were characterized by FTIR, 1HNMR, elemental analysis, PL spectroscopy, DSC, TGA and cyclic voltammetry. The resulting polymer shows strong yellow PL emission (561 nm) and good solubility in polar aprotic solvents, i.e. THF, DMF, DMAC, DMSO, etc. DSC and TGA studies reveal that the novel polymer possesses excellent thermal stability with high glass transition temperature of 127℃ and onset decomposition temperature of 411℃. Cyclic voltammetry measurement demonstrated that the polymer has both hole and electron-transporting property.
