Retention behavior of U(VI) and Th(IV) as their 2, 6-pyridine dicarboxylic acid (PDCA) complexes on reversed phase and ion exchange (cation, anion and mixed ion exchange) columns was studied and based on the results, ...Retention behavior of U(VI) and Th(IV) as their 2, 6-pyridine dicarboxylic acid (PDCA) complexes on reversed phase and ion exchange (cation, anion and mixed ion exchange) columns was studied and based on the results, a simple ion chromatography method for the determination of trace level thorium in uranium oxide using 0.075mM 2, 6-pyridine dicarboxylic acid (PDCA) and 1M KNO3 in 1.2M HNO3 as eluent (flow rate 1 mL/min)was proposed. The advantage of the developed method is that the separation of uranium matrix is not required prior to the ion chromatographic determination of trace Th. Separation was carried out on a mixed ion exchange stationary phase and a 10?4 M arsenazo (III) solution was used as post column reagent for detecting the separated metal ions. The separation of Th from uranium using PDCA in the present investigation is attributed through cation exchange mechanism. A calibration plot was constructed by following the standard addition method over the concentration range of 0.25 to 10 ppm of Th in the presence of uranium matrix, which resulted in a linear regression coefficient of 0.9978. The precision of the method was better than 5% and the LOD for Th was found to be 0.1ppm (S/N=3). The method has been validated by comparing the results with the results obtained from ICP-MS analysis where the This separated from the uranium matrix. The proposed method is simple, rapid, accurate and cost effective compared to techniques like ICP-MS or ICP-AES and is suitable for the routine kind of analysis.展开更多
Synchronization behavior of an ensemble of unidirectionally coupled neurons with a constant input is investigated. Chemical synapses are considered for coupling. Each neuron is also considered to be exposed to a self-...Synchronization behavior of an ensemble of unidirectionally coupled neurons with a constant input is investigated. Chemical synapses are considered for coupling. Each neuron is also considered to be exposed to a self-delayed feedback. The synchronization phenomenon is analyzed by the error dynamics of the response trajectories of the system. The effect of various model parameters e.g. coupling strength, feedback gain and time delay, on synchronization is also investigated and a measure of synchrony is computed in each cases. It is shown that the synchronization is not only achieved by increasing the coupling strength, the system also required to have a suitable feedback gain and time delay for synchrony. Robustness of the parameters for synchrony is verified for larger systems.展开更多
文摘Retention behavior of U(VI) and Th(IV) as their 2, 6-pyridine dicarboxylic acid (PDCA) complexes on reversed phase and ion exchange (cation, anion and mixed ion exchange) columns was studied and based on the results, a simple ion chromatography method for the determination of trace level thorium in uranium oxide using 0.075mM 2, 6-pyridine dicarboxylic acid (PDCA) and 1M KNO3 in 1.2M HNO3 as eluent (flow rate 1 mL/min)was proposed. The advantage of the developed method is that the separation of uranium matrix is not required prior to the ion chromatographic determination of trace Th. Separation was carried out on a mixed ion exchange stationary phase and a 10?4 M arsenazo (III) solution was used as post column reagent for detecting the separated metal ions. The separation of Th from uranium using PDCA in the present investigation is attributed through cation exchange mechanism. A calibration plot was constructed by following the standard addition method over the concentration range of 0.25 to 10 ppm of Th in the presence of uranium matrix, which resulted in a linear regression coefficient of 0.9978. The precision of the method was better than 5% and the LOD for Th was found to be 0.1ppm (S/N=3). The method has been validated by comparing the results with the results obtained from ICP-MS analysis where the This separated from the uranium matrix. The proposed method is simple, rapid, accurate and cost effective compared to techniques like ICP-MS or ICP-AES and is suitable for the routine kind of analysis.
文摘Synchronization behavior of an ensemble of unidirectionally coupled neurons with a constant input is investigated. Chemical synapses are considered for coupling. Each neuron is also considered to be exposed to a self-delayed feedback. The synchronization phenomenon is analyzed by the error dynamics of the response trajectories of the system. The effect of various model parameters e.g. coupling strength, feedback gain and time delay, on synchronization is also investigated and a measure of synchrony is computed in each cases. It is shown that the synchronization is not only achieved by increasing the coupling strength, the system also required to have a suitable feedback gain and time delay for synchrony. Robustness of the parameters for synchrony is verified for larger systems.
