The stability of the tribological properties of polymer coatings is vital to ensure their long term use.The superlubricity of the poly(vinylphosphonic acid) (PVPA)-modified Ti6A14V/polytetrafluoroethylene (PTFE)interf...The stability of the tribological properties of polymer coatings is vital to ensure their long term use.The superlubricity of the poly(vinylphosphonic acid) (PVPA)-modified Ti6A14V/polytetrafluoroethylene (PTFE)interface can be obtained when lubricated by phosphate-buffered saline (PBS,pH =7.2),but not when lubricated by deionized water and ethanol.Therefore,the mechanisms for the superlubricity of PVPA coatings affected by lubricant were investigated in detail.The stability of the PVPA coatings and their compatibility with the lubricant are critical factors in realizing ideal tribological properties of PVPA coatings.Robust PVPA coatings are stable under a wide range of pH values (6-10) using PBS as the basic solution,and are also characterized by superlubricity.The hydrolysis kinetics of phosphate anhydride is the main reason for the pH responses.In addition,along with stability,PVPA coatings exhibit different friction coefficients in salt solutions which are composed of various ions,which indicates that the compatibility between PVPA coatings and the lubricant can be used to regulate the superlubricity properties.Based on a fundamental understanding of the mechanism of surperlubricity by considering the effects of the lubricant,PVPA coatings with stability and perfect tribological performance are expected to be applied in more aspects.展开更多
基金The authors also appreciate the funding supported by the Beijing Natural Science Foundation，the Tribology Science Fund of State Key Laboratory of Tribology，as well as the National Natural Science Foundation of China
文摘The stability of the tribological properties of polymer coatings is vital to ensure their long term use.The superlubricity of the poly(vinylphosphonic acid) (PVPA)-modified Ti6A14V/polytetrafluoroethylene (PTFE)interface can be obtained when lubricated by phosphate-buffered saline (PBS,pH =7.2),but not when lubricated by deionized water and ethanol.Therefore,the mechanisms for the superlubricity of PVPA coatings affected by lubricant were investigated in detail.The stability of the PVPA coatings and their compatibility with the lubricant are critical factors in realizing ideal tribological properties of PVPA coatings.Robust PVPA coatings are stable under a wide range of pH values (6-10) using PBS as the basic solution,and are also characterized by superlubricity.The hydrolysis kinetics of phosphate anhydride is the main reason for the pH responses.In addition,along with stability,PVPA coatings exhibit different friction coefficients in salt solutions which are composed of various ions,which indicates that the compatibility between PVPA coatings and the lubricant can be used to regulate the superlubricity properties.Based on a fundamental understanding of the mechanism of surperlubricity by considering the effects of the lubricant,PVPA coatings with stability and perfect tribological performance are expected to be applied in more aspects.
