In this work,rare earth ions(REs)including Yb^(3+)/Er^(3+),Yb^(3+)/Ho^(3+)and Yb^(3+)/Tm^(3+)co-doped manganese oxyfluoride glasses were fabricated using melt quenching method.By fully utilizing the upconversion lumin...In this work,rare earth ions(REs)including Yb^(3+)/Er^(3+),Yb^(3+)/Ho^(3+)and Yb^(3+)/Tm^(3+)co-doped manganese oxyfluoride glasses were fabricated using melt quenching method.By fully utilizing the upconversion luminescence(UCL)of REs and regulating energy transfer between the different energy levels of RE ions and the4T1level of Mn^(2+),the output of UCL was regulated and even pure-red light can be achieved.Moreover,owing to the selective partitioning caused by phase-separation network structure in the oxyfluoride glass,the UCL intensity of glasses annealed for 72 h is significantly enhanced 58 times compared to the rapidly quenched samples.展开更多
Visible light microlasers are essential building blocks for integrated photonics.However,achieving low-threshold(μw),continuous-wave(CW)visible light lasing at room temperature(RT)has been a challenge because of the ...Visible light microlasers are essential building blocks for integrated photonics.However,achieving low-threshold(μw),continuous-wave(CW)visible light lasing at room temperature(RT)has been a challenge because of the formidable requirement of population inversion at short wavelengths.Rare-earth(RE)-activated microcavities,featuring highquality factor(Q)and small mode volume of whispering gallery modes,offer a great opportunity for achieving infrared-to-visible upconversion(UC)lasing.Here,we report that batch-produced nano-glass composite(GC)microspheres incorporating RE-doped fluoride nanocrystals show efficient UC emissions.These multi-phase composite microspheres exhibit a high Q value(≥10^(5)),comparable to that of conventional multi-component glass microspheres.The UC lasing with pure red,green,and blue(RGB)emissions are demonstrated based on a highly efficient tapered fiber-microsphere system.More importantly,the GC microspheres manifest reduced(by 45%)lasing threshold and enhanced(more than four times)slope effciency.These characteristics,together with excellent long-term stability,suggest a promising solution to achieving highly robust,stand-alone,low-threshold,and versatile UC microlasers.展开更多
基金Project supported by National Natural Science Foundation of China(62305244,62374112,62105078)Shandong Province Natural Science Foundation(ZR2021QE060,ZR2021QF009)+1 种基金Young Elite Scientists Sponsorship Program by China Association for Science and Technology(2022QNRC001)Youth Science and Technology Innovation Team of Shandong Province Institution of Higher Learning(2022KJ258)。
文摘In this work,rare earth ions(REs)including Yb^(3+)/Er^(3+),Yb^(3+)/Ho^(3+)and Yb^(3+)/Tm^(3+)co-doped manganese oxyfluoride glasses were fabricated using melt quenching method.By fully utilizing the upconversion luminescence(UCL)of REs and regulating energy transfer between the different energy levels of RE ions and the4T1level of Mn^(2+),the output of UCL was regulated and even pure-red light can be achieved.Moreover,owing to the selective partitioning caused by phase-separation network structure in the oxyfluoride glass,the UCL intensity of glasses annealed for 72 h is significantly enhanced 58 times compared to the rapidly quenched samples.
基金supported by the National Natural Science Foundation of China(62305244,52372003,62374112,62105078)Shandong Province Natural ScienceFoundation(ZR2021QE060,ZR2021QF009)+2 种基金Natural Science Foundation of Heilongjiang Province of China(ZD2023E004)Young Elite Scientists Sponsorship Program by China Association for Science and Technology(2022QNRC001)Youth science and technology innovation team of Shandong Province institution of higher learning(2022KJ258).
文摘Visible light microlasers are essential building blocks for integrated photonics.However,achieving low-threshold(μw),continuous-wave(CW)visible light lasing at room temperature(RT)has been a challenge because of the formidable requirement of population inversion at short wavelengths.Rare-earth(RE)-activated microcavities,featuring highquality factor(Q)and small mode volume of whispering gallery modes,offer a great opportunity for achieving infrared-to-visible upconversion(UC)lasing.Here,we report that batch-produced nano-glass composite(GC)microspheres incorporating RE-doped fluoride nanocrystals show efficient UC emissions.These multi-phase composite microspheres exhibit a high Q value(≥10^(5)),comparable to that of conventional multi-component glass microspheres.The UC lasing with pure red,green,and blue(RGB)emissions are demonstrated based on a highly efficient tapered fiber-microsphere system.More importantly,the GC microspheres manifest reduced(by 45%)lasing threshold and enhanced(more than four times)slope effciency.These characteristics,together with excellent long-term stability,suggest a promising solution to achieving highly robust,stand-alone,low-threshold,and versatile UC microlasers.
