The Qinling Orogen in Central China records the history of a complex geological evolution and tectonic transition from compression to extension during the Late Mesozoic,with concomitant voluminous granitoids formation...The Qinling Orogen in Central China records the history of a complex geological evolution and tectonic transition from compression to extension during the Late Mesozoic,with concomitant voluminous granitoids formation.In this study,we present results from petrological,geochemical,zircon U-Pb-Lu-Hf isotopic studies on the Lengshui felsic dykes from Luanchuan region in the East Qinling Orogen.We also compile published geochronological,geochemical,and Hf isotopic data from Luanchuan region and present zircon Hf isotopic contour maps.The newly obtained age data yield two group of ages at w145 Ma and 140 Ma for two granite porphyries from the Lengshui felsic dykes,with the w145 Ma interpreted as response to the peak of magmatism in the region,and the w140 Ma as the timing of formation of the felsic dykes.The corresponding Hf isotopic data of the granite porphyries display negative εHf(t) values of e16.67 to e4.61,and Hf crustal model ages (TDM^C) of 2255e1490 Ma,indicating magma sourced from the melting of Paleo- to Mesoproterozoic crustal materials.The compiled age data display two major magmatic pulses at 160e130 Ma and 111e108 Ma with magmatic quiescence in between,and the zircon Hf isotopic data display εHf(t) values ranging from e41.9 to 2.1 and TDM^C values of 3387e1033 Ma,suggesting mixed crustal and mantle-derived components in the magma source,and correspond to multiple tectonic events during the Late Mesozoic.The Luanchuan granitoids are identified as I-type granites and most of these are highly fractionated granites,involving magma mixing and mingling and crystal fractionation.The tectonic setting in the region transformed from the Late Jurassic syn-collision setting to Early Cretaceous within-plate setting,with EeW extension in the Early Cretaceous.This extension is correlated with the NeS trending post-collisional extension between the North China Craton and Yangtze Craton as well as the EeW trending back-arc extension triggered by the westward Paleo-Pacific Plate subduction,eventually leading to lithospheric thinning,asthenospheric upwelling,mafic magma underplating,and crustal melting in the East Qinling Orogen.展开更多
The Southern Great Xing’an Range (SGXR) which forms part of the eastern segment of the Central Asian Orogenic Belt (CAOB) is known as one of the most important Cu-Mo-Pb-Zn-Ag-Au metallogenic belts in China,hosting a ...The Southern Great Xing’an Range (SGXR) which forms part of the eastern segment of the Central Asian Orogenic Belt (CAOB) is known as one of the most important Cu-Mo-Pb-Zn-Ag-Au metallogenic belts in China,hosting a number of porphyry Mo (Cu),skarn Fe (Sn),epithermal Au-Ag,and hydrothermal veintype Ag-Pb-Zn ore deposits.Here we investigate the Bianjiadayuan hydrothermal vein-type Ag-Pb-Zn ore deposit in the southern part of the SGXR.Porphyry Sn ±Cu ± Mo mineralization is also developed to the west of the Ag-Pb-Zn veins in the ore field.We identify a five-stage mineralization process based on field and petrologic studies including (i) the early porphyry mineralization stage,(ii) main porphyry mineralization stage,(iii) transition mineralization stage,(iv) vein-type mineralization stage and (v) late mineralization stage.Pyrite is the predominant sulfide mineral in all stages except in the late mineralization stage,and we identify corresponding four types of pyrites: Py1 is medium-grained subhedral to euhedral occurring in the early barren quartz vein;Py2 is medium- to fine-grained euhedral pyrite mainly coexisting with molybdenite,chalcopyrite,minor sphalerite and galena;Py3 is fine-grained,subhedral to irregular pyrite and displays cataclastic textures with micro-fractures;Py4 occurs as euhedral microcrystals and forms irregularly shaped aggregate with sphalerite and galena.LA-ICP-MS trace element analyses of pyrite show that Cu,Pb,Zn,Ag,Sn,Cd and Sb are partitioned into pyrite as structurally bound metals or mineral micro/nano-inclusions,whereas Co,Ni,As and Se enter the lattice via isomorphism in all types of pyrite.The Cu,Zn,Ag,Cd concentrations gradually increase from Py1 to Py4,which we correlate with cooling and mixing of ore-forming fluid with meteoric water.Py2 contains the highest contents of Co,Ni,Se,Te and Bi,suggesting high temperature conditions for the porphyry mineralization stage.Ratios of Co/Ni (0.03-10.79,average 2.13) and sulphur isotope composition of sulfide indicate typical hydrothermal origin for pyrites.The δ^34SCDT values of Py1 (0.42‰-1.61‰,average 1.16‰),Py2 (-1.23‰ to 0.82‰,average 0.35‰),Py3 (-0.36‰ to 2.47‰,average 0.97‰),Py4 (2.51‰-3.72‰,average 3.06‰),and other sulfides are consistent with those of typical porphyry deposit (-5‰ to 5‰),indicating that the Pb-Zn polymetallic mineralization in the Bianjiadayuan deposit is genetically linked to the Yanshanian (JurassiceCretaceous) magmatic-hydrothermal events.Variations of d34S values are ascribed to the changes in physical and chemical conditions during the evolution and migration of the ore-forming fluid.We propose that the high Sn content of pyrite in the Bianjiadayuan hydrothermal vein-type PbeZn polymetallic deposit can be used as a possible pathfinder to prospect for Sn mineralization in the surrounding area or deeper level of the ore field in this region.展开更多
The Khondalite Belt within the Inner Mongolia Suture Zone （IMSZ） in the North China Craton is a classic example for Paleoproterozoic ultrahigh-temperature （UHT） metamorphism. Here we report new spinel-bearing meta...The Khondalite Belt within the Inner Mongolia Suture Zone （IMSZ） in the North China Craton is a classic example for Paleoproterozoic ultrahigh-temperature （UHT） metamorphism. Here we report new spinel-bearing metapelitic granulites from a new locality at Xumayao within the southern domain of the IMSZ. Petrological studies and thermodynamic modeling of the spinel -- quartz-bearing assemblage shows that these rocks experienced extreme metamorphism at UHT conditions. Spinel occurs in two textural settings：（1） high Xzn（Zn/（Mg ＋ FeH -- Zn） = 0.071--0.232） spinel with perthitic K-feld- spar, sillimanite and quartz in the rock matrix; and （2）low Xzn （0.045-0.070） spinel as inclusions within garnet porphyroblasts in association with quartz and sillimanite. Our phase equilibria modeling indicates two main stages during the metamorphic evolution of these rocks：（l） near-isobaric cooling from 975 ℃ to 875 ℃ around 8 kbar, represented by the formation of garnet porphyroblasts from spinel and quartz; and（2）cooling and decompression from 850 ℃, 8 kbar to below 750 ℃- 6.5 kbar, represented by the break-down of garnet. The spinel ＋ quartz assemblage is considered to have been stable at peak metamorphism, formed through the break-down of cordierite, indi- caring a near isothermal compression process. Our study confirms the regional extent of UHT metamor- phism within the IMSZ associated with the Paleoproterozoic subduction-collision process.展开更多
The Berezitovoe deposit in the Sergachi volcano-plutonic and metallogenic belt preserves evidence for polymetallic mineralization of multiple stages.The steeply dipping gamet-tourmaline-muscovite-quartz metasomatites...The Berezitovoe deposit in the Sergachi volcano-plutonic and metallogenic belt preserves evidence for polymetallic mineralization of multiple stages.The steeply dipping gamet-tourmaline-muscovite-quartz metasomatites（with K-Ar ages of 132 ± 2.9 and 127 ± 4.4 Ma） carry two distinct stages of mineralization developed at different times：（1） polymetallic mineralization and（2） gold-quartz.The deposit is located within Paleozoic gneissose granitoids of the Pikansky complex（dated as 379 ± 1.1 Ma by zircon U-Pb method） intruded by early Cretaceous porphyry-like granites of the Haikta pluton（dated as137 ± 0.67 Ma by zircon U-Pb method） and late Cretaceous dikes of porphyrites,porphyries,and lamprophyres.Evidence suggests the action of late gold-bearing hydrothermal fluids on the early polymetallic ores and the selective mobilization of some elements from these lead to redeposition together with complex sulphosalts.展开更多
The origin of life on Earth remains enigmatic with diverse models and debates.Here we discuss essential requirements for the first emergence of life on our planet and propose the following nine requirements:(1)an ener...The origin of life on Earth remains enigmatic with diverse models and debates.Here we discuss essential requirements for the first emergence of life on our planet and propose the following nine requirements:(1)an energy source(ionizing radiation and thermal energy);(2)a supply of nutrients(P.K.REE.etc.);(3)a supply of life-constituting major elements;(4)a high concentration of reduced gases such as CH4,HCN and NH3;(5)dry-wet cycles to create membranes and polymerize RNA;(6)a non-toxic aqueous environment;(7)Na-poor water;(8)highly diversified environments,and(9)cyclic conditions,such as dayto-night,hot-to-cold etc.Based on these nine requirements,we evaluate previously proposed locations for the origin of Earth’s life,including:(1)Darwin’s"warm little pond",leading to a"prebiotic soup"for life;(2)panspermia or Neo-panspermia(succession model of panspermia);(3)transportation from/through Mars;(4)a deepsea hydrothermal system;(5)an on-land subduct ion-zone hot spring,and(6)a geyser systems driven by a natural nuclear reactor.We conclude that location(6)is the most ideal candidate for the o rigin point for Earth’s life because of its efficiency in continuously supplying both the energy and the necessary materials for life,thereby maintaining the essential"cradle"for its initial development.We also emphasize that falsifiable working hypothesis provides an important tool to evaluate one of the biggest mysteries of the universe-the origin of life.展开更多
＂Geoscience Frontiers＂ （GSF） has just completed one year, bringing out its maiden issues promptly and gaining reputation as a high quality multidisciplinary journal. As a ＇fledgling＇ journal, GSF is just spreadi...＂Geoscience Frontiers＂ （GSF） has just completed one year, bringing out its maiden issues promptly and gaining reputation as a high quality multidisciplinary journal. As a ＇fledgling＇ journal, GSF is just spreading its wings and preparing to soar into the skies.展开更多
基金jointly supported by the Fundamental Research Funds for the Central Universities (Grant No.2652016066)China Scholarship Council (Grant Nos.201706400016, 201806400026)+2 种基金Basic Research Project (GP2017021Development of integrated geological information based on digital mapping) of the Korea Institute of Geoscience and Mineral Resourcesfunded by the Ministry of Science, ICT,Future Planning
文摘The Qinling Orogen in Central China records the history of a complex geological evolution and tectonic transition from compression to extension during the Late Mesozoic,with concomitant voluminous granitoids formation.In this study,we present results from petrological,geochemical,zircon U-Pb-Lu-Hf isotopic studies on the Lengshui felsic dykes from Luanchuan region in the East Qinling Orogen.We also compile published geochronological,geochemical,and Hf isotopic data from Luanchuan region and present zircon Hf isotopic contour maps.The newly obtained age data yield two group of ages at w145 Ma and 140 Ma for two granite porphyries from the Lengshui felsic dykes,with the w145 Ma interpreted as response to the peak of magmatism in the region,and the w140 Ma as the timing of formation of the felsic dykes.The corresponding Hf isotopic data of the granite porphyries display negative εHf(t) values of e16.67 to e4.61,and Hf crustal model ages (TDM^C) of 2255e1490 Ma,indicating magma sourced from the melting of Paleo- to Mesoproterozoic crustal materials.The compiled age data display two major magmatic pulses at 160e130 Ma and 111e108 Ma with magmatic quiescence in between,and the zircon Hf isotopic data display εHf(t) values ranging from e41.9 to 2.1 and TDM^C values of 3387e1033 Ma,suggesting mixed crustal and mantle-derived components in the magma source,and correspond to multiple tectonic events during the Late Mesozoic.The Luanchuan granitoids are identified as I-type granites and most of these are highly fractionated granites,involving magma mixing and mingling and crystal fractionation.The tectonic setting in the region transformed from the Late Jurassic syn-collision setting to Early Cretaceous within-plate setting,with EeW extension in the Early Cretaceous.This extension is correlated with the NeS trending post-collisional extension between the North China Craton and Yangtze Craton as well as the EeW trending back-arc extension triggered by the westward Paleo-Pacific Plate subduction,eventually leading to lithospheric thinning,asthenospheric upwelling,mafic magma underplating,and crustal melting in the East Qinling Orogen.
基金financially supported by National Key Research and Development Program of China (2016YFC0600504)Fundamental Research Funds for the Central Universities (2652017218)
文摘The Southern Great Xing’an Range (SGXR) which forms part of the eastern segment of the Central Asian Orogenic Belt (CAOB) is known as one of the most important Cu-Mo-Pb-Zn-Ag-Au metallogenic belts in China,hosting a number of porphyry Mo (Cu),skarn Fe (Sn),epithermal Au-Ag,and hydrothermal veintype Ag-Pb-Zn ore deposits.Here we investigate the Bianjiadayuan hydrothermal vein-type Ag-Pb-Zn ore deposit in the southern part of the SGXR.Porphyry Sn ±Cu ± Mo mineralization is also developed to the west of the Ag-Pb-Zn veins in the ore field.We identify a five-stage mineralization process based on field and petrologic studies including (i) the early porphyry mineralization stage,(ii) main porphyry mineralization stage,(iii) transition mineralization stage,(iv) vein-type mineralization stage and (v) late mineralization stage.Pyrite is the predominant sulfide mineral in all stages except in the late mineralization stage,and we identify corresponding four types of pyrites: Py1 is medium-grained subhedral to euhedral occurring in the early barren quartz vein;Py2 is medium- to fine-grained euhedral pyrite mainly coexisting with molybdenite,chalcopyrite,minor sphalerite and galena;Py3 is fine-grained,subhedral to irregular pyrite and displays cataclastic textures with micro-fractures;Py4 occurs as euhedral microcrystals and forms irregularly shaped aggregate with sphalerite and galena.LA-ICP-MS trace element analyses of pyrite show that Cu,Pb,Zn,Ag,Sn,Cd and Sb are partitioned into pyrite as structurally bound metals or mineral micro/nano-inclusions,whereas Co,Ni,As and Se enter the lattice via isomorphism in all types of pyrite.The Cu,Zn,Ag,Cd concentrations gradually increase from Py1 to Py4,which we correlate with cooling and mixing of ore-forming fluid with meteoric water.Py2 contains the highest contents of Co,Ni,Se,Te and Bi,suggesting high temperature conditions for the porphyry mineralization stage.Ratios of Co/Ni (0.03-10.79,average 2.13) and sulphur isotope composition of sulfide indicate typical hydrothermal origin for pyrites.The δ^34SCDT values of Py1 (0.42‰-1.61‰,average 1.16‰),Py2 (-1.23‰ to 0.82‰,average 0.35‰),Py3 (-0.36‰ to 2.47‰,average 0.97‰),Py4 (2.51‰-3.72‰,average 3.06‰),and other sulfides are consistent with those of typical porphyry deposit (-5‰ to 5‰),indicating that the Pb-Zn polymetallic mineralization in the Bianjiadayuan deposit is genetically linked to the Yanshanian (JurassiceCretaceous) magmatic-hydrothermal events.Variations of d34S values are ascribed to the changes in physical and chemical conditions during the evolution and migration of the ore-forming fluid.We propose that the high Sn content of pyrite in the Bianjiadayuan hydrothermal vein-type PbeZn polymetallic deposit can be used as a possible pathfinder to prospect for Sn mineralization in the surrounding area or deeper level of the ore field in this region.
文摘The Khondalite Belt within the Inner Mongolia Suture Zone （IMSZ） in the North China Craton is a classic example for Paleoproterozoic ultrahigh-temperature （UHT） metamorphism. Here we report new spinel-bearing metapelitic granulites from a new locality at Xumayao within the southern domain of the IMSZ. Petrological studies and thermodynamic modeling of the spinel -- quartz-bearing assemblage shows that these rocks experienced extreme metamorphism at UHT conditions. Spinel occurs in two textural settings：（1） high Xzn（Zn/（Mg ＋ FeH -- Zn） = 0.071--0.232） spinel with perthitic K-feld- spar, sillimanite and quartz in the rock matrix; and （2）low Xzn （0.045-0.070） spinel as inclusions within garnet porphyroblasts in association with quartz and sillimanite. Our phase equilibria modeling indicates two main stages during the metamorphic evolution of these rocks：（l） near-isobaric cooling from 975 ℃ to 875 ℃ around 8 kbar, represented by the formation of garnet porphyroblasts from spinel and quartz; and（2）cooling and decompression from 850 ℃, 8 kbar to below 750 ℃- 6.5 kbar, represented by the break-down of garnet. The spinel ＋ quartz assemblage is considered to have been stable at peak metamorphism, formed through the break-down of cordierite, indi- caring a near isothermal compression process. Our study confirms the regional extent of UHT metamor- phism within the IMSZ associated with the Paleoproterozoic subduction-collision process.
基金the financial support of the Presidium and Far East Branch of the Russian Academy of Sciences (Grant No.15-1-2-019)the Russian Foundation for Basic Research(Grant No.15-05-00809)+1 种基金supported by the Talent Award to M.Santosh from the 1000 Plan of the Chinese Governmentthe Foreign Expert grants from China University of Geosciences(Beijing)
文摘The Berezitovoe deposit in the Sergachi volcano-plutonic and metallogenic belt preserves evidence for polymetallic mineralization of multiple stages.The steeply dipping gamet-tourmaline-muscovite-quartz metasomatites（with K-Ar ages of 132 ± 2.9 and 127 ± 4.4 Ma） carry two distinct stages of mineralization developed at different times：（1） polymetallic mineralization and（2） gold-quartz.The deposit is located within Paleozoic gneissose granitoids of the Pikansky complex（dated as 379 ± 1.1 Ma by zircon U-Pb method） intruded by early Cretaceous porphyry-like granites of the Haikta pluton（dated as137 ± 0.67 Ma by zircon U-Pb method） and late Cretaceous dikes of porphyrites,porphyries,and lamprophyres.Evidence suggests the action of late gold-bearing hydrothermal fluids on the early polymetallic ores and the selective mobilization of some elements from these lead to redeposition together with complex sulphosalts.
基金supported by MEXT KAKENHI:Grant-in-Aid for Scientific Research on Innovative Areas,Grant Numbers26106002,26106004,26106006the Ministry of Education and Science of the Russian Federation,Project No.14.Y26.31.0018
文摘The origin of life on Earth remains enigmatic with diverse models and debates.Here we discuss essential requirements for the first emergence of life on our planet and propose the following nine requirements:(1)an energy source(ionizing radiation and thermal energy);(2)a supply of nutrients(P.K.REE.etc.);(3)a supply of life-constituting major elements;(4)a high concentration of reduced gases such as CH4,HCN and NH3;(5)dry-wet cycles to create membranes and polymerize RNA;(6)a non-toxic aqueous environment;(7)Na-poor water;(8)highly diversified environments,and(9)cyclic conditions,such as dayto-night,hot-to-cold etc.Based on these nine requirements,we evaluate previously proposed locations for the origin of Earth’s life,including:(1)Darwin’s"warm little pond",leading to a"prebiotic soup"for life;(2)panspermia or Neo-panspermia(succession model of panspermia);(3)transportation from/through Mars;(4)a deepsea hydrothermal system;(5)an on-land subduct ion-zone hot spring,and(6)a geyser systems driven by a natural nuclear reactor.We conclude that location(6)is the most ideal candidate for the o rigin point for Earth’s life because of its efficiency in continuously supplying both the energy and the necessary materials for life,thereby maintaining the essential"cradle"for its initial development.We also emphasize that falsifiable working hypothesis provides an important tool to evaluate one of the biggest mysteries of the universe-the origin of life.
文摘＂Geoscience Frontiers＂ （GSF） has just completed one year, bringing out its maiden issues promptly and gaining reputation as a high quality multidisciplinary journal. As a ＇fledgling＇ journal, GSF is just spreading its wings and preparing to soar into the skies.
