The exploration of transition metal Mn^(2+)-activated luminescent materials is gaining increasing interests due to their diverse uses.Herein,Mn^(2+)-incorporated fluorphlogopite(FP;KMg_(3)AlSi_(3)O_(10)F_(2))mica cera...The exploration of transition metal Mn^(2+)-activated luminescent materials is gaining increasing interests due to their diverse uses.Herein,Mn^(2+)-incorporated fluorphlogopite(FP;KMg_(3)AlSi_(3)O_(10)F_(2))mica ceramics were successfully prepared by a hightemperature solid-state reaction process,in which Mn^(2+)occupied the Mg^(2+)site through isomorphic substitution.The FP itself and derived Mn-mica(KMg_(2.5)Mn_(0.5)AlSi_(3)O_(10)F_(2))possess negligible luminescence under ultraviolet(UV)excitation.However,the doping of rare earth Eu^(2+)into Mn-mica generates an evident deep-far-red broadband emission at approximately 620-860 nm,peaking at 720 nm when excited with 240-360 nm,which is ascribed to the intrinsic^(4)T_(1)→^(6)A_(1)transition of Mn^(2+),and the maximum spectral enhancement reaches approximately 22-fold when excited with 320 nm.The more dramatic result is that the complete substitution of Na^(+)for K^(+)in Mnmica(NaMg_(2.5)Mn_(0.5)AlSi_(3)O_(10)F_(2))not only results in an enlarged excitation range toward the near-UV region but also greatly enhances the deep-far-red emission(more than 12-fold)under 365 nm excitation.After optimization,the luminescence internal quantum yield(QY)is 87.4%,and the emission intensity at 423 K retains 78%of that at ambient temperature,indicating that the modified mica ceramics have superior luminescence and thermal stability through the cooperative effects of isomorphic cation substitution and doping,which is applicable for plant cultivation lighting and latent fingerprint identification.展开更多
基金financially supported by the Southwest United Graduate School Research Program(No.202302AO370008)the Natural Science Foundation of China(No.51972097)+1 种基金the scope of the projects CICECOAveiro Institute of Materials(Nos.UIDB/50011/2020,UIDP/50011/2020,and LA/P/0006/2020)financed by national funds through the FCT/MCTES(PIDDAC)。
文摘The exploration of transition metal Mn^(2+)-activated luminescent materials is gaining increasing interests due to their diverse uses.Herein,Mn^(2+)-incorporated fluorphlogopite(FP;KMg_(3)AlSi_(3)O_(10)F_(2))mica ceramics were successfully prepared by a hightemperature solid-state reaction process,in which Mn^(2+)occupied the Mg^(2+)site through isomorphic substitution.The FP itself and derived Mn-mica(KMg_(2.5)Mn_(0.5)AlSi_(3)O_(10)F_(2))possess negligible luminescence under ultraviolet(UV)excitation.However,the doping of rare earth Eu^(2+)into Mn-mica generates an evident deep-far-red broadband emission at approximately 620-860 nm,peaking at 720 nm when excited with 240-360 nm,which is ascribed to the intrinsic^(4)T_(1)→^(6)A_(1)transition of Mn^(2+),and the maximum spectral enhancement reaches approximately 22-fold when excited with 320 nm.The more dramatic result is that the complete substitution of Na^(+)for K^(+)in Mnmica(NaMg_(2.5)Mn_(0.5)AlSi_(3)O_(10)F_(2))not only results in an enlarged excitation range toward the near-UV region but also greatly enhances the deep-far-red emission(more than 12-fold)under 365 nm excitation.After optimization,the luminescence internal quantum yield(QY)is 87.4%,and the emission intensity at 423 K retains 78%of that at ambient temperature,indicating that the modified mica ceramics have superior luminescence and thermal stability through the cooperative effects of isomorphic cation substitution and doping,which is applicable for plant cultivation lighting and latent fingerprint identification.
