In this paper, a new pressure reducing valve （PRV） with an orifice plate is proposed. The main objective is to explain the mechanisms of pressure reduction and energy conversion in the new PRV. A numerical simulatio...In this paper, a new pressure reducing valve （PRV） with an orifice plate is proposed. The main objective is to explain the mechanisms of pressure reduction and energy conversion in the new PRV. A numerical simulation method was used to investigate the PRV internal flow field and to analyze the throttling effects of the orifice plate and the transform of thermal parameters as outlet pressure, outlet temperature, velocity, and superheat. A structure improvement method for the valve body and orifice plate is put forward to reduce energy loss. The governing equations for internal flow numerical simulation are composed of the continuity, momentum, energy and k-e transport equations, based on isotropic eddy viscosity theory. Different valve plug displacement models were built to describe the double throttling process. Our analysis shows that the steam pressure drops twice and the degree of superheat increases. There are also lots of eddies which clog the flow channel and disturb the steam flow in the valve cavity after the valve plug and the outlet cavity. After modifying the structure, the numerical results show a better performance of steam flow.展开更多
In this study, Yb immobilized NaY zeolite catalyst（Yb/NaY） was obtained by a hydrothermal method and characterized by XRD, BET, FT-IR, ICP-AES, and NH3-TPD. The catalyst displayed good catalytic activity when applie...In this study, Yb immobilized NaY zeolite catalyst（Yb/NaY） was obtained by a hydrothermal method and characterized by XRD, BET, FT-IR, ICP-AES, and NH3-TPD. The catalyst displayed good catalytic activity when applied to the synthesis of quinoxalines via condensation of a-hydroxyketones with 1,2-diamines,and could be reused several times without any loss of catalytic activity.展开更多
NO oxidation is the key reaction for the oxidative NO x removal process.In this work,the catalytic NO oxidation performance of the Al2O3 supported metal oxide catalysts(M-Al2O3,M=V,Mn,Fe,Co,Ni and Ce)is evaluated.The ...NO oxidation is the key reaction for the oxidative NO x removal process.In this work,the catalytic NO oxidation performance of the Al2O3 supported metal oxide catalysts(M-Al2O3,M=V,Mn,Fe,Co,Ni and Ce)is evaluated.The oxidation product is absorbed by the alkaline solution for NO x removal.The NO oxidation activity increases in the following order:V<<Ce<Ni<Fe<Co<Mn.As the NO oxidation involves the O uptake into the metal oxide lattice and oxidation of the adsorbed NO by the lattice O,the highest activity of Mn is attributed to the appropriate redox potential of Mn,which favors both the O uptake and the NO oxidation steps.For all the M-Al2O3 catalysts,there is an intermediate temperature to achieve maximum NO conversion,which is lower for more efficient M-Al2O3 catalyst.The temperature dependence suggests that the NO oxidation at low temperature is kinetically controlled while it is thermodynamically limited at higher temperature.The NO x removal ratio by the alkaline solution absorption increases with the NO2/NO ratio,with a maximum removal ratio of 80%when the NO2/NO ratio is higher than 3,indicating that a very high NO conversion is unnecessary.展开更多
基金Project (No. 2012C11018-1) supported by the Science and Technology Department of Zhejiang Province,China
文摘In this paper, a new pressure reducing valve （PRV） with an orifice plate is proposed. The main objective is to explain the mechanisms of pressure reduction and energy conversion in the new PRV. A numerical simulation method was used to investigate the PRV internal flow field and to analyze the throttling effects of the orifice plate and the transform of thermal parameters as outlet pressure, outlet temperature, velocity, and superheat. A structure improvement method for the valve body and orifice plate is put forward to reduce energy loss. The governing equations for internal flow numerical simulation are composed of the continuity, momentum, energy and k-e transport equations, based on isotropic eddy viscosity theory. Different valve plug displacement models were built to describe the double throttling process. Our analysis shows that the steam pressure drops twice and the degree of superheat increases. There are also lots of eddies which clog the flow channel and disturb the steam flow in the valve cavity after the valve plug and the outlet cavity. After modifying the structure, the numerical results show a better performance of steam flow.
基金the National Natural Science Foundation of China (No. 20802052) for financial support
文摘In this study, Yb immobilized NaY zeolite catalyst（Yb/NaY） was obtained by a hydrothermal method and characterized by XRD, BET, FT-IR, ICP-AES, and NH3-TPD. The catalyst displayed good catalytic activity when applied to the synthesis of quinoxalines via condensation of a-hydroxyketones with 1,2-diamines,and could be reused several times without any loss of catalytic activity.
基金supported by the research funds from RIPP, SINOPEC
文摘NO oxidation is the key reaction for the oxidative NO x removal process.In this work,the catalytic NO oxidation performance of the Al2O3 supported metal oxide catalysts(M-Al2O3,M=V,Mn,Fe,Co,Ni and Ce)is evaluated.The oxidation product is absorbed by the alkaline solution for NO x removal.The NO oxidation activity increases in the following order:V<<Ce<Ni<Fe<Co<Mn.As the NO oxidation involves the O uptake into the metal oxide lattice and oxidation of the adsorbed NO by the lattice O,the highest activity of Mn is attributed to the appropriate redox potential of Mn,which favors both the O uptake and the NO oxidation steps.For all the M-Al2O3 catalysts,there is an intermediate temperature to achieve maximum NO conversion,which is lower for more efficient M-Al2O3 catalyst.The temperature dependence suggests that the NO oxidation at low temperature is kinetically controlled while it is thermodynamically limited at higher temperature.The NO x removal ratio by the alkaline solution absorption increases with the NO2/NO ratio,with a maximum removal ratio of 80%when the NO2/NO ratio is higher than 3,indicating that a very high NO conversion is unnecessary.
