Pt-（Sn,Re）/HZSM5-HMS catalysts were evaluated for n-heptane isomerization at 200–350 ℃.To characterize the catalyst,X-ray diffraction,X-ray fluorescene,Fourier transform infrared spectroscopy,ultraviolet-visible d...Pt-（Sn,Re）/HZSM5-HMS catalysts were evaluated for n-heptane isomerization at 200–350 ℃.To characterize the catalyst,X-ray diffraction,X-ray fluorescene,Fourier transform infrared spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,temperature-programmed reduction of H2,temperature-programmed desorption of NH3,infrared spectroscopy of adsorbed pyridine,H2 chemisorption,nitrogen adsorption-desorption,scanning electron microscopy and thermogravimetric analysis were performed.Kinetics of n-C7 isomerization were investigated under various hydrogen and n-C7 pressures,and the effects of reaction conditions on catalytic performance were studied.The results showed that bi-and trimetallic catalysts exhibit better performance than monometallic catalysts for this reaction.For example,a maximum i-C7 selectivity（ 〉74%） and multibranched isomer selectivity（40%） were observed for Pt-Sn/HZSM5-HMS at 200 ℃.展开更多
This report aims to reduce the benzene in a mixture of benzene and toluene as a model reaction using catalytic hydrogenation. In this research, we developed a series of catalysts with different supports such as Ni/HMS...This report aims to reduce the benzene in a mixture of benzene and toluene as a model reaction using catalytic hydrogenation. In this research, we developed a series of catalysts with different supports such as Ni/HMS, Ni/HZSM-5, Ni/HZSM5-HMS, Ni/Al2O3 and Ni/SiO2. Kinetic of this reaction was investigated under various hydrogen and benzene pressures. For more study, two kinetic models have also been selected and tested to describe the kinetics for this reaction. Both used models, the power law and Langmuir-Hinshelwood, provided a good fit toward the experimental data and allowed to determine the kinetic parameters. Among these catalysts, Ni/Al2O3 showed the maximum benzene conversion （99.19%） at 130℃ for benzene hydrogenation. The lowest toluene conversion was observed for Ni/SiO2. Furthermore, this catalyst presented high selectivity to benzene （75.26%） at 130℃. The catalytic performance （activity, selectivity and stability） and kinetics evaluations were shown that the Ni/SiO2 is an effective catalyst to hydrogenate benzene. It seems that the surface properties particularly pore size are effective parameter compared to other factors such as acidity and metal dispersion in this process.展开更多
文摘Pt-（Sn,Re）/HZSM5-HMS catalysts were evaluated for n-heptane isomerization at 200–350 ℃.To characterize the catalyst,X-ray diffraction,X-ray fluorescene,Fourier transform infrared spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,temperature-programmed reduction of H2,temperature-programmed desorption of NH3,infrared spectroscopy of adsorbed pyridine,H2 chemisorption,nitrogen adsorption-desorption,scanning electron microscopy and thermogravimetric analysis were performed.Kinetics of n-C7 isomerization were investigated under various hydrogen and n-C7 pressures,and the effects of reaction conditions on catalytic performance were studied.The results showed that bi-and trimetallic catalysts exhibit better performance than monometallic catalysts for this reaction.For example,a maximum i-C7 selectivity（ 〉74%） and multibranched isomer selectivity（40%） were observed for Pt-Sn/HZSM5-HMS at 200 ℃.
文摘This report aims to reduce the benzene in a mixture of benzene and toluene as a model reaction using catalytic hydrogenation. In this research, we developed a series of catalysts with different supports such as Ni/HMS, Ni/HZSM-5, Ni/HZSM5-HMS, Ni/Al2O3 and Ni/SiO2. Kinetic of this reaction was investigated under various hydrogen and benzene pressures. For more study, two kinetic models have also been selected and tested to describe the kinetics for this reaction. Both used models, the power law and Langmuir-Hinshelwood, provided a good fit toward the experimental data and allowed to determine the kinetic parameters. Among these catalysts, Ni/Al2O3 showed the maximum benzene conversion （99.19%） at 130℃ for benzene hydrogenation. The lowest toluene conversion was observed for Ni/SiO2. Furthermore, this catalyst presented high selectivity to benzene （75.26%） at 130℃. The catalytic performance （activity, selectivity and stability） and kinetics evaluations were shown that the Ni/SiO2 is an effective catalyst to hydrogenate benzene. It seems that the surface properties particularly pore size are effective parameter compared to other factors such as acidity and metal dispersion in this process.
