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Microstructure and mechanical properties of ZK61 magnesium alloy thin-walled cylindrical component processed by two-step forging
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作者 Fang Chai Jianqiang Feng +6 位作者 Xinghui Han Wuhao Zhuang Yizhe Chen Zhili Hu Xuan Hu Fangyan Zheng lin hua 《Journal of Magnesium and Alloys》 2025年第5期2416-2432,共17页
Magnesium alloy thin-walled cylindrical components with the advantages of high specific stiffness and strength present broad prospect for the lightweight of aerospace components.However,poor formability resulting from... Magnesium alloy thin-walled cylindrical components with the advantages of high specific stiffness and strength present broad prospect for the lightweight of aerospace components.However,poor formability resulting from the hexagonal close-packed crystal structure in magnesium alloy puts forwards a great challenge for thin-walled cylindrical components fabrication,especially for extreme structure with the thicknesschanging web and the high thin-wall.In this research,an ZK61 magnesium alloy thin-walled cylindrical component was successfully fabricated by two-step forging,i.e.,the pre-forging and final-forging is mainly used for wed and thin-wall formation,respectively.Microstructure and mechanical properties at the core,middle and margin of the web and the thin-wall of the pre-forged and final-forged components are studied in detail.Due to the large strain-effectiveness and metal flow along the radial direction(RD),the grains of the web are all elongated along RD for the pre-forged component,where an increasingly elongated trend is found from the core to the margin of the wed.A relatively low recrystallized degree occurs during pre-forging,and the web at different positions are all with prismatic and pyramid textures.During finalforging,the microstructures of the web and the thin-wall are almost equiaxed due to the remarkable occurrence of dynamic recrystallization.Similarity,except for few basal texture of the thin-wall,only prismatic and pyramid textures are found for the final-forged component.Compared with the initial billet,an obviously improved mechanical isotropy is achieved during pre-forging,which is well-maintained during final-forging. 展开更多
关键词 Magnesium alloy Thin-walled cylindrical component Two-step forging Microstructure Mechanical properties
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富铁载硫生物炭固定稻田土壤镉砷的效果和机制
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作者 许垂堃 曾鸿鹄 +9 位作者 梁延鹏 张学洪 林华 涂志红 周自坚 李华伟 谭智宇 梁子豪 张雨喆 陈功宁 《环境科学学报》 北大核心 2026年第1期385-400,共16页
稻田镉、砷环境行为差异大,生物炭在降低镉有效性的同时提高了砷在土壤中的移动性.本研究通过硫铁化改性合成了富铁载硫生物炭(FSBC),并探明其固定稻田土壤镉、砷的效果和机制.通过吸附等温实验发现,25°C条件下,FSBC对Cd(II)和As(I... 稻田镉、砷环境行为差异大,生物炭在降低镉有效性的同时提高了砷在土壤中的移动性.本研究通过硫铁化改性合成了富铁载硫生物炭(FSBC),并探明其固定稻田土壤镉、砷的效果和机制.通过吸附等温实验发现,25°C条件下,FSBC对Cd(II)和As(III)的最大吸附容量分别为152.7 mg·g^(-1)(pH=6)和134.8 mg·g^(-1)(pH=4),FSBC主要通过共沉淀和表面络合固定水溶液中的Cd(II)和As(III).通过水稻盆栽试验发现,与对照组(CK)相比,添加1%(m/m)FSBC使土壤中高生物有效性的Cd和As分别减少了13.9%和11.6%,使籽粒中Cd和As含量分别降低了28.9%和61.1%,其中,As(III)含量减少了16.0%.其主要机制包括:(1)提升土壤pH;(2)促进无定型铁氧化矿物的形成与分散,增加其对土壤镉、砷的截留贮存作用;(3)硫铁纳米材料通过共沉淀固定土壤Cd和As;(4)促进了水稻根表铁膜形成及其对镉、砷的固定;(5)增强了土壤耐镉耐砷的微生物群落.该研究成果可以拓展生物炭的环境应用,为稻田镉、砷复合污染的治理提供新的理论依据和技术支持. 展开更多
关键词 同步阻控 水稻 富铁载硫生物炭
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Modeling studies on divorced eutectic formation of high pressure die cast magnesium alloy 被引量:4
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作者 Meng-wu Wu lin hua Shou-mei Xiong 《China Foundry》 SCIE 2018年第1期58-65,共8页
The morphology and content of the divorced eutectic in the microstructure of high pressure die casting(HPDC) magnesium alloy have a great influence on the final performance of castings. Based on the previous work conc... The morphology and content of the divorced eutectic in the microstructure of high pressure die casting(HPDC) magnesium alloy have a great influence on the final performance of castings. Based on the previous work concerning simulation of the nucleation and dendritic growth of primary α-Mg during the solidification of magnesium alloy under HPDC process, an extension was made to the formerly established CA(Cellular Automaton) model with the purpose of modeling the nucleation and growth of Mg-Al eutectic. With a temperature field and solute field obtained during simulation of the primary α-Mg dendrites as the initial condition of the modified CA model, modeling of the Mg-Al eutectic with a divorced morphology was achieved. Moreover, the simulated results were in accordance with the experimental ones regarding the distribution and content of the divorced eutectic. Taking a "cover-plate" die casting with AM60 magnesium alloy as an example, the rapid solidification with a high cooling rate at the surface layer of the casting led to a fine and uniform grain size of primary α-Mg, while the divorced eutectic at the grain boundary revealed a more dispersed and granular morphology. Islands of divorced eutectic were observed at the central region of the casting, due to the existence of ESCs(Externally Solidified Crystals) which contributed to a coarse and non-uniform grain size of primary α-Mg. The volume percentage of the eutectic β-Mg_(17)Al_(12) phase is about 2%-6% in the die casting as a whole. The numerical model established in this study is of great significance to the study of the divorced eutectic in the microstructure of die cast magnesium alloy. 展开更多
关键词 magnesium alloy high pressure die casting divorced eutectic microstructure simulation
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Radial envelope forming mechanism and process design method for cylindrical rings with thin wall and high web ribs 被引量:3
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作者 Xinghui HAN Yanlei MIN +4 位作者 Wuhao ZhuaNG lin hua Duanyang TIAN Zushen DENG Ningbo LIU 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第12期461-476,共16页
Cylindrical rings with thin wall and high web ribs(CRTWHWR)are widely used as the key load bearing structures such as rocket body and space station cabin in aerospace field.However,it is still difficult to efficiently... Cylindrical rings with thin wall and high web ribs(CRTWHWR)are widely used as the key load bearing structures such as rocket body and space station cabin in aerospace field.However,it is still difficult to efficiently manufacture CRTWHWR with high performance because of their extreme geometry with thin-walled skins,high web ribs and large size.In this paper,a novel radial envelope forming process is put forward to efficiently achieve the plastic forming of CRTWHWR with high performance.Firstly,the principle of radial envelope forming process is clarified.Then,an efficient design method for the tool motion and geometry is proposed based on the reverse envelope principle,i.e.,CRTWHWR is adopted to reversely envelope the tool and thus the tool which does not interfere with CRTWHWR can be efficiently obtained in a single operation.Finally,a reasonable 3D FE model of the radial envelope forming process of CRTWHWR is established and the radial envelope forming mechanism of CRTWHWR is comprehensively revealed.Through the FE simulation and experiments with material of plastic mud,a typical CRTWHWR with diameter of 300 mm,axial height of 192 mm,the maximum rib height of 25 mm,the minimum rib thickness of 3 mm and skin thickness of 5 mm is radial envelope formed,i.e.,the ratio of the maximum rib height to the minimum rib thickness reaches 8.33,the ratio of the maximum rib height to skin thickness reaches 5 and the ratio of diameter to the minimum rib thickness reaches 100.The above results verify that the proposed radial envelope forming process has great potentials in efficiently manufacturing CRTWHWR with extreme geometry. 展开更多
关键词 Radial envelope forming Cylindrical ring with thin wall and high web ribs Forming mechanism FE simulation Tool design
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Modelling and analysis of metal flowing behaviors in constraining ring rolling of tapered ring with thin wall and three high ribs 被引量:3
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作者 lin hua Duanyang TIAN +1 位作者 Xinghui HAN Wuhao ZhuaNG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第6期476-492,共17页
Tapered ring with thin wall and three high ribs(TRTWTHR),showing complicated geometry(wall thickness is less than 4 mm and rib height exceeds 20 mm),is extensively utilized to fabricate the critical structural parts o... Tapered ring with thin wall and three high ribs(TRTWTHR),showing complicated geometry(wall thickness is less than 4 mm and rib height exceeds 20 mm),is extensively utilized to fabricate the critical structural parts of aerospace equipment such as spacecraft cabin,rocket body and fuel tank because of light weight and high carrying capacity.How to fabricate TRTWTHR with high performance is a critical problem that aerospace area needs to solve.In this work,constraining ring rolling(CRR)technique is first adopted to form TRTWTHR.However.unreasonable metal streamlines(UMS)and uncoordinated growth of three ribs easily occur in CRR of TRTWTHR,which makes the forming quality of TRTWTHR difficult to be controlled.Faced with this difficulty,an analytical model that can predict UMS and the height of three ribs in CRR of TRTWTHR is established so as to guide the process design of CRR.Subsequently,the reliability of the established analytical model and the feasibility of CRR of TRTWTHR are confirmed by FE simulation and experiment.Then,using the established analytical model,the window of UMS occurring relevant to the tapered angle of TRTWTHR and the location of the rib of middle end is developed.Finally,three uncoordinated growth modes among three ribs are found when the width of three ribs is identical and UMS do not occur,and the mechanisms of three uncoordinated growth modes are revealed. 展开更多
关键词 Analytical model Constraining ring rolling Growth of three ribs Metal streamlines Tapered ring with thin wall and three high ribs
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An innovative constraining ring rolling process for manufacturing conical rings with thin sterna and high ribs 被引量:3
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作者 Duanyang TIAN Xinghui HAN +1 位作者 lin hua Xuan HU 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2022年第8期324-339,共16页
Conical rings with thin sterna and high ribs(CRTSHR)are key bearing-load parts of aerospace equipment,which are required to be manufactured with high performance and efficiency.Traditional ring rolling is the most pre... Conical rings with thin sterna and high ribs(CRTSHR)are key bearing-load parts of aerospace equipment,which are required to be manufactured with high performance and efficiency.Traditional ring rolling is the most preferred method for manufacturing high-performance ring parts,but it can hardly achieve the forming of CRTSHR due to the extreme geometry of CRTSHR.To solve this difficulty,an innovative constraining ring rolling process(CRR)is proposed in this paper to manufacture CRTSHR.To evaluate the proposed CRR and reveal its deformation behaviors,a thermomechanical coupled FE model for CRR of CRTSHR is established.Then,the experiment for CRR of CRTSHR is performed on a modified ring rolling machine,which proves that CRR of CRTSHR is feasible and the established FE model is reliable.Based on the reliable FE model,the metal flow mode in deformed CRTSHR is analyzed,and the deformation characteristics such as the stress state,strain distribution and the evolution of power parameters in CRR of CRTSHR are revealed.Finally,the influences of key parameters such as the friction factor between ring and molds,the diameter of idle roll and the feed velocity of idle roll on CRR of CRTSHR are investigated by FE simulation. 展开更多
关键词 Conical rings with thin sterna and high ribs Deformation characteristics FE simulation Metal flow Ring rolling
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支气管肺泡灌洗液宏基因组二代测序技术在成人重症肺炎患者中的应用价值 被引量:3
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作者 黄捷敏 林化 +2 位作者 梁道业 韦湫桂 谢娟娟 《中国现代药物应用》 2025年第11期88-91,共4页
目的探讨支气管肺泡灌洗液(BALF)宏基因组二代测序技术(mNGS)在成人重症肺炎病原学诊断中的价值及对患者预后的影响。方法28例成人重症肺炎患者,留取BALF,分别进行传统微生物培养及mNGS检测。分析患者基本资料,比较BALF传统微生物培养及... 目的探讨支气管肺泡灌洗液(BALF)宏基因组二代测序技术(mNGS)在成人重症肺炎病原学诊断中的价值及对患者预后的影响。方法28例成人重症肺炎患者,留取BALF,分别进行传统微生物培养及mNGS检测。分析患者基本资料,比较BALF传统微生物培养及mNGS阳性检出率及细菌、真菌阳性检出率,分析入住重症加强护理病房(ICU)后留取BALF送检mNGS的时间与预后的关系。结果28例患者急性生理与慢性健康评分系统Ⅱ(APACHEⅡ)评分、序贯器官衰竭估计(SOFA)评分分别为204(138,427)、9(7.75,12.25)分;17例(60.7%)生存,11例死亡(39.3%)。mNGS阳性检出率为96.4%(27/28),高于传统微生物培养的46.4%(13/28),差异存在统计学意义(P<0.05)。mNGS对细菌、真菌的阳性检出率分别为75.0%、67.9%,高于传统微生物培养的39.3%、10.7%,差异存在统计学意义(P<0.05)。生存和死亡患者入住ICU后留取BALF送检m NGS的时间比较未发现统计学差异(Z=0.190,P=0.848>0.05)。结论相比传统微生物培养,mNGS对成人重症肺炎患者病原体的阳性检出率更高,入住ICU后留取BALF送检mNGS的时间对重症肺炎患者预后并未发现存在影响,能够为临床诊疗提供更多的思路。 展开更多
关键词 宏基因组二代测序技术 重症肺炎 支气管肺泡灌洗液 病原体检测
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集成式锻炼操预防社区老年人跌倒的效果观察 被引量:1
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作者 谭英葵 林桦 +6 位作者 农冬晖 赖青 高熙 梁胜珍 杨丽妍 施勇 谢先乾 《护理实践与研究》 2025年第1期134-140,共7页
目的探讨集成式锻炼操在预防社区老年人跌倒中的实施效果。方法选取2020年5月—2022年9月南宁市某社区的180名老年人为研究对象,按照组间基本资料具有可比性的原则分为观察组和对照组,各90名,干预期间,对照组1名因个人原因退出研究,观察... 目的探讨集成式锻炼操在预防社区老年人跌倒中的实施效果。方法选取2020年5月—2022年9月南宁市某社区的180名老年人为研究对象,按照组间基本资料具有可比性的原则分为观察组和对照组,各90名,干预期间,对照组1名因个人原因退出研究,观察组1名因突发脑梗死瘫痪、1名患胰腺癌退出研究,最终观察组纳入88名,对照组纳入89名。两组均采用常规个性化药物治疗和预防跌倒指导及宣教,对照组继续原本的生活方式及锻炼习惯,观察组在对照组基础上实施集成式锻炼操预防跌倒。两组老年人入组时、入组3个月、入组6个月、入组12个月采用Morse跌倒评估量表(MFS)、Berg平衡量表(BBS)、日常生活活动能力量表(Barthel指数)评定跌倒风险、平衡能力、日常生活能力,统计两组老年人12个月内累计跌倒发生例数。结果观察组老年人入组时、入组3个月、入组6个月、入组12个月后MFS评分出现逐渐降低的状况,对照组呈现逐渐增高的状况,时间比较差异有统计学意义(P_(时间)<0.05);入组3个月后各时间点观察组老年人MFS评分均低于对照组,组间比较差异有统计学意义(P_(组间)<0.05);且随着观察时间延长,组间差距逐渐增大,交互差异有统计学意义(P_(交互)<0.05)。观察组老年人入组时、入组3个月、入组6个月后BBS评分出现逐渐升高的状况,至12个月评分较6个月稍下降,仍比入组时高;对照组入组时、入组3个月、入组6个月后评分呈现逐渐降低状况,至12个月评分稍升高,时间比较差异有统计学意义(P_(时间)<0.05);入组3个月后各时间点观察组BBS评分均高于对照组,组间比较差异有统计学意义(P_(组间)<0.05);综合来看入组后随着观察时间延长,6个月时差异最大,6个月后差异逐渐减少,交互差异有统计学意义(P_(交互)<0.05)。观察组老年人入组时、入组3个月、入组6个月、入组12个月后Barthel指数出现逐渐升高状况,对照组呈现逐渐降低趋势,时间比较差异有统计学意义(P_(时间)<0.05);各时间点组间比较差异有统计学意义(P_(组间)<0.05);且随着观察时间延长,组间差距逐渐增大,交互差异有统计学意义(P_(交互)<0.05)。观察组老年人在干预12个月跌倒率低于对照组,经比较差异有统计学意义(P<0.05)。结论集成式锻炼操可提高社区老年人的平衡能力及日常生活能力,降低社区老年人跌倒风险,坚持锻炼可减少社区老年人跌倒的发生。 展开更多
关键词 集成式锻炼操 社区 老年人 预防跌倒 日常生活能力 平衡能力
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灵芝多肽提取及冲剂制备工艺研究 被引量:1
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作者 林花 金海强 +5 位作者 姜银姬 金美玉 王婷 金星爱 尹花 车成来 《黑龙江农业科学》 2025年第3期54-60,共7页
为探明超声波辅助酶解法在提取灵芝多肽时的最佳工艺参数,促进灵芝多肽的提取及相应产品的工厂化生产,以多肽提取量为参考指标,进行灵芝多肽的提取及灵芝多肽冲剂制备工艺研究,首先进行单因素试验,随后采用正交试验设计来优化结合超声... 为探明超声波辅助酶解法在提取灵芝多肽时的最佳工艺参数,促进灵芝多肽的提取及相应产品的工厂化生产,以多肽提取量为参考指标,进行灵芝多肽的提取及灵芝多肽冲剂制备工艺研究,首先进行单因素试验,随后采用正交试验设计来优化结合超声波与酶法提取灵芝多肽的工艺条件,并进一步探究灵芝多肽冲剂的配方。结果表明,通过优化确定了灵芝多肽的最佳提取工艺参数,即料液比为1∶50,反应时间为2 h,反应温度为60℃,加酶量为6000 U·g^(-1)。此外,针对灵芝多肽冲剂的配方,也得出了最优比例,糊精占20%,淀粉占25%,柠檬酸占0.3%,蔗糖占6%。 展开更多
关键词 灵芝子实体 活性多肽 酶解法 提取 最佳条件
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不同原料对螺蛳汤风味形成的影响
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作者 刘纯友 丘静 +5 位作者 王书军 殷朝敏 林华 任仙娥 唐湘毅 黄永春 《食品工业科技》 北大核心 2025年第15期103-114,共12页
为探究螺蛳肉、猪骨、鸡架和香辛料等不同原料对螺蛳汤风味形成的影响,采用光谱技术、气相色谱、高效液相色谱和气相色谱-质谱联用技术对螺蛳汤的理化特性和风味成分进行测定。结果表明,不同原料对螺蛳汤中水溶性蛋白含量、颗粒平均粒... 为探究螺蛳肉、猪骨、鸡架和香辛料等不同原料对螺蛳汤风味形成的影响,采用光谱技术、气相色谱、高效液相色谱和气相色谱-质谱联用技术对螺蛳汤的理化特性和风味成分进行测定。结果表明,不同原料对螺蛳汤中水溶性蛋白含量、颗粒平均粒径和聚集度指数有显著影响,但不同原料对螺蛳汤的Zeta电位无显著影响。气相色谱结果显示,猪骨和鸡架是螺蛳汤中油酸、亚油酸、棕榈酸和棕榈油酸的主要来源。GC-MS结果表明,螺蛳汤中共鉴定出35种挥发性风味化合物,包括醛类10种、醇类4种、烯烃11种、烷烃1种、酮类2种、酯类2种、醚类2种、酚类3种。香气活度值显示,茴香脑、草蒿脑、桉叶油醇和壬醛是螺蛳汤中关键挥发性化合物,其中茴香脑和桉叶油醇源自香辛料,而壬醛来自螺蛳肉、猪骨和鸡架,这些挥发性化合物赋予螺蛳汤甜味、樟脑香、油脂味、柑橘香。氨基酸分析结果显示,谷氨酸、天冬氨酸、甘氨酸和丙氨酸等游离氨基酸是螺蛳汤中重要的呈味氨基酸;5’-GMP、5’-AMP和5’-IMP等核苷酸是螺蛳汤中主要的鲜味核苷酸,这些呈味氨基酸和核苷酸共同赋予螺蛳汤鲜甜的滋味特性,而这些滋味物质主要来自螺蛳肉、猪骨和鸡架。综上,动物基肉类原料和植物基香辛料共同构成螺蛳汤的特征香气和滋味。 展开更多
关键词 螺蛳汤 原料 挥发性风味化合物 滋味化合物 气相色谱-质谱联用
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高压流体动静压结合型机械密封空化分析 被引量:2
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作者 张伟政 林华 +3 位作者 张琦璇 黄文彬 韩东民 刘经纬 《液压气动与密封》 2025年第6期62-69,共8页
为探究动静压结合型机械密封对液膜空化的影响,以瑞利台阶-环槽-静压台阶为研究对象,建立三维液膜模型,对比分析了瑞利台阶-环槽与瑞利台阶-环槽-静压台阶两种模型的空化面积及泄漏量,揭示了瑞利台阶-环槽-静压台阶流体动静压结合型机... 为探究动静压结合型机械密封对液膜空化的影响,以瑞利台阶-环槽-静压台阶为研究对象,建立三维液膜模型,对比分析了瑞利台阶-环槽与瑞利台阶-环槽-静压台阶两种模型的空化面积及泄漏量,揭示了瑞利台阶-环槽-静压台阶流体动静压结合型机械密封的密封机理。研究结果表明:瑞利台阶-环槽-静压台阶比瑞利台阶-环槽的空化面积大,且前者泄漏量更小一些。空化区域从反向槽槽根处向槽区延长,空化面积比与气相体积分数随转速的增大而增大,随压力和膜厚的增大而减小。因此,在高压工况下,正反向瑞利台阶-环槽-静压台阶流体动静压结合型机械密封能更好地减小泄漏。 展开更多
关键词 动静压结合型机械密封 高压工况 空化效应 CFD分析
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隐藻在象山港浮游植物群落中的重要性
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作者 王鹏 江志兵 +4 位作者 朱元励 孙振皓 蒋雨露 林华 曾江宁 《应用生态学报》 北大核心 2025年第5期1531-1539,共9页
隐藻是近岸海域重要的浮游植物类群,但在传统显微镜检中往往被忽视。本文利用2021年4季浮游植物与环境因子数据,探究象山港隐藻的时空分布格局及其在浮游植物群落中的重要性。结果表明:象山港隐藻丰度存在显著的季节和空间差异。季节层... 隐藻是近岸海域重要的浮游植物类群,但在传统显微镜检中往往被忽视。本文利用2021年4季浮游植物与环境因子数据,探究象山港隐藻的时空分布格局及其在浮游植物群落中的重要性。结果表明:象山港隐藻丰度存在显著的季节和空间差异。季节层面上,隐藻丰度(cells·mL^(-1))呈夏季(3944)>冬季(2533)>春季(271)>秋季(199)的趋势。空间层面上,隐藻丰度呈港底(2179)>港中(1799)>港口(897)。春、秋季隐藻的优势度(61.7%、43.5%)均超过硅藻(5.7%、32.1%),冬、夏季隐藻是相对丰度(21.9%、22.3%)仅次于硅藻(76.3%、74.5%)的优势类群。相似性百分比分析显示,隐藻对浮游植物群落的季节和空间差异贡献较大(均>11.2%),在象山港浮游植物群落中占据重要地位。广义相加模型显示,隐藻丰度的季节变化主要受温度影响,空间分布主要受盐度和活性磷酸盐的影响,而相对丰度的时空变化主要受温度影响。研究表明,低温、低盐、高活性磷酸盐环境可能更有利于隐藻在象山港生长。 展开更多
关键词 隐藻 浮游植物 象山港 广义相加模型 季节变化 空间分布
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活性氧介导的微纳塑料老化过程:机制、影响因素及环境健康风险
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作者 林华 黄子滔 +5 位作者 俞果 于洪伟 毕家政 陈继焕 孙家君 刘杰 《环境科学研究》 北大核心 2025年第10期2322-2331,共10页
微纳塑料因其广泛分布、难降解性及潜在毒性,成为当前环境研究的热点。活性氧(ROS)可驱动微纳塑料老化并影响其环境行为与生态风险。本文系统综述了ROS的环境来源及其在微纳塑料表面的生成机制、多路径协同老化作用机制,解析了光照波长... 微纳塑料因其广泛分布、难降解性及潜在毒性,成为当前环境研究的热点。活性氧(ROS)可驱动微纳塑料老化并影响其环境行为与生态风险。本文系统综述了ROS的环境来源及其在微纳塑料表面的生成机制、多路径协同老化作用机制,解析了光照波长、氧浓度、聚合物结构等因子对老化过程的调控效应,重点探讨老化微纳塑料在污染物吸附、生物毒性等方面的生态效应,梳理了典型表征技术的应用。结果表明:①ROS广泛来源于自然环境及微纳塑料自身反应过程,能通过光化学反应、生物代谢和化学氧化等机制持续在其表面生成,诱导官能团重构与结构破碎,加速老化进程,并增强其对污染物的吸附能力与生态风险。②ROS通过链式反应引发聚合物分子断裂与官能团转化,呈现多路径协同老化特征,受聚合物结构、光热条件、自由基类型及氧浓度等多因素共同调控,显著改变微纳塑料的理化性质。③微纳塑料老化过程中表面产生的ROS自由基可通过氧化降解、结构重组与能量转移等机制影响有机污染物、药物和重金属的环境行为,并与污染物产生拮抗或协同效应,进一步加剧其生态风险。鉴于此,未来研究应聚焦ROS原位高分辨监测技术的开发与“ROS-微纳塑料-污染物”三元交互机制的深入解析,拓展非光老化条件下ROS生成路径,并构建多环境因子协同调控的老化动力学模型,为微纳塑料环境行为与生态风险评估提供精准支撑。 展开更多
关键词 微纳塑料 活性氧 老化 自由基 交互作用
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纳米铁酸锌改性槟榔纤维对废水中Pb(Ⅱ)的吸附实验
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作者 张伟 林华 +3 位作者 俞果 周欣雨 李珉 董堃 《桂林理工大学学报》 北大核心 2025年第3期394-403,共10页
以槟榔纤维为原料,使用纳米铁酸锌作为改性剂制备纳米铁酸锌改性槟榔纤维,开展了Pb(Ⅱ)的静态吸附实验,探讨了溶液初始pH、吸附剂投加量、吸附时间及吸附温度对Pb(Ⅱ)的吸附性能的影响及其动力学特征。结果表明:在Pb(Ⅱ)的初始浓度为30 ... 以槟榔纤维为原料,使用纳米铁酸锌作为改性剂制备纳米铁酸锌改性槟榔纤维,开展了Pb(Ⅱ)的静态吸附实验,探讨了溶液初始pH、吸附剂投加量、吸附时间及吸附温度对Pb(Ⅱ)的吸附性能的影响及其动力学特征。结果表明:在Pb(Ⅱ)的初始浓度为30 mg/L、pH为6、改性槟榔纤维投加量为75 mg、温度为35℃的条件下,对Pb(Ⅱ)的吸附量为59.40 mg/g。改性槟榔纤维对Pb(Ⅱ)的吸附为不均匀表面的多层吸附,符合准二级动力学模型和Freundlich等温吸附模型。采用SEM-EDS、XRD、FT-IR和XPS进行解析发现,吸附机制可能是纳米铁酸锌的催化作用、改性槟榔纤维CO与Pb(Ⅱ)阳离子之间的金属-π电子相互作用、空隙填充来吸附Pb(Ⅱ),以及在槟榔纤维表面形成Pb—O配合物使得材料能够与Pb(Ⅱ)发生离子交换和表面结合等化学反应。 展开更多
关键词 纳米铁酸锌 改性 槟榔纤维 Pb(Ⅱ) 吸附
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大豆突变体研究进展
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作者 李永一 姜银姬 +5 位作者 丁洪玲 张庆宇 车成来 金学勇 林花 王光达 《大豆科技》 2025年第4期35-39,45,共6页
大豆突变体是研究基因功能的重要基础材料,不同突变体利用价值不同,可作为大豆育种中间材料或直接用于大豆种质资源创制。文章通过介绍大豆突变体及其特性研究进展,旨在为高产优质大豆种质资源创新与新品种选育提供参考。
关键词 大豆 突变体 表型分类 种质资源
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骨质疏松在体检人群中的流行状况及其影响因素分析
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作者 陆丽莹 林华 +2 位作者 罗娓 黄琳秋 廖苑竹 《当代临床医刊》 2025年第6期5-8,共4页
目的分析体检人群中骨质疏松的流行状况及其危险因素,为防治工作提供参考。方法选择2022年1月至2024年12月在我院健康体检中心进行双能X线骨密度检查的健康体检者500例作为研究对象,根据患骨质疏松情况分为患病组(116例)与未患病组(384... 目的分析体检人群中骨质疏松的流行状况及其危险因素,为防治工作提供参考。方法选择2022年1月至2024年12月在我院健康体检中心进行双能X线骨密度检查的健康体检者500例作为研究对象,根据患骨质疏松情况分为患病组(116例)与未患病组(384例),对比分析两组一般资料情况,并将单因素分析中有统计学意义的变量纳入Logistic回归模型,分析导致体检人群出现骨质疏松的独立危险因素。结果500例体检者中,共检出骨质疏松116例(23.20%),患病数由2022年的16例增至2024年的59例,呈逐年上升趋势。单因素分析显示,两组在性别、年龄、文化程度、BMI、身体活动、牛奶饮用、日均日照时长、25-羟维生素D水平及定期体检情况上差异有统计学意义(P<0.05)。多因素Logistic回归分析证实,女性、高龄、低文化程度(小学)、低体重、每日身体活动<2 h、不饮用牛奶、日均日照时长不足、25-羟维生素D水平偏低及不定期健康体检是骨质疏松的独立危险因素(P<0.05)。结论体检人群骨质疏松患病率逐年升高,应重点针对具备上述危险因素的高危群体开展早期筛查与干预。 展开更多
关键词 骨质疏松 体检 流行 危险因素 双能X线骨密度检查
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Unveiling strength-plasticity synergic mechanism of AZ91 alloy during multi-DOF forming
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作者 Fang Chai Xinghui Han +4 位作者 Zhiyuan Ma lin hua Xuan Hu Wuhao Zhuang Fangyan Zheng 《Journal of Materials Science & Technology》 CSCD 2024年第28期80-92,共13页
High performance is of great importance to expand the application of magnesium alloys,and the inherent strength-plasticity synergic mechanism during a specific process should be unveiled.In this paper,a multi-degrees ... High performance is of great importance to expand the application of magnesium alloys,and the inherent strength-plasticity synergic mechanism during a specific process should be unveiled.In this paper,a multi-degrees of freedom(multi-DOF)forming process is conducted on initially extruded AZ91 magnesium alloy at different deformation degrees,including small deformation with deformation amounts of 10%and 20%,medium deformation with deformation amounts of 30%and 40%,and large deformation with deformation amounts of 60%and 70%.Simultaneous enhancement of ultimate tensile strength(UTS)and plasticity is achieved in all these multi-DOF processed alloys in comparison to the initially extruded one.As deformation degrees increase,both UTS and elongation of the multi-DOF processed alloy gradually increase in small and medium deformation and then slightly decrease in large deforma-tion,exhibiting a superior strength(401 MPa)and plasticity(16.3%)combination at deformation amount of 40%.The evolution of mechanical properties varying with deformation degrees is closely dependent on microstructure and texture characterization.The microstructures of multi-DOF processed AZ91 alloy are increasingly refined and heterogeneous as deformation degrees gradually increase,which consist of the predominant equiaxed coarse grains(CGs)and a few fine grains(FGs)in small deformation,some CGs(equiaxed or slightly elongated)and some FGs in medium deformation,and some remarkably elongated CGs and the predominant FGs in large deformation.The area fraction of basal texture gradually decreases while that of prismatic texture gradually increases with increasing deformation degrees,finally resulting in a complete disappearance of basal texture at a deformation amount of 70%.Thus,the strength-plasticity synergic mechanism related to increasingly obvious heterogeneous structure,gradually refined microstructure,and gradually decreased basal texture contribute to the constantly simultaneous improvement of UTS and plasticity until in medium deformation,and the remarkably elongated CGs play a significant role in the slight decrease of UTS and plasticity in large deformation even with further increasing grain refinement and decreasing basal texture.This research provides an efficient and novel way to achieve strength-plasticity synergic magnesium alloy via optimizing microstructure and texture. 展开更多
关键词 AZ91 magnesium alloy Multi-degrees of freedom forming Strength-plasticity synergic mechanism MICROSTRUCTURE TEXTURE
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Strength-plasticity matching regulation of cold rotary forged Al5A06 sheets by annealing treatment and its influence on fatigue property
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作者 Xuan Hu Xinghui Han +5 位作者 lin hua Fang Chai Wuhao Zhuang Fangyan Zheng Fei Yin Xiaokai Wang 《Journal of Materials Science & Technology》 CSCD 2024年第25期123-148,共26页
Al5A06 sheets by large cold plastic deformation usually have high strength but low plasticity,i.e.weak strength-plasticity matching,which may lead to their poor fatigue property.In this study,annealing treat-ments are... Al5A06 sheets by large cold plastic deformation usually have high strength but low plasticity,i.e.weak strength-plasticity matching,which may lead to their poor fatigue property.In this study,annealing treat-ments are applied on cold rotary forged Al5A06 sheets to regulate strength-plasticity matching and im-prove fatigue properties.The microstructures,tensile mechanical properties and fatigue properties un-der different annealing parameters were analyzed.The abnormal grain growth mechanism of cold rotary forged Al5A06 sheets during 300℃ annealing treatment was investigated,and the fatigue failure mech-anism of Al5A06 sheets with different annealing temperatures was also investigated.The abnormal grain growth during 300℃ annealing treatment is mainly due to the asynchronous recrystallization behavior with low recrystallization driving force,which leads to the early recrystallized regions directly absorb-ing adjacent grains along134crystal direction.The cold rotary forged Al5A06 sheets after 250℃-2 h annealing treatment exhibit the best fatigue property,which is mainly because the optimum strength-plasticity matching brings about coordinate plastic deformation throughout most grains,and the effective dislocation movement between adjacent grains can delay the appearance of strain localization and ac-commodate continuous fatigue cyclic loading. 展开更多
关键词 Al5A06 sheets Cold rotary forging Annealing treatment Strength-plasticity matching Fatigue property
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浙西北常绿阔叶林与针叶林物种多样性及其与土壤理化性质的关系研究
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作者 赖江 叶柳欣 +3 位作者 黄颖磊 林华 蔡文龙 胡飞 《浙江林业科技》 2025年第4期25-32,共8页
为探究不同森林物种多样性及其与土壤理化性质的关系,采用典型样地法研究建德市林业总场常绿阔叶林、针叶林的物种多样性和土壤理化性质。结果表明,常绿阔叶林乔木层木本植物共有65种,是针叶林的2.95倍,林下灌木、草本植物分别有62种、1... 为探究不同森林物种多样性及其与土壤理化性质的关系,采用典型样地法研究建德市林业总场常绿阔叶林、针叶林的物种多样性和土壤理化性质。结果表明,常绿阔叶林乔木层木本植物共有65种,是针叶林的2.95倍,林下灌木、草本植物分别有62种、17种,分别占针叶林下灌木、草本植物总种数的72.9%、56.7%。乔木层的物种丰富度指数、Simpson指数、 Shannon指数和Pielou指数均表现为常绿阔叶林显著大于针叶林(P<0.05);针叶林下草本层物种丰富度指数显著高于常绿阔叶林(P<0.05);常绿阔叶林土壤有机碳、全氮含量显著高于针叶林(P<0.05)。乔木层物种丰富度、Simpson指数和土壤容重具有显著负相关(P<0.05),和土壤总孔隙度具有显著正相关(P<0.05);乔木层物种丰富度和土壤全碳、总氮含量呈显著正相关(P<0.05);乔木层Shannon指数、Pielou指数和总氮含量具有显著正相关(P<0.05);草本层的.Shannon指数、Pielou指数与土壤pH呈现显著正相关(P<0.05)。灌木层的4个物种多样性指数在2种森林间没有显著性差异(P>0.05),与土壤理化性质间的相关性也没有达到显著水平(P>0.05)。今后在森林经营中优先保育现有常绿阔叶林,而对针叶林则实施适度疏伐。 展开更多
关键词 常绿阔叶林 针叶林 物种多样性 土壤理化性质 相关性
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新型文化业态视域下贵州文旅体融合发展研究——以红色题材微短剧创作为例
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作者 林华 曹先东 《合肥师范学院学报》 2025年第6期28-32,共5页
在新型文化业态蓬勃发展背景下,文旅体融合成为推动区域经济与文化传播的重要路径。红色微短剧的创作不仅是红色文化的现代表达,更是构建“以文塑旅、以旅彰文、以体促旅”新业态的有效抓手。基于此,文章聚焦于红色题材微短剧这一新兴... 在新型文化业态蓬勃发展背景下,文旅体融合成为推动区域经济与文化传播的重要路径。红色微短剧的创作不仅是红色文化的现代表达,更是构建“以文塑旅、以旅彰文、以体促旅”新业态的有效抓手。基于此,文章聚焦于红色题材微短剧这一新兴文化形态,分析新型文化业态视域下贵州文旅体融合发展现状,探索新型文化业态视域下贵州文旅体融合实践路径及其发展态势,为提升贵州文旅品牌影响力、促进贵州高质量发展提供借鉴。 展开更多
关键词 新型文化业态 微短剧 贵州红色文化 文旅体融合
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