The scratching mechanism of polycrystallineγ-TiAl alloy was investigated at the atomic scale using the molecular dynamics method,with a focus on the influence of different grain sizes.The analysis encompassed tribolo...The scratching mechanism of polycrystallineγ-TiAl alloy was investigated at the atomic scale using the molecular dynamics method,with a focus on the influence of different grain sizes.The analysis encompassed tribological characteristics,scratch morphology,subsurface defect distribution,temperature variations,and stress states during the scratching process.The findings indicate that the scratch force,number of recovered atoms,and pile-up height exhibit abrupt changes when the critical size is 9.41 nm due to the influence of the inverse Hall-Petch effect.Variations in the number of grain boundaries and randomness of grain orientation result in different accumulation patterns on the scratch surface.Notably,single crystal materials and those with 3.73 nm in grain size display more regular surface morphology.Furthermore,smaller grain size leads to an increase in average coefficient of friction,removed atoms number,and wear rate.While it also causes higher temperatures with a larger range of distributions.Due to the barrier effect of grain boundaries,smaller grains exhibit reduced microscopic defects.Additionally,average von Mises stress and hydrostatic compressive stress at the indenter tip decrease as grain size decreases owing to grain boundary obstruction.展开更多
A continuous terrestrial succession was recovered from the Songke-2(SK-2)borehole in the Songliao Basin,Northeastern China.This borehole provides a unique material for further research on the continental paleoclimate ...A continuous terrestrial succession was recovered from the Songke-2(SK-2)borehole in the Songliao Basin,Northeastern China.This borehole provides a unique material for further research on the continental paleoclimate during Cretaceous greenhouse period,following a series of achievements of the Songke-1(SK-1)core.In this study,thorium(Th)logging data were chosen as a paleoclimate proxy to conduct a detailed cyclostratigraphic analysis.The Th series varies quasi-periodically;power spectra and evolutionary fast Fourier transformation(FFT)analysis reveal significant cycles in the Quantou(K2 q),Qingshankou(K2 qn),Yaojia(K2 y)and Nenjiang(K2 n)formations.The ratio of cycle wavelengths in these stratigraphic units is approximately 20:5:2:1,corresponding to long orbital eccentricity(405 kyr),short orbital eccentricity(100 kyr),obliquity(37 kyr),and precession cycles(22.5 kyr and 18.4 kyr).The durations of the K2 n,K2 y,K2 qn and K2 q are estimated as 6.97,1.83,5.30 and 4.52 Myr,respectively,based on the constructed^18.62 Myr"floating"astronomical time scale(ATS).Comparison of the durations between the SK-1 s and SK-2 boreholes exhibits a slight difference of 0.06 Myr and 0.459 Myr for K2 qn and K2 y.Nevertheless,our ATS of K2 n supports the chronostratigraphic frame constructed by the CA-ID-TIMS data of the SK-1 s borehole.This new"floating"ATS provides precise numerical ages for stratigraphic boundaries,biozones and geological events in the Songliao Basin,and can serve as a basis for correlation of strata and events between marine and terrestrial systems.展开更多
Magnetic susceptibility(MS)data were obtained from 11 sections of the Doushantuo(Edicaran)cap carbonate that directly overlies the Nantuo glacial diamictite in the southeastern margin of the Yangtze plat-form.The MS d...Magnetic susceptibility(MS)data were obtained from 11 sections of the Doushantuo(Edicaran)cap carbonate that directly overlies the Nantuo glacial diamictite in the southeastern margin of the Yangtze plat-form.The MS data revealed two regionally correlatable peaks at the bottom and top of the cap carbonate,sepa-rated by an interval of low values.The lower MS peak coincides with high percentage of insoluble siliciclastic residues that are compositionally identical to the matrix of the underlying diamictite,suggesting its origin con-trolled mainly by detrital components during the first phase of cap carbonate deposition at the end of the glacia-tion.The upper MS peak is associated with high clay content and iron sulfides,and can be interpreted as either derived from enhanced greenhouse weathering that could have brought more terrigenous components into the ocean,or the result of ocean anoxia at the late stage of cap carbonate deposition that could led to formation of abundant iron sulfides.The regionally consistent MS curves from the cap carbonates provided the first geo-physical record for the rapid climate change from icehouse to greenhouse conditions in the aftermath of the Neoproterozoic“snowball Earth”event.展开更多
A detailed paleomagnetic and rock-magnetic investigation spanning loess L7 to paleosol S8 has been carried out at the Baoji and Xifeng sections. Results of anisotropy of magnetic susceptibility confirm that the studie...A detailed paleomagnetic and rock-magnetic investigation spanning loess L7 to paleosol S8 has been carried out at the Baoji and Xifeng sections. Results of anisotropy of magnetic susceptibility confirm that the studied loess-paleosol sediments retain primary sedimentary fabrics. Stepwise thermal demagnetization shows that two well-defined magnetization components can be isolated from both loess and paleosol specimens. A low-temperature component, isolated between 100°C and 200°C, is consistent with the present geomagnetic field direction, and a high-temperature component, isolated between 200-300°C and 620-680°C, includes clearly normal and reversed polarities. Isothermal remanent magnetization and thermomagnetic analyses indicate that characteristic remanent magnetization is mainly carried by magnetite and hematite. The Day plot, together with the stratigraphic variations of rock-magnetic parameters, shows that the uniformity of magnetic mineralogy and grain size fulfills the criteria for relative paleointensity （RPI） studies. RPI records have been constructed using natural remanent magnetization （NRM） intensity after thermal demagnetization at 300°C normalized by low-frequency magnetic susceptibility （NRM 300 /χ）. The results show that the RPI record from the Baoji section, where pedogenesis is quite weak, is compatible with the stacked PISO-1500 paleointensity record, suggesting that it might reflect the paleointensity variation of the geomagnetic field. The RPI record from the Xifeng section, where pedogenesis is rather strong, indicates a clear dissimilarity with the stacked PISO-1500 paleointensity record, implying that it does not reflect the paleointensity variation of the geomagnetic field. Our new results show that the NRM 300 /χ from the strongly pedogenetic paleosols does not completely eliminate the pedogenetic （climatic） influence, so it might be unsuitable for a reliable paleointensity study.展开更多
基金National Natural Science Foundation of China(52065036,52365018)Natural Science Foundation of Gansu(23JRRA760)+1 种基金Hongliu Outstanding Youth Foundation of Lanzhou University of TechnologyChina Postdoctoral Science Foundation(2023M733583)。
文摘The scratching mechanism of polycrystallineγ-TiAl alloy was investigated at the atomic scale using the molecular dynamics method,with a focus on the influence of different grain sizes.The analysis encompassed tribological characteristics,scratch morphology,subsurface defect distribution,temperature variations,and stress states during the scratching process.The findings indicate that the scratch force,number of recovered atoms,and pile-up height exhibit abrupt changes when the critical size is 9.41 nm due to the influence of the inverse Hall-Petch effect.Variations in the number of grain boundaries and randomness of grain orientation result in different accumulation patterns on the scratch surface.Notably,single crystal materials and those with 3.73 nm in grain size display more regular surface morphology.Furthermore,smaller grain size leads to an increase in average coefficient of friction,removed atoms number,and wear rate.While it also causes higher temperatures with a larger range of distributions.Due to the barrier effect of grain boundaries,smaller grains exhibit reduced microscopic defects.Additionally,average von Mises stress and hydrostatic compressive stress at the indenter tip decrease as grain size decreases owing to grain boundary obstruction.
基金supported by the National Natural Science Foundation of China(41790451,41925010,and 41688103)National Key R&D Program of China(2019YFC0605403)the subject development project of RIPED(yjkt2019-3).
文摘A continuous terrestrial succession was recovered from the Songke-2(SK-2)borehole in the Songliao Basin,Northeastern China.This borehole provides a unique material for further research on the continental paleoclimate during Cretaceous greenhouse period,following a series of achievements of the Songke-1(SK-1)core.In this study,thorium(Th)logging data were chosen as a paleoclimate proxy to conduct a detailed cyclostratigraphic analysis.The Th series varies quasi-periodically;power spectra and evolutionary fast Fourier transformation(FFT)analysis reveal significant cycles in the Quantou(K2 q),Qingshankou(K2 qn),Yaojia(K2 y)and Nenjiang(K2 n)formations.The ratio of cycle wavelengths in these stratigraphic units is approximately 20:5:2:1,corresponding to long orbital eccentricity(405 kyr),short orbital eccentricity(100 kyr),obliquity(37 kyr),and precession cycles(22.5 kyr and 18.4 kyr).The durations of the K2 n,K2 y,K2 qn and K2 q are estimated as 6.97,1.83,5.30 and 4.52 Myr,respectively,based on the constructed^18.62 Myr"floating"astronomical time scale(ATS).Comparison of the durations between the SK-1 s and SK-2 boreholes exhibits a slight difference of 0.06 Myr and 0.459 Myr for K2 qn and K2 y.Nevertheless,our ATS of K2 n supports the chronostratigraphic frame constructed by the CA-ID-TIMS data of the SK-1 s borehole.This new"floating"ATS provides precise numerical ages for stratigraphic boundaries,biozones and geological events in the Songliao Basin,and can serve as a basis for correlation of strata and events between marine and terrestrial systems.
基金This work was supported by the National Natural Science Foundation(Grant No.40032010B)
文摘Magnetic susceptibility(MS)data were obtained from 11 sections of the Doushantuo(Edicaran)cap carbonate that directly overlies the Nantuo glacial diamictite in the southeastern margin of the Yangtze plat-form.The MS data revealed two regionally correlatable peaks at the bottom and top of the cap carbonate,sepa-rated by an interval of low values.The lower MS peak coincides with high percentage of insoluble siliciclastic residues that are compositionally identical to the matrix of the underlying diamictite,suggesting its origin con-trolled mainly by detrital components during the first phase of cap carbonate deposition at the end of the glacia-tion.The upper MS peak is associated with high clay content and iron sulfides,and can be interpreted as either derived from enhanced greenhouse weathering that could have brought more terrigenous components into the ocean,or the result of ocean anoxia at the late stage of cap carbonate deposition that could led to formation of abundant iron sulfides.The regionally consistent MS curves from the cap carbonates provided the first geo-physical record for the rapid climate change from icehouse to greenhouse conditions in the aftermath of the Neoproterozoic“snowball Earth”event.
基金supported by the National Natural Science Foundation of China (no. 41172038)the Programfor New Century Excellent Talents in University (no.NCET-11-0720)+2 种基金the Fundamental Research Funds for the Central Universities (no. 2010ZD05, 2011YXL010)the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education MinistryApart of this study was performed under the cooperative research program of CMCR (no. 07A017, 08A001)
文摘A detailed paleomagnetic and rock-magnetic investigation spanning loess L7 to paleosol S8 has been carried out at the Baoji and Xifeng sections. Results of anisotropy of magnetic susceptibility confirm that the studied loess-paleosol sediments retain primary sedimentary fabrics. Stepwise thermal demagnetization shows that two well-defined magnetization components can be isolated from both loess and paleosol specimens. A low-temperature component, isolated between 100°C and 200°C, is consistent with the present geomagnetic field direction, and a high-temperature component, isolated between 200-300°C and 620-680°C, includes clearly normal and reversed polarities. Isothermal remanent magnetization and thermomagnetic analyses indicate that characteristic remanent magnetization is mainly carried by magnetite and hematite. The Day plot, together with the stratigraphic variations of rock-magnetic parameters, shows that the uniformity of magnetic mineralogy and grain size fulfills the criteria for relative paleointensity （RPI） studies. RPI records have been constructed using natural remanent magnetization （NRM） intensity after thermal demagnetization at 300°C normalized by low-frequency magnetic susceptibility （NRM 300 /χ）. The results show that the RPI record from the Baoji section, where pedogenesis is quite weak, is compatible with the stacked PISO-1500 paleointensity record, suggesting that it might reflect the paleointensity variation of the geomagnetic field. The RPI record from the Xifeng section, where pedogenesis is rather strong, indicates a clear dissimilarity with the stacked PISO-1500 paleointensity record, implying that it does not reflect the paleointensity variation of the geomagnetic field. Our new results show that the NRM 300 /χ from the strongly pedogenetic paleosols does not completely eliminate the pedogenetic （climatic） influence, so it might be unsuitable for a reliable paleointensity study.
