The reaction of[CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex,cis-[(CpMo(CO)2{S2C-N(CH2)5}]as red crystals in moderate yield.The compound was formed ...The reaction of[CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex,cis-[(CpMo(CO)2{S2C-N(CH2)5}]as red crystals in moderate yield.The compound was formed by the oxidative cleavage of metal-metal bond in[CpMo(CO)3]2 together with a reductive sulfur-sulfur bond scission in the ligand.展开更多
文摘The reaction of[CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex,cis-[(CpMo(CO)2{S2C-N(CH2)5}]as red crystals in moderate yield.The compound was formed by the oxidative cleavage of metal-metal bond in[CpMo(CO)3]2 together with a reductive sulfur-sulfur bond scission in the ligand.
