A single-phase anti-perovskite medium-entropy alloy nitride foams(MEANFs),as innovative materials for electromagnetic wave(EMW)absorption,have been successfully synthesized through the lattice expansion induced by nit...A single-phase anti-perovskite medium-entropy alloy nitride foams(MEANFs),as innovative materials for electromagnetic wave(EMW)absorption,have been successfully synthesized through the lattice expansion induced by nitrogen doping.This achievement notably overcomes the inherent constraints of conventional metal-based absorbers,including low resonance frequency,high conductivity,and elevated density,for the synergistic advantages provided by multimetallic alloys and foams.Microstructural analysis with comprehensive theoretical calculations provides in-depth insights into the formation mechanism,electronic structure,and magnetic moment of MEANFs.Furthermore,deliberate component design along with the foam structure proves to be an effective strategy for enhancing impedance matching and absorption.The results show that the MEANFs exhibit a minimum reflection loss(RL_(min))value of-60.32 dB and a maximum effective absorption bandwidth(EAB_(max))of 5.28 GHz at 1.69 mm.This augmentation of energy dissipation in EMW is predominantly attributed to factors such as porous structure,interfacial polarization,defect-induced polarization,and magnetic resonance.This study demonstrates a facile and efficient approach for synthesizing single-phase medium-entropy alloys,emphasizing their potential as materials for electromagnetic wave absorption due to their adjustable magnetic-dielectric properties.展开更多
Despite significant progress in the structure and properties of porous absorbing materials,major challenges remain due to complex preparation technology,high production costs,and poor corrosion resistance.In this stud...Despite significant progress in the structure and properties of porous absorbing materials,major challenges remain due to complex preparation technology,high production costs,and poor corrosion resistance.In this study,nanowires were used as the substrate,liquid nitrogen controls ice crystal growth orientation,and ammonia gas facilitates the generation of magnetic substances.The resulting pure magnetic porous foam(PMF)material exhibits enhanced performance in absorbing electromagnetic waves(EMWs)and improved corrosion resistance.The PMF's microstructure was analyzed for its dielectric and magnetic loss characteristics.The PMF combines a porous framework,nanoscale architecture,and exclusive magnetic components to create a lightweight foam absorbent material with enhanced magnetic dissipation capabilities.Among them,the Fe_(4)N PMF demonstrates an impressive minimum reflection loss(RLmin)value of−66.8 dB at a thickness of 1.09 mm,exhibits an effective absorption bandwidth of 4.00 GHz,and shows exceptional corrosion resistance with a self-corrosion potential of−0.65 V.Moreover,the effectiveness of the Fe_(4)N PMF in absorbing intelligent EMWs has been validated through radar cross-section(RCS)simulations.In summary,this study has developed electromagnetic wave-absorbing materials with slim profiles,lightweight properties,strong absorption capabilities,and excellent corrosion resistance.These characteristics make them highly promising for microwave absorption applications.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.52071294)the National Key Research and Development Program(Grant No.2022YFE0109800)the Natural Science Foundation of Zhejiang Province(Grant No.LY20E020015).
文摘A single-phase anti-perovskite medium-entropy alloy nitride foams(MEANFs),as innovative materials for electromagnetic wave(EMW)absorption,have been successfully synthesized through the lattice expansion induced by nitrogen doping.This achievement notably overcomes the inherent constraints of conventional metal-based absorbers,including low resonance frequency,high conductivity,and elevated density,for the synergistic advantages provided by multimetallic alloys and foams.Microstructural analysis with comprehensive theoretical calculations provides in-depth insights into the formation mechanism,electronic structure,and magnetic moment of MEANFs.Furthermore,deliberate component design along with the foam structure proves to be an effective strategy for enhancing impedance matching and absorption.The results show that the MEANFs exhibit a minimum reflection loss(RL_(min))value of-60.32 dB and a maximum effective absorption bandwidth(EAB_(max))of 5.28 GHz at 1.69 mm.This augmentation of energy dissipation in EMW is predominantly attributed to factors such as porous structure,interfacial polarization,defect-induced polarization,and magnetic resonance.This study demonstrates a facile and efficient approach for synthesizing single-phase medium-entropy alloys,emphasizing their potential as materials for electromagnetic wave absorption due to their adjustable magnetic-dielectric properties.
基金financially supported by the National Natural Science Foundation of China(No.52471212)the National Key Research and Development Program(No.2022YFE0109800).
文摘Despite significant progress in the structure and properties of porous absorbing materials,major challenges remain due to complex preparation technology,high production costs,and poor corrosion resistance.In this study,nanowires were used as the substrate,liquid nitrogen controls ice crystal growth orientation,and ammonia gas facilitates the generation of magnetic substances.The resulting pure magnetic porous foam(PMF)material exhibits enhanced performance in absorbing electromagnetic waves(EMWs)and improved corrosion resistance.The PMF's microstructure was analyzed for its dielectric and magnetic loss characteristics.The PMF combines a porous framework,nanoscale architecture,and exclusive magnetic components to create a lightweight foam absorbent material with enhanced magnetic dissipation capabilities.Among them,the Fe_(4)N PMF demonstrates an impressive minimum reflection loss(RLmin)value of−66.8 dB at a thickness of 1.09 mm,exhibits an effective absorption bandwidth of 4.00 GHz,and shows exceptional corrosion resistance with a self-corrosion potential of−0.65 V.Moreover,the effectiveness of the Fe_(4)N PMF in absorbing intelligent EMWs has been validated through radar cross-section(RCS)simulations.In summary,this study has developed electromagnetic wave-absorbing materials with slim profiles,lightweight properties,strong absorption capabilities,and excellent corrosion resistance.These characteristics make them highly promising for microwave absorption applications.
