A conductive and fluorescent metallohydrogel(1%w/v,CPH)involving coordination polymers has been synthesized from non-fluorescent components viz.,an L-tyrosine derived pro-ligand(1),LiOH and Zn(NO_(3))_(2)used in 1:3:1...A conductive and fluorescent metallohydrogel(1%w/v,CPH)involving coordination polymers has been synthesized from non-fluorescent components viz.,an L-tyrosine derived pro-ligand(1),LiOH and Zn(NO_(3))_(2)used in 1:3:1 proportion at pH 11–12.CPH shows reversible gel–sol transitions in response to external stimuli including thermal,mechanical and ultrasound stress.展开更多
基金the Department of Science and Technology,New Delhi,India,for research grant under DST-INSPIRE Faculty award(IFA-14/CH-156).MKD acknowledges IIT(BHU)and MHRD for fellowship.We acknowledge SIC IIT Indore,CIF IIT(BHU)Varanasi and AMU Aligarh for extending the instrumental facilities.
文摘A conductive and fluorescent metallohydrogel(1%w/v,CPH)involving coordination polymers has been synthesized from non-fluorescent components viz.,an L-tyrosine derived pro-ligand(1),LiOH and Zn(NO_(3))_(2)used in 1:3:1 proportion at pH 11–12.CPH shows reversible gel–sol transitions in response to external stimuli including thermal,mechanical and ultrasound stress.
