Cobalt-based phosphate/phosphonates are a class of promising water oxidation catalysts at neutralpH.Herein,we reported a facile hydrothermal synthesis of various nanostructured cobalt phe-nylphosphonates.It is found t...Cobalt-based phosphate/phosphonates are a class of promising water oxidation catalysts at neutralpH.Herein,we reported a facile hydrothermal synthesis of various nanostructured cobalt phe-nylphosphonates.It is found that the number of hydroxyl group of structure-directing reagent iscrucial for the construction of 3D hierarchical structures including hierarchical nanosheet flow-er-like assemblies and nanothorn microsphere.These samples were characterized by scanningelectron microscopy,transmission electron microscopy,X-ray diffraction,infrared,and X-ray pho-toelectron spectroscopy techniques.They can act as highly efficient electrocatalysts for the oxygenevolution reaction at neutral pH.Among these,hierarchical cobalt phenylphosphonate nanothornflowers present excellent performance,affording a current density of 1 mA cm^-2 required a smalloverpotential of 393 mV.This work offers a new clue to develop high-performance metal phospho-nate/phosphate catalysts toward electrochemical water oxidation.展开更多
We study the Goos-Hanchen-like shift of single silicene barrier under the external perpendicular electric field,off- resonant circularly polarized light and the exchange field modulation using the stationary-phase met...We study the Goos-Hanchen-like shift of single silicene barrier under the external perpendicular electric field,off- resonant circularly polarized light and the exchange field modulation using the stationary-phase method.The results show that the Goos-Hanchen-like shift of silicene resulting from the external perpendicular electric field does not have the characteristics of spin or valley polarization,while that from off-resonant circularly polarized light or the exchange field is spin-polarized.More importantly,the combined effect of the external perpendicular electric field and the exchange field or off-resonant circularly polarized light can cause the Goos-Hanchen-like shift of the system to be spin and valley polarized.It is particularly worth noting that when the three modulations are considered at the same time,as the exchange field changes,the system will have a positive or negative Goos-Hanchen-like shift.展开更多
We investigate the band structure and Goos–Hänchen-like shift in ferromagnetic mass graphene junction modulated by the circularly polarized light.It is found that both spin and valley-related energy gaps can be ...We investigate the band structure and Goos–Hänchen-like shift in ferromagnetic mass graphene junction modulated by the circularly polarized light.It is found that both spin and valley-related energy gaps can be opened by employing the circularly polarized light and the exchange field in mass graphene.The valley-polarized Goos–Hänchen-like shift can be identified in the presence of circularly polarized light,and the spin-polarized Goos–Hänchen-like shift can be realized with introduction of exchange field in mass graphene.Furthermore,the spin and valley polarization-related Goos–Hänchen-like shift can be achieved by combination of circularly polarized light and exchange field in mass graphene.It is hopeful that our work will be more conducive for future applications in graphene polarization transport devices.展开更多
High-dose melphalan(HDM)is the standard conditioning regimen before autologous stem cell transplantation(ASCT)in plasma cell malignancies.Despite prophylactic antiemetics,chemotherapy-induced nausea and vomiting(CINV)...High-dose melphalan(HDM)is the standard conditioning regimen before autologous stem cell transplantation(ASCT)in plasma cell malignancies.Despite prophylactic antiemetics,chemotherapy-induced nausea and vomiting(CINV)remains a prevalent challenge.We retrospectively compared the efficacy of netupitant and palonosetron(NEPA)plus dexamethasone with that of serotonin receptor antagonist(5-HT3RA)-based regimens(the control group)for patients receiving HDM.The primary endpoint was complete resolution(CR)of CINV in the acute(0-24 hours)and delayed(24-168 hours)phases.Secondary endpoints included overall response rate(ORR),subgroup benefit,and nutritional outcomes.In total,108 patients were included(NEPA,n=38;control,n=70).The NEPA group exhibited higher CR rates in both acute(65.8%vs 32.9%;p<0.010)and delayed phases(50.0%vs 12.9%;p<0.010).NEPA achieved a higher ORR(73.7%vs 24.3%;p<0.010).Subgroup analysis indicated consistent benefits across most clinical strata.Multivariable analysis identified NEPA and male gender as independent factors predicting CR.The median duration of parenteral nutrition(PN)was shorter in the NEPA group than in the control group(median,2 days[range 1-2]vs 3 days[range,3-5.75];p=0.046).Compared to standard 5-HT3RA regimens,NEPA significantly improved antiemetic efficacy in patients undergoing HDM conditioning.展开更多
文摘Cobalt-based phosphate/phosphonates are a class of promising water oxidation catalysts at neutralpH.Herein,we reported a facile hydrothermal synthesis of various nanostructured cobalt phe-nylphosphonates.It is found that the number of hydroxyl group of structure-directing reagent iscrucial for the construction of 3D hierarchical structures including hierarchical nanosheet flow-er-like assemblies and nanothorn microsphere.These samples were characterized by scanningelectron microscopy,transmission electron microscopy,X-ray diffraction,infrared,and X-ray pho-toelectron spectroscopy techniques.They can act as highly efficient electrocatalysts for the oxygenevolution reaction at neutral pH.Among these,hierarchical cobalt phenylphosphonate nanothornflowers present excellent performance,affording a current density of 1 mA cm^-2 required a smalloverpotential of 393 mV.This work offers a new clue to develop high-performance metal phospho-nate/phosphate catalysts toward electrochemical water oxidation.
基金supported by the National Natural Science Foundation of China(Grant Nos.11864012 and 11764013)the Natural Science Foundation of Jiangxi Province,China(Grant No.20202BABL201018)Jiangxi University of Traditional Chinese Medicine 1050 Youth Talent Project(Grant No.5142001010)。
文摘We study the Goos-Hanchen-like shift of single silicene barrier under the external perpendicular electric field,off- resonant circularly polarized light and the exchange field modulation using the stationary-phase method.The results show that the Goos-Hanchen-like shift of silicene resulting from the external perpendicular electric field does not have the characteristics of spin or valley polarization,while that from off-resonant circularly polarized light or the exchange field is spin-polarized.More importantly,the combined effect of the external perpendicular electric field and the exchange field or off-resonant circularly polarized light can cause the Goos-Hanchen-like shift of the system to be spin and valley polarized.It is particularly worth noting that when the three modulations are considered at the same time,as the exchange field changes,the system will have a positive or negative Goos-Hanchen-like shift.
基金the Natural Science Foundation of Jiangxi Province,China(Grant Nos.20224BAB201025 and 20202BABL201018)the National Natural Science Foundation of China(Grant Nos.11864012,11764013,and 12164021).
文摘We investigate the band structure and Goos–Hänchen-like shift in ferromagnetic mass graphene junction modulated by the circularly polarized light.It is found that both spin and valley-related energy gaps can be opened by employing the circularly polarized light and the exchange field in mass graphene.The valley-polarized Goos–Hänchen-like shift can be identified in the presence of circularly polarized light,and the spin-polarized Goos–Hänchen-like shift can be realized with introduction of exchange field in mass graphene.Furthermore,the spin and valley polarization-related Goos–Hänchen-like shift can be achieved by combination of circularly polarized light and exchange field in mass graphene.It is hopeful that our work will be more conducive for future applications in graphene polarization transport devices.
基金supported by the Beijing Natural Science Foundation(Z230016)the National Key Research and Development Program of China(No.2022YFA1103300 and 2022YFC2502606)+4 种基金the Major Program of the National Natural Science Foundation of China(No.82293630)the Peking University Medicine Fund for World’s Leading Discipline or Discipline Cluster Development(No.71003Y3035)Plan Project of Tongzhou Municipal Science and Technology(No.KJ2024CX045)the National Natural Science Foundation of China(No.82170208)the Fundamental Research Funds for the Central Universities.
文摘High-dose melphalan(HDM)is the standard conditioning regimen before autologous stem cell transplantation(ASCT)in plasma cell malignancies.Despite prophylactic antiemetics,chemotherapy-induced nausea and vomiting(CINV)remains a prevalent challenge.We retrospectively compared the efficacy of netupitant and palonosetron(NEPA)plus dexamethasone with that of serotonin receptor antagonist(5-HT3RA)-based regimens(the control group)for patients receiving HDM.The primary endpoint was complete resolution(CR)of CINV in the acute(0-24 hours)and delayed(24-168 hours)phases.Secondary endpoints included overall response rate(ORR),subgroup benefit,and nutritional outcomes.In total,108 patients were included(NEPA,n=38;control,n=70).The NEPA group exhibited higher CR rates in both acute(65.8%vs 32.9%;p<0.010)and delayed phases(50.0%vs 12.9%;p<0.010).NEPA achieved a higher ORR(73.7%vs 24.3%;p<0.010).Subgroup analysis indicated consistent benefits across most clinical strata.Multivariable analysis identified NEPA and male gender as independent factors predicting CR.The median duration of parenteral nutrition(PN)was shorter in the NEPA group than in the control group(median,2 days[range 1-2]vs 3 days[range,3-5.75];p=0.046).Compared to standard 5-HT3RA regimens,NEPA significantly improved antiemetic efficacy in patients undergoing HDM conditioning.
