In this manuscript,the neat epoxy(EP)and functionalized Fe_(3)O_(4)(G-Fe_(3)O_(4))reinforced epoxy(G-Fe_(3)O_(4)/EP)coatings were cured under different temperatures,and the effect of the low curing temperature on the ...In this manuscript,the neat epoxy(EP)and functionalized Fe_(3)O_(4)(G-Fe_(3)O_(4))reinforced epoxy(G-Fe_(3)O_(4)/EP)coatings were cured under different temperatures,and the effect of the low curing temperature on the anticorrosion performance was investigated.The experimental results show that the epoxy-amine ring-open addition reaction mainly exists in the curing process,and the activation energies of the reaction for the two coatings are 55.84 and 53.29 kJ/mol,respectively.For the coatings cured at the low temperature,almost no pores could be detected on the fracture surface,but the presentence of the rough regions reflects the poor curing state.As compared with the samples cured at the high temperature,the anticorrosion performance of the coatings with the low curing temperature is worse,and the decrease rate of the anticorrosion performance is slower,because of the poor curing state and low adhesion obtained at the low temperature.展开更多
Revegetation is a traditional practice widely used for soil protection. We evaluated the effect of natural revegetation succession on soil chemical properties and carbon fractions （particulate organic carbon （POC）,...Revegetation is a traditional practice widely used for soil protection. We evaluated the effect of natural revegetation succession on soil chemical properties and carbon fractions （particulate organic carbon （POC）, humus carbon （HS-C）, humic acid carbon （HA-C） and fulvic acid carbon （FA-C）） on the Loess Plateau of China. The vegetation types, in order from the shortest to the longest enclosure duration, were： （a） abandoned overgrazed grassland （AbG3; 3 years）; （b） Hierochloe odorata Beauv. （HiO7; 7 years）; （c） Thymus mongoficus Ronnm （ThM15; 15 years）; （d） Artemisia sacrorum Ledeb （AtS25; 25 years）; （e） Stipa bungeana Trin Ledeb （StB36; 36 years） and （f） Stipa grandis P. Smirn （StG56; 56 years）. The results showed that the concentrations of soil organic carbon, total nitrogen and available phosphorus increased with the increase of restoration time except for ThM15. The concen- tration of NH4-N increased in the medium stage （for ThM15 and AtS25） and decreased in the later stage （for StB36 and StG56） of vegetation restoration. However, NO3-N concentration significantly increased in the later stage （for StB36 and StG56）. Carbon fractions had a similar increasing trend during natural vegetation restoration. The con- centrations of POC, HS-C, FA-C and HA-C accounted for 24.5%-49.1%, 10.6%-15.2%, 5.8%-9.1% and 4.6%-6.1% of total carbon, respectively. For AbG3, the relative changes of POC, HS-C and FA-C were significantly higher than that of total carbon during the process of revegetation restoration. The higher relative increases in POC, HS-C and FA-C confirmed that soil carbon induced by vegetation restoration was sequestrated by higher physical and chemical protection. The increases of soil C fractions could also result in higher ecological function in semiarid grassland ecosystems.展开更多
基金Project(U2106216)supported by the National Natural Science Foundation of China。
文摘In this manuscript,the neat epoxy(EP)and functionalized Fe_(3)O_(4)(G-Fe_(3)O_(4))reinforced epoxy(G-Fe_(3)O_(4)/EP)coatings were cured under different temperatures,and the effect of the low curing temperature on the anticorrosion performance was investigated.The experimental results show that the epoxy-amine ring-open addition reaction mainly exists in the curing process,and the activation energies of the reaction for the two coatings are 55.84 and 53.29 kJ/mol,respectively.For the coatings cured at the low temperature,almost no pores could be detected on the fracture surface,but the presentence of the rough regions reflects the poor curing state.As compared with the samples cured at the high temperature,the anticorrosion performance of the coatings with the low curing temperature is worse,and the decrease rate of the anticorrosion performance is slower,because of the poor curing state and low adhesion obtained at the low temperature.
基金supported by the National Natural Science Foundation of China (41171226)the Program for New Century Excellent Talents in University (NCET-12-0479)the Foundation for Youths Teacher by Northwest A&F University
文摘Revegetation is a traditional practice widely used for soil protection. We evaluated the effect of natural revegetation succession on soil chemical properties and carbon fractions （particulate organic carbon （POC）, humus carbon （HS-C）, humic acid carbon （HA-C） and fulvic acid carbon （FA-C）） on the Loess Plateau of China. The vegetation types, in order from the shortest to the longest enclosure duration, were： （a） abandoned overgrazed grassland （AbG3; 3 years）; （b） Hierochloe odorata Beauv. （HiO7; 7 years）; （c） Thymus mongoficus Ronnm （ThM15; 15 years）; （d） Artemisia sacrorum Ledeb （AtS25; 25 years）; （e） Stipa bungeana Trin Ledeb （StB36; 36 years） and （f） Stipa grandis P. Smirn （StG56; 56 years）. The results showed that the concentrations of soil organic carbon, total nitrogen and available phosphorus increased with the increase of restoration time except for ThM15. The concen- tration of NH4-N increased in the medium stage （for ThM15 and AtS25） and decreased in the later stage （for StB36 and StG56） of vegetation restoration. However, NO3-N concentration significantly increased in the later stage （for StB36 and StG56）. Carbon fractions had a similar increasing trend during natural vegetation restoration. The con- centrations of POC, HS-C, FA-C and HA-C accounted for 24.5%-49.1%, 10.6%-15.2%, 5.8%-9.1% and 4.6%-6.1% of total carbon, respectively. For AbG3, the relative changes of POC, HS-C and FA-C were significantly higher than that of total carbon during the process of revegetation restoration. The higher relative increases in POC, HS-C and FA-C confirmed that soil carbon induced by vegetation restoration was sequestrated by higher physical and chemical protection. The increases of soil C fractions could also result in higher ecological function in semiarid grassland ecosystems.
