Dynamic multi-decryption with luminescent anti-counterfeit materials still presents a challenge in information storage and security.In this work,Gd^(3+)is introduced into the structure of lanthanide-based metal–organ...Dynamic multi-decryption with luminescent anti-counterfeit materials still presents a challenge in information storage and security.In this work,Gd^(3+)is introduced into the structure of lanthanide-based metal–organic frameworks(LnMOFs)([LnNa(HL^(2))_(2)(H_(3)L^(2))0.5]·EtOH,H_(3)L^(2)=5-hydroxy-isophthalic acid,abbreviated as LnHIP)to adjust the Ln–Ln distances.The emission intensity of Tb^(3+)and Eu^(3+)reached a maximum with the dilution rate of Gd^(3+)fixed at 50%.The temperature-dependent luminescent properties reveal thermal stability even at an ultra-low temperature.The developed samples present water sensitive properties,thus the luminescence could be quenched by water atomization.Furthermore,by combining inkjet printing and the water quenching effect,the encrypted information could be decrypted by ultraviolet irradiation and water atomization successively.These results demonstrate the promising applications of LnMOFs in dynamic information decryption with Gd^(3+)doping to save cost and enhance luminescence intensity.展开更多
基金supported by the National Natural Science Foundation of China(52003144)the Youth Science Foundation of Shanxi Province(202203021212406)+1 种基金the Research Project Supported by Shanxi Scholarship Council of China(2022-121)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province(2021L264).
文摘Dynamic multi-decryption with luminescent anti-counterfeit materials still presents a challenge in information storage and security.In this work,Gd^(3+)is introduced into the structure of lanthanide-based metal–organic frameworks(LnMOFs)([LnNa(HL^(2))_(2)(H_(3)L^(2))0.5]·EtOH,H_(3)L^(2)=5-hydroxy-isophthalic acid,abbreviated as LnHIP)to adjust the Ln–Ln distances.The emission intensity of Tb^(3+)and Eu^(3+)reached a maximum with the dilution rate of Gd^(3+)fixed at 50%.The temperature-dependent luminescent properties reveal thermal stability even at an ultra-low temperature.The developed samples present water sensitive properties,thus the luminescence could be quenched by water atomization.Furthermore,by combining inkjet printing and the water quenching effect,the encrypted information could be decrypted by ultraviolet irradiation and water atomization successively.These results demonstrate the promising applications of LnMOFs in dynamic information decryption with Gd^(3+)doping to save cost and enhance luminescence intensity.
