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中国沉积岩容矿铅锌矿床中的关键金属 被引量:19
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作者 刘英超 侯增谦 +2 位作者 岳龙龙 马旺 唐波浪 《科学通报》 EI CAS CSCD 北大核心 2022年第4期406-424,共19页
沉积岩容矿铅锌矿床主要包括碎屑岩赋矿(clastic-dominated,CD)矿床和密西西比河谷型(Mississippi-Valley type,MVT)矿床两种,它是世界上Cd、Ga、Ge等关键金属的重要来源,并具有In、Co、Tl的资源潜力.中国沉积岩容矿铅锌矿床主要分布在... 沉积岩容矿铅锌矿床主要包括碎屑岩赋矿(clastic-dominated,CD)矿床和密西西比河谷型(Mississippi-Valley type,MVT)矿床两种,它是世界上Cd、Ga、Ge等关键金属的重要来源,并具有In、Co、Tl的资源潜力.中国沉积岩容矿铅锌矿床主要分布在5个成矿区/带,提供了全国54%的铅锌用量,但其伴生关键金属的资源潜力和成矿机制尚不清楚.本文在综述沉积岩容矿铅锌矿床中伴生的主要关键金属和中国沉积岩容矿铅锌矿床的基础上,详细总结了中国沉积岩容矿铅锌矿床中关键金属的分布特征和富集机制.各类关键金属元素在中国沉积岩容矿铅锌矿床中分布不均,相对地壳丰度,Cd、Ge、In最为富集,Tl、Co有一定富集,Ga的富集程度较低;从矿床类型上来看,Cd、Ga、Ge、Tl在中国MVT矿床中相对富集,In、Co在CD矿床中相对富集;从区域分布上来看,不同元素的富集区带差异很大,除Cd在5个成矿区/带都有较好富集外,其他金属在三江带、扬子地台、厂坝成矿带出现不同程度富集.总结发现,沉积岩容矿铅锌矿床对所富集关键金属的种类具选择性,而关键金属在该类矿床中的富集程度也具差异性.前者主要由关键金属元素同矿床中相关矿物组成元素(主要为Zn和Fe)的地球化学相似性导致,后者则由关键金属进入赋存矿物的替代形式、成矿流体的物理化学条件、成矿背景导致.目前,中国沉积岩容矿铅锌矿床伴生关键金属的研究尚处于起步阶段,建立相关资源数据库,深入开展富集成矿机制研究,厘定不同铅锌成矿区/带关键金属的区域成矿规律是亟须开展的工作. 展开更多
关键词 沉积岩容矿铅锌矿床 密西西比河谷型(MVT)铅锌矿床 碎屑岩赋矿(CD)铅锌矿床 关键金属
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Palynological constraints on the age of the Mississippi Valley-type Changdong Pb-Zn deposit,Sanjiang belt,West China 被引量:3
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作者 Yingchao LIU Yucai SONG +5 位作者 Zengqian HOU Dangpeng XI Suping LI longlong yue Wang MA Bolang TANG 《Science China Earth Sciences》 SCIE EI CSCD 2022年第1期167-181,共15页
Mississippi Valley-type(MVT)Pb-Zn deposits serve as the world’s major supply of Pb-Zn resources.However,the age constraint of MVT Pb-Zn deposits has long been a big challenge,due to the lack of minerals that are uneq... Mississippi Valley-type(MVT)Pb-Zn deposits serve as the world’s major supply of Pb-Zn resources.However,the age constraint of MVT Pb-Zn deposits has long been a big challenge,due to the lack of minerals that are unequivocally related to ore deposition and that can be used for radioisotopic dating.Here we show sporopollens can provide useful chronological information on the Changdong MVT Pb-Zn deposit in the Simao basin,Sanjiang belt,West China.The Pb-Zn ores in the Changdong deposit are hosted by internal sediments in paleo-karst caves of meteoric origin.Sphalerite and galena occur as replacements of carbonate minerals and void infillings in the internal sediments.The relations suggest that the Pb-Zn mineralization occurred after the deposition of the internal sediments.A palynological assemblage mainly composed of angiosperm pollen dominated by Castanea,Quercus,and Carya and fern spores dominated by Polypodiaceae,Pteris,and Athyriaceae was identified.These pollen and spores place the ore-hosting internal sediments and the Changdong paleo-karst at early to middle Oligocene.Consequently,the Changdong Pb-Zn deposit must have formed after the early Oligocene(~34 Ma).These age constraints,together with the geological characteristics,indicate that the Changdong Pb-Zn deposit is a paleo-karst-controlled MVT deposit related to fold-thrust systems in the Sanjiang belt.The Changdong deposit is similar to other MVT Pb-Zn deposits in the northern part of the Sanjiang belt,making it possible to extend this Pb-Zn belt 500 km further to the South.Results presented here highlights the potential of sporopollens in dating the age of MVT deposits related to paleo-karst formation in young orogenic belts. 展开更多
关键词 Mississippi Valley-type(MVT)Pb-Zn deposits Age constraint PALYNOMORPHS Internal sediments Paleo-karst Changdong deposit Sanjiang fold-thrust belt
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