Fe-based metallic glasses (Fe–MGs) are potential candidate catalysts for advanced oxidation processes(AOPs) for recalcitrant organic pollutant degradation. However, industrial wastewater and natural contaminated site...Fe-based metallic glasses (Fe–MGs) are potential candidate catalysts for advanced oxidation processes(AOPs) for recalcitrant organic pollutant degradation. However, industrial wastewater and natural contaminated sites usually contain abundant inorganic ions, like the chloride ion (Cl−), which significantly affectAOPs, but their influence on MG-activated AOPs still remains unclear. Through the study of three commonly used oxidants, hydrogen peroxide (H_(2)O_(2)), peroxydisulfate (PDS), and peroxymonosulfate (PMS), theeffect of Cl− on the FeSiB-catalyzed process of degradation of the typical azo dye Orange Ⅱ was investigated. Evidence indicates that the addition of Cl− resulted in the monotonous inhibition of the degradation process when the H_(2)O_(2)/FeSiB and PDS/FeSiB systems were employed, but promoted effect wasdetected with the PMS/FeSiB system, which is different from the previously observed dual effect of Cl−.It is closely relative with FeSiB induced unique variety of degradation pathways, including radicals, nonradicals (^(1)O_(2)), and direct reduction degradation. Moreover, the presence of Cl− significantly affected thesystems’ absorbable organic halogen content and the amount of Fe leached into the solution. The resultsof this work will provide essential references for Fe-based MG used as AOP catalysts in field applicationsand the development of advanced MGs with excellent adaptability to complex environments.展开更多
BACKGROUND The prevalence of female infertility between the ages of 25 and 44 is 3.5%to 16.7%in developed countries and 6.9%to 9.3%in developing countries.This means that infertility affects one in six couples and is ...BACKGROUND The prevalence of female infertility between the ages of 25 and 44 is 3.5%to 16.7%in developed countries and 6.9%to 9.3%in developing countries.This means that infertility affects one in six couples and is recognized by the World Health Organization as the fifth most serious global disability.The International Committee for Monitoring Assisted Reproductive Technology reported that the global total of babies born as a result of assisted reproductive technology procedures and other advanced fertility treatments is more than 8 million.Advancements in controlled ovarian hyperstimulation procedures led to crucial accomplishments in human fertility treatments.The European Society for Human Reproduction and Embryology guideline on ovarian stimulation gave us valuable evidence-based recommendations to optimize ovarian stimulation in assisted reproductive technology.Conventional ovarian stimulation protocols for in vitro fertilization(IVF)–embryo transfer are based upon the administration of gonadotropins combined with gonadotropin-releasing hormone(GnRH)analogues,either GnRH agonists(GnRHa)or antagonists.The development of ovarian cysts requires the combination of GnRHa and gonadotropins for controlled ovarian hyperstimulation.However,in rare cases patients may develop an ovarian hyper response after administration of GnRHa alone.CASE SUMMARY Here,two case studies were conducted.In the first case,a 33-year-old female diagnosed with polycystic ovary syndrome presented for her first IVF cycle at our reproductive center.Fourteen days after triptorelin acetate was administrated(day 18 of her menstrual cycle),bilateral ovaries presented polycystic manifestations.The patient was given 5000 IU of human chorionic gonadotropin.Twenty-two oocytes were obtained,and eight embryos formed.Two blastospheres were transferred in the frozen-thawed embryo transfer cycle,and the patient was impregnated.In the second case,a 37-year-old woman presented to the reproductive center for her first donor IVF cycle.Fourteen days after GnRHa administration,the transvaginal ultrasound revealed six follicles measuring 17-26 mm in the bilateral ovaries.The patient was given 10000 IU of human chorionic gonadotropin.Three oocytes were obtained,and three embryos formed.Two high-grade embryos were transferred in the frozen-thawed embryo transfer cycle,and the patient was impregnated.CONCLUSION These two special cases provide valuable knowledge through our experience.We hypothesize that oocyte retrieval can be an alternative to cycle cancellation in these conditions.Considering the high progesterone level in most cases of this situation,we advocate freezing embryos after oocyte retrieval rather than fresh embryo transfer.展开更多
Metallic glasses(MGs)are rising novae in the catalytic field,due to their unique amorphous structure,large residual stress,and high density of low coordination sites.However,there is still an absence of suitable MGs&#...Metallic glasses(MGs)are rising novae in the catalytic field,due to their unique amorphous structure,large residual stress,and high density of low coordination sites.However,there is still an absence of suitable MGs'catalysts for advanced oxidation processes(AOPs)with peroxymonosulfate(PMS),the most efficient and promising wastewater remediation technology.Herein,the cobalt-based MG(Co-MG)with a nominal composition of Co_(67)Fe_(4)-Mo_(1.5)Si_(16.5)B_(11)(at%)was utilized as an activator of PMS for azo dye degradation.The results demonstrated that the CoMG/PMS system had an order of magnitude higher efficiency on OrangeⅡ(OII)degradation than the Fe-MG/PMS system.For fundamental study and field application,the effect of adding inorganic anions(Cl^(-),HCO_(3)^(-),H_(2)PO_(4)^(-),SO_(4)^(2-),NO_(3)^(-)),environmental factors,and cycle experiments on the catalytic properties of Co-MG were investigated emphatically to evaluate overall degradation performance.It has demonstrated that the Co-MG with more stability,better corrosion resistance and durability contrasted to Fe-MGs.In addition,the excellent catalytic performance of Co-MG was analyzed based on the quenched experiment,electron paramagnetic resonance(EPR),and X-ray photoelectron spectroscopy(XPS)analysis.The present results provide not only a new candidate but also shed light on exploring a new kind of AOPs system based on Co-MGs for wastewater treatment.展开更多
基金This work was financially supported by the National Natural Science Foundation of China(Nos.52101195,51871120)the Natural Science Foundation of Jiangsu Province(Nos.BK20190480,BK20200019)+1 种基金the Fundamental Research Funds for the Central Universities(Nos.30920021156,30920010004)the GuangdongHong Kong-Macao Joint Laboratory for Neutron Scattering Science and Technology。
文摘Fe-based metallic glasses (Fe–MGs) are potential candidate catalysts for advanced oxidation processes(AOPs) for recalcitrant organic pollutant degradation. However, industrial wastewater and natural contaminated sites usually contain abundant inorganic ions, like the chloride ion (Cl−), which significantly affectAOPs, but their influence on MG-activated AOPs still remains unclear. Through the study of three commonly used oxidants, hydrogen peroxide (H_(2)O_(2)), peroxydisulfate (PDS), and peroxymonosulfate (PMS), theeffect of Cl− on the FeSiB-catalyzed process of degradation of the typical azo dye Orange Ⅱ was investigated. Evidence indicates that the addition of Cl− resulted in the monotonous inhibition of the degradation process when the H_(2)O_(2)/FeSiB and PDS/FeSiB systems were employed, but promoted effect wasdetected with the PMS/FeSiB system, which is different from the previously observed dual effect of Cl−.It is closely relative with FeSiB induced unique variety of degradation pathways, including radicals, nonradicals (^(1)O_(2)), and direct reduction degradation. Moreover, the presence of Cl− significantly affected thesystems’ absorbable organic halogen content and the amount of Fe leached into the solution. The resultsof this work will provide essential references for Fe-based MG used as AOP catalysts in field applicationsand the development of advanced MGs with excellent adaptability to complex environments.
文摘BACKGROUND The prevalence of female infertility between the ages of 25 and 44 is 3.5%to 16.7%in developed countries and 6.9%to 9.3%in developing countries.This means that infertility affects one in six couples and is recognized by the World Health Organization as the fifth most serious global disability.The International Committee for Monitoring Assisted Reproductive Technology reported that the global total of babies born as a result of assisted reproductive technology procedures and other advanced fertility treatments is more than 8 million.Advancements in controlled ovarian hyperstimulation procedures led to crucial accomplishments in human fertility treatments.The European Society for Human Reproduction and Embryology guideline on ovarian stimulation gave us valuable evidence-based recommendations to optimize ovarian stimulation in assisted reproductive technology.Conventional ovarian stimulation protocols for in vitro fertilization(IVF)–embryo transfer are based upon the administration of gonadotropins combined with gonadotropin-releasing hormone(GnRH)analogues,either GnRH agonists(GnRHa)or antagonists.The development of ovarian cysts requires the combination of GnRHa and gonadotropins for controlled ovarian hyperstimulation.However,in rare cases patients may develop an ovarian hyper response after administration of GnRHa alone.CASE SUMMARY Here,two case studies were conducted.In the first case,a 33-year-old female diagnosed with polycystic ovary syndrome presented for her first IVF cycle at our reproductive center.Fourteen days after triptorelin acetate was administrated(day 18 of her menstrual cycle),bilateral ovaries presented polycystic manifestations.The patient was given 5000 IU of human chorionic gonadotropin.Twenty-two oocytes were obtained,and eight embryos formed.Two blastospheres were transferred in the frozen-thawed embryo transfer cycle,and the patient was impregnated.In the second case,a 37-year-old woman presented to the reproductive center for her first donor IVF cycle.Fourteen days after GnRHa administration,the transvaginal ultrasound revealed six follicles measuring 17-26 mm in the bilateral ovaries.The patient was given 10000 IU of human chorionic gonadotropin.Three oocytes were obtained,and three embryos formed.Two high-grade embryos were transferred in the frozen-thawed embryo transfer cycle,and the patient was impregnated.CONCLUSION These two special cases provide valuable knowledge through our experience.We hypothesize that oocyte retrieval can be an alternative to cycle cancellation in these conditions.Considering the high progesterone level in most cases of this situation,we advocate freezing embryos after oocyte retrieval rather than fresh embryo transfer.
文摘目的:探究肝硬化相关血清学指标与肝硬化Child-Pugh分级之间的关系和临床意义。方法:收集重庆医科大学附属第二医院感染科2016年7月至2017年4月间肝硬化患者血清235例,其中Child-Pugh A组55例,B组90例,C组90例,以及同期健康体检人群35例,分别检测肝功能、肝纤维化、血小板计数等指标并分析其特征。结果:透明质酸(hyaluronic acid,HA)、层粘连蛋白(laminin,LN)、Ⅲ型胶原蛋白(typeⅢcollagen,PC-Ⅲ)、Ⅳ型胶原蛋白(typeⅣcollagen,Ⅳ-C)、天门冬氨酸氨基转移酶(aspartate aminotransferase,AST)、丙氨酰氨基转移酶(alanyl aminotransferase,ALT)及天门冬氨酸氨基转移酶与血小板计数比(aspartate aminotransferase to platelet ratio index,APRI)指数之间差异均具有统计学意义(P<0.05)。HA、PC-Ⅲ、Ⅳ-C、LN和AST指标对预测肝硬化的曲线下面积(AUC)分别为0.910、0.804、0.833、0.753、0.730。HA、PC-Ⅲ、Ⅳ-C与Child-Pugh分级呈高度正相关(r>0.7,P<0.01),APRI与分级呈显著性正相关(0.4<r<0.7,P<0.05)。结论:HA、PC-Ⅲ、Ⅳ-C、APRI可作为Child-Pugh分级的潜在临床指标,这将有助于临床更好地制定诊疗方案及预后评估。
基金financially supported by the National Key R&D Program of China(No.2021YFB3802800)the National Key R&D Program of China(No.2021YFB3802800)+2 种基金the National Natural Science Foundation of China(Nos.52101195 and 51871120)the Natural Science Foundation of Jiangsu Province(Nos.BK20190480 and BK20200019)the Fundamental Research Funds for the Central Universities(Nos.30920021156 and 30920010004)。
文摘Metallic glasses(MGs)are rising novae in the catalytic field,due to their unique amorphous structure,large residual stress,and high density of low coordination sites.However,there is still an absence of suitable MGs'catalysts for advanced oxidation processes(AOPs)with peroxymonosulfate(PMS),the most efficient and promising wastewater remediation technology.Herein,the cobalt-based MG(Co-MG)with a nominal composition of Co_(67)Fe_(4)-Mo_(1.5)Si_(16.5)B_(11)(at%)was utilized as an activator of PMS for azo dye degradation.The results demonstrated that the CoMG/PMS system had an order of magnitude higher efficiency on OrangeⅡ(OII)degradation than the Fe-MG/PMS system.For fundamental study and field application,the effect of adding inorganic anions(Cl^(-),HCO_(3)^(-),H_(2)PO_(4)^(-),SO_(4)^(2-),NO_(3)^(-)),environmental factors,and cycle experiments on the catalytic properties of Co-MG were investigated emphatically to evaluate overall degradation performance.It has demonstrated that the Co-MG with more stability,better corrosion resistance and durability contrasted to Fe-MGs.In addition,the excellent catalytic performance of Co-MG was analyzed based on the quenched experiment,electron paramagnetic resonance(EPR),and X-ray photoelectron spectroscopy(XPS)analysis.The present results provide not only a new candidate but also shed light on exploring a new kind of AOPs system based on Co-MGs for wastewater treatment.
