Development of on-chip coherent light sources with desired single-mode operation and straightforward spectral tunability has attracted intense interest due to ever-increasing demand for photonic devices and optoelectr...Development of on-chip coherent light sources with desired single-mode operation and straightforward spectral tunability has attracted intense interest due to ever-increasing demand for photonic devices and optoelectronic integration,but still faces serious challenges.Herein,we propose a facile method to synthesize cesium lead halide(CsPbX3)microstructures with well-defined morphologies,sizes,and constituent element gradient.The scheme is conducted using a chemical vapor deposition(CVD),which is subsequently associated with annealing-assisted solid-solid anion exchange.For the plate-shaped structures,the controllability on the cross-sectional dimension enables to precisely modulate the lasing modes,thus achieving single-mode operation;while tuning the stoichiometric of the halogen anion components in the plate-shaped CsPbI_(x)Br_(3−x) alloy samples,the lasing wavelengths are straightforwardly varied to span the entire visible spectrum.By comparison,the experimental scheme on synthesizing alloyed CsPbI_(x)Br_(3−x) perovskites is conducted using an in-situ approach,thereby achieving precise modulation of bandgap-controlled microlasers by controlling the reaction time.Such laser properties like controllable microcavity modes and broad stoichiometry-dependent tunability of light-emitting/lasing colors,associated with the facile synthesizing method of monocrystalline CsPbI_(x)Br_(3−x) structures,make lead halide perovskites ideal materials for the development of wavelength-controlled microlasers toward practical photonic integration.展开更多
We used the Integrated Biological Responses version 2(IBRv2)method to evaluate the biological eff ects of heavy metals in the sediments in Laizhou Bay,China on the benthic goby Acanthogobius ommaturus.In December 2018...We used the Integrated Biological Responses version 2(IBRv2)method to evaluate the biological eff ects of heavy metals in the sediments in Laizhou Bay,China on the benthic goby Acanthogobius ommaturus.In December 2018,gobies and sediments were collected from 15 stations.We measured the activities of defense enzymes and the contents of malondialdehyde(MDA)and metallothionein(MT)in the goby liver as well as the levels of heavy metals in the sediments and goby muscle tissue.Most of the heavy metal concentrations in sediment at each station were below the Class I criteria set by Chinese Standards for Marine Sediment Quality,and the Håkanson ecological risk index suggested low risk for the heavy metals.We found that A.ommaturus could eff ectively accumulate mercury,cadmium,arsenic,and zinc and that the contents of MT and MDA and the activities of glutathione peroxidase and glutathione reductase were suitable biomarkers of heavy metal pollution in this species.The IBRv2 method integrated these four biomarkers and discriminated stations according to heavy metal pollution.Higher IBRv2 values suggested more adverse eff ects in gobies,corroborating more serious heavy metal contamination.The stations with high IBRv2 values and high contents of heavy metals were mainly distributed in the west and northeast parts of the bay.These results show that the IBRv2 approach is a feasible strategy for assessing heavy metal pollution through biological response and biological status and that it can be implemented for environmental monitoring in Laizhou Bay.展开更多
The research of recovering WO3 from ammonia leaching slag in the extractive process of tungsten has been performed. The results show that the mechanically activated decomposition with Na2CO3 for ammonia leaching slag...The research of recovering WO3 from ammonia leaching slag in the extractive process of tungsten has been performed. The results show that the mechanically activated decomposition with Na2CO3 for ammonia leaching slag is feasible. After the treatment of a展开更多
The achievement of electrically pumped lasers with smaller and more compact physical dimensions is expected to be crucial for future optical information processing,optical storage,and photonic integrated circuits.Howe...The achievement of electrically pumped lasers with smaller and more compact physical dimensions is expected to be crucial for future optical information processing,optical storage,and photonic integrated circuits.However,developing laser devices upon electrical injection remains challenging due to stability issues,significant non-radiative losses,and severe Joule heating effects.Herein,we exhibit an ultralow-threshold low-dimensional perovskite microlaser coated with Au nanoparticles(AuNPs),which enables the optimization of its lasing properties upon optical pumping synchronized with current injection at ambient temperature.The threshold value is considerably reduced to 8.6μJ/cm^(2),which is approximately 44%lower than that of the pristine one.The microlaser incorporates size-optimized AuNPs that simultaneously enhance perovskite's lasing performance and electrical properties,particularly enabling a current injection of approximately 2.98 kA/cm^(2).Besides,AuNPs can accelerate hot-carrier cooling in perovskites,thereby reducing non-radiative recombination losses and mitigating Joule heating effects.The microlaser thresholds show progressive reduction with increasing electrical assist fraction.This study underscores that the ultimate goal of realizing electrically driven perovskite microlasers may eventually become a reality,paving a promising avenue toward the further development of electrically pumped microlaser diodes.展开更多
Engineering the lasing-mode oscillations effectively within a laser cavity is a relatively updated attentive study and perplexing issue in the field of laser physics and applications. Herein, we report a realization o...Engineering the lasing-mode oscillations effectively within a laser cavity is a relatively updated attentive study and perplexing issue in the field of laser physics and applications. Herein, we report a realization of electrically driven single-mode microlaser, which is composed of gallium incorporated zinc oxide microwire (ZnO:Ga MW) with platinum nanoparticles (PtNPs, d ~ 130 nm) covering, a magnesium oxide (MgO) nanofilm, a Pt nanofilm, and a p-type GaN substrate. The laser cavity modes could resonate following the whispering-gallery mode (WGM) among the six side surfaces by total internal reflection, and the single-mode lasing wavelength is centered at 390.5 nm with a linewidth of about 0.18 nm. The cavity quality factor Q is evaluated to about 2169. In the laser structure, the usage of Pt and MgO buffer layers can be utilized to engineer the band alignment of ZnO:Ga/GaN heterojunction, optimize the p-n junction quality and increase the current injection. Thus, the well-designed device structure can seamlessly unite the electron-hole recombination region, the gain medium, and optical microresonator into the PtNPs@ZnO:Ga wire perfectly. Such a single MW microlaser is essentially single-mode regardless of the gain spectral bandwidth. To study the single-mode operation, PtNPs working as superabsorber can engineering the multimode lasing actions of ZnO:Ga MWs even if their dimensions are typically much larger than that of lasing wavelength. Our findings can provide a straightforward and effective scheme to develop single-mode microlaser devices based on one-dimensional wire semiconductors.展开更多
Low-power, flexible, and integrated photodetectors have attracted increasing attention due to their potential applications of photosensing, astronomy, communications, wearable electronics, etc. Herein, the samples of ...Low-power, flexible, and integrated photodetectors have attracted increasing attention due to their potential applications of photosensing, astronomy, communications, wearable electronics, etc. Herein, the samples of ZnO microwires having p-type(Sb-doped ZnO, ZnO:Sb) and n-type(Ga-doped ZnO, ZnO:Ga) conduction properties were synthesized individually. Sequentially, a p-n homojunction vertical structure photodiode involving a single ZnO:Sb microwire crossed with a ZnO:Ga microwire, which can detect ultraviolet light signals, was constructed.展开更多
Acoustic agglomeration technology use high-intensity acoustic field to make aerosol particles collide and condense rapidly. Existing studies have shown that 70%–90% of fine particles can be eliminated within minutes ...Acoustic agglomeration technology use high-intensity acoustic field to make aerosol particles collide and condense rapidly. Existing studies have shown that 70%–90% of fine particles can be eliminated within minutes using compression drives and air-jet generators. Currently, there are limitations to the sound sources used. In this paper, an airborne ultrasonic transducer with a resonant frequency of 15 kHz is designed, followed by the corresponding numerical simulation and experiments for the evaluation of the vibration modal and sound pressure field. The sound pressure levels (SPL) of the open space and the agglomeration chamber can reach 150 dB and 156 dB, respectively. The agglomeration effect of water droplets, liquid phase smoke, solid phase smoke and mixed smoke is experimentally investigated, and the light transmittance rapidly increases from 8% to 60% within 4 s, 8 s, 5 s and 6 s, respectively. Agglomeration is also effective in the high-frequency range, and we infer that the acoustic wake effect is the predominant mechanism. The elimination effect is promoted with the increasing of SPL until the corresponding secondary acoustic effect is enhanced. Moreover, the agglomeration rate of higher concentration aerosol is significantly better than that of diluted aerosols in ultrasonic agglomeration process.展开更多
基金supported by the National Natural Science Foundation of China(No.12374257)。
文摘Development of on-chip coherent light sources with desired single-mode operation and straightforward spectral tunability has attracted intense interest due to ever-increasing demand for photonic devices and optoelectronic integration,but still faces serious challenges.Herein,we propose a facile method to synthesize cesium lead halide(CsPbX3)microstructures with well-defined morphologies,sizes,and constituent element gradient.The scheme is conducted using a chemical vapor deposition(CVD),which is subsequently associated with annealing-assisted solid-solid anion exchange.For the plate-shaped structures,the controllability on the cross-sectional dimension enables to precisely modulate the lasing modes,thus achieving single-mode operation;while tuning the stoichiometric of the halogen anion components in the plate-shaped CsPbI_(x)Br_(3−x) alloy samples,the lasing wavelengths are straightforwardly varied to span the entire visible spectrum.By comparison,the experimental scheme on synthesizing alloyed CsPbI_(x)Br_(3−x) perovskites is conducted using an in-situ approach,thereby achieving precise modulation of bandgap-controlled microlasers by controlling the reaction time.Such laser properties like controllable microcavity modes and broad stoichiometry-dependent tunability of light-emitting/lasing colors,associated with the facile synthesizing method of monocrystalline CsPbI_(x)Br_(3−x) structures,make lead halide perovskites ideal materials for the development of wavelength-controlled microlasers toward practical photonic integration.
基金Supported by the National Key Research and Development Program of China(No.2019YFD0900704)the Yantai Key Research and Development Program(No.2019XDHZ097)+2 种基金the National Natural Science Foundation of China(No.42076137)the Natural Science Foundation of Shandong Province(No.ZR2020QD003)the Shandong Key Laboratory of Coastal Environmental Processes,YICCAS(No.2019SDHADKFJJ16)。
文摘We used the Integrated Biological Responses version 2(IBRv2)method to evaluate the biological eff ects of heavy metals in the sediments in Laizhou Bay,China on the benthic goby Acanthogobius ommaturus.In December 2018,gobies and sediments were collected from 15 stations.We measured the activities of defense enzymes and the contents of malondialdehyde(MDA)and metallothionein(MT)in the goby liver as well as the levels of heavy metals in the sediments and goby muscle tissue.Most of the heavy metal concentrations in sediment at each station were below the Class I criteria set by Chinese Standards for Marine Sediment Quality,and the Håkanson ecological risk index suggested low risk for the heavy metals.We found that A.ommaturus could eff ectively accumulate mercury,cadmium,arsenic,and zinc and that the contents of MT and MDA and the activities of glutathione peroxidase and glutathione reductase were suitable biomarkers of heavy metal pollution in this species.The IBRv2 method integrated these four biomarkers and discriminated stations according to heavy metal pollution.Higher IBRv2 values suggested more adverse eff ects in gobies,corroborating more serious heavy metal contamination.The stations with high IBRv2 values and high contents of heavy metals were mainly distributed in the west and northeast parts of the bay.These results show that the IBRv2 approach is a feasible strategy for assessing heavy metal pollution through biological response and biological status and that it can be implemented for environmental monitoring in Laizhou Bay.
文摘The research of recovering WO3 from ammonia leaching slag in the extractive process of tungsten has been performed. The results show that the mechanically activated decomposition with Na2CO3 for ammonia leaching slag is feasible. After the treatment of a
基金supported by the National Natural Science Foundation of China (12374257)the Outstanding Doctoral Dis-sertation in Nanjing University of Aeronautics and Astronautics (BCXJ23-15)+1 种基金the Interdisciplinary Innovation Fund for Doctoral Students of Nanjing University of Aeronautics and Astronautics (KXKCXJJ202406)the Postgraduate Research&Practice Innovation Program of Jiangsu Province (KYCX25_0638)。
文摘The achievement of electrically pumped lasers with smaller and more compact physical dimensions is expected to be crucial for future optical information processing,optical storage,and photonic integrated circuits.However,developing laser devices upon electrical injection remains challenging due to stability issues,significant non-radiative losses,and severe Joule heating effects.Herein,we exhibit an ultralow-threshold low-dimensional perovskite microlaser coated with Au nanoparticles(AuNPs),which enables the optimization of its lasing properties upon optical pumping synchronized with current injection at ambient temperature.The threshold value is considerably reduced to 8.6μJ/cm^(2),which is approximately 44%lower than that of the pristine one.The microlaser incorporates size-optimized AuNPs that simultaneously enhance perovskite's lasing performance and electrical properties,particularly enabling a current injection of approximately 2.98 kA/cm^(2).Besides,AuNPs can accelerate hot-carrier cooling in perovskites,thereby reducing non-radiative recombination losses and mitigating Joule heating effects.The microlaser thresholds show progressive reduction with increasing electrical assist fraction.This study underscores that the ultimate goal of realizing electrically driven perovskite microlasers may eventually become a reality,paving a promising avenue toward the further development of electrically pumped microlaser diodes.
基金the National Natural Science Foundation of China(Grant Nos.11974182 and 11874220)the Fundamental Research Funds for the Central Universities(NO.NC2022008).
文摘Engineering the lasing-mode oscillations effectively within a laser cavity is a relatively updated attentive study and perplexing issue in the field of laser physics and applications. Herein, we report a realization of electrically driven single-mode microlaser, which is composed of gallium incorporated zinc oxide microwire (ZnO:Ga MW) with platinum nanoparticles (PtNPs, d ~ 130 nm) covering, a magnesium oxide (MgO) nanofilm, a Pt nanofilm, and a p-type GaN substrate. The laser cavity modes could resonate following the whispering-gallery mode (WGM) among the six side surfaces by total internal reflection, and the single-mode lasing wavelength is centered at 390.5 nm with a linewidth of about 0.18 nm. The cavity quality factor Q is evaluated to about 2169. In the laser structure, the usage of Pt and MgO buffer layers can be utilized to engineer the band alignment of ZnO:Ga/GaN heterojunction, optimize the p-n junction quality and increase the current injection. Thus, the well-designed device structure can seamlessly unite the electron-hole recombination region, the gain medium, and optical microresonator into the PtNPs@ZnO:Ga wire perfectly. Such a single MW microlaser is essentially single-mode regardless of the gain spectral bandwidth. To study the single-mode operation, PtNPs working as superabsorber can engineering the multimode lasing actions of ZnO:Ga MWs even if their dimensions are typically much larger than that of lasing wavelength. Our findings can provide a straightforward and effective scheme to develop single-mode microlaser devices based on one-dimensional wire semiconductors.
基金Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX23_0348)Funding for Outstanding Doctoral Dissertation in Nanjing University of Aeronautics and Astronautics(BCXJ22-14)+1 种基金Fundamental Research Funds for the Central Universities(NC2022008)National Natural Science Foundation of China(11974182,12374257)。
文摘Low-power, flexible, and integrated photodetectors have attracted increasing attention due to their potential applications of photosensing, astronomy, communications, wearable electronics, etc. Herein, the samples of ZnO microwires having p-type(Sb-doped ZnO, ZnO:Sb) and n-type(Ga-doped ZnO, ZnO:Ga) conduction properties were synthesized individually. Sequentially, a p-n homojunction vertical structure photodiode involving a single ZnO:Sb microwire crossed with a ZnO:Ga microwire, which can detect ultraviolet light signals, was constructed.
基金supported by the National Natural Science Foundation of China(Grant No.52276162 and 51876197)the Fundamental Research Funds for the Provincial Universities of Zhejiang.
文摘Acoustic agglomeration technology use high-intensity acoustic field to make aerosol particles collide and condense rapidly. Existing studies have shown that 70%–90% of fine particles can be eliminated within minutes using compression drives and air-jet generators. Currently, there are limitations to the sound sources used. In this paper, an airborne ultrasonic transducer with a resonant frequency of 15 kHz is designed, followed by the corresponding numerical simulation and experiments for the evaluation of the vibration modal and sound pressure field. The sound pressure levels (SPL) of the open space and the agglomeration chamber can reach 150 dB and 156 dB, respectively. The agglomeration effect of water droplets, liquid phase smoke, solid phase smoke and mixed smoke is experimentally investigated, and the light transmittance rapidly increases from 8% to 60% within 4 s, 8 s, 5 s and 6 s, respectively. Agglomeration is also effective in the high-frequency range, and we infer that the acoustic wake effect is the predominant mechanism. The elimination effect is promoted with the increasing of SPL until the corresponding secondary acoustic effect is enhanced. Moreover, the agglomeration rate of higher concentration aerosol is significantly better than that of diluted aerosols in ultrasonic agglomeration process.
