This paper reports the optical and electrical properties of electrochemically deposited polyaniline (PANI)/cerium oxide(CeO;) hybrid nano-composite film onto indium-tin-oxide(ITO) glass substrate.UV-visible spec...This paper reports the optical and electrical properties of electrochemically deposited polyaniline (PANI)/cerium oxide(CeO;) hybrid nano-composite film onto indium-tin-oxide(ITO) glass substrate.UV-visible spectroscopy andⅠ-Ⅴcharacteristic were performed to study the optical and electrical parameters of the electrochemically deposited film.The film exhibited a strong absorption below 400 nm(3.10 eV) with a well defined absorbance peak at around 285 nm(4.35 eV).The estimated band gap of the CeO;sample was 3.44 eV,higher than bulk CeO;powder(E;= 3.19 eV) due to the quantum confinement effect.Optical and electrochemical characteristics indicated that the electrical properties of PANI/CeO;hybrid nanocomposite film arc dominated by PANI doping.展开更多
文摘This paper reports the optical and electrical properties of electrochemically deposited polyaniline (PANI)/cerium oxide(CeO;) hybrid nano-composite film onto indium-tin-oxide(ITO) glass substrate.UV-visible spectroscopy andⅠ-Ⅴcharacteristic were performed to study the optical and electrical parameters of the electrochemically deposited film.The film exhibited a strong absorption below 400 nm(3.10 eV) with a well defined absorbance peak at around 285 nm(4.35 eV).The estimated band gap of the CeO;sample was 3.44 eV,higher than bulk CeO;powder(E;= 3.19 eV) due to the quantum confinement effect.Optical and electrochemical characteristics indicated that the electrical properties of PANI/CeO;hybrid nanocomposite film arc dominated by PANI doping.