The Dachang superlarge Sn-polymetal deposit in Guangxi, China, is one of the largest tin deposit all over the world. However, this deposit has long been in debate as to its origin. One of the opinions is that the Dach...The Dachang superlarge Sn-polymetal deposit in Guangxi, China, is one of the largest tin deposit all over the world. However, this deposit has long been in debate as to its origin. One of the opinions is that the Dachang deposit was formed by replacement of hydrothermal solution originating from Yanshanian granites, and the other is that this deposit was formed by submarine exhalation in the Devonian. This paper presents some new isotopic geochronology data obtained with the 40Ar-39Ar method for quartz and sanidine from massive ore in the No. 91 and No. 100 orebodies. Analytic results show that the No. 91 orebody was formed at 94.52±0.33 Ma (the plateau age obtained with the 40Ar-39Ar method for quartz) or 91.4±2.9 Ma (the plateau age obtained with the 40Ar-39Ar method for feldspar), while the No. 100 orebody was formed at 94.56±0.45 Ma (the plateau age obtained with the 40Ar-39Ar method for quartz), suggesting that both the No. 91 and the No. 100 orebodies were formed at the Late Yanshanian instead of the Devonian. The No. 100 orebody might be formed by filling of ore materials into caves in Devonian reef limestone. Because the ore-bearing solution released its pressure and lowered its temperature suddenly in a cave environment, ore minerals were formed concentratedly while water and other materials such as CO2 evaporated quickly, resulting less alteration of host rocks.展开更多
Lead isotopic analytic data of 30 ores gathered from the Zhuanmiao boron deposit, Wengquangou boron (iron) deposit and its Dongtaizi Ore Member constitute three isochrons, the corresponding ages of which are 1902 ...Lead isotopic analytic data of 30 ores gathered from the Zhuanmiao boron deposit, Wengquangou boron (iron) deposit and its Dongtaizi Ore Member constitute three isochrons, the corresponding ages of which are 1902 ± 12 Ma, 1852 ± 9 Ma and 1917 ± 48 Ma. Lead isotopic analyses of marble from the Xiquegou Member of the Qingchenzi orefield yield a Pb-Pb isochron age of 1844 ± 27 Ma. 40Ar-39Ar quick neutron activation dating of phlogopites and microclines coexisting with ore minerals in the Wengquangou boron (iron) and Zhuanmiao boron deposits shows that: (1) the phlogopite from the Wengquangou has a plateau age of 1923 ± 1.5 Ma and an isochron age of 1924 ± 2.5 Ma; (2) the microcline from the Wengquangou has the plateau age of 1407 ± 5.4 Ma and 220 ± 12 Ma and an isochron age of 1403 ± 19 Ma; (3) the phlogopites from the Zhuanmiao yield a plateau age 1918 ± 1.3 Ma and an isochron age of 1918 ± 2.9 Ma; (4) the microclines from the Zhuanmiao yield the plateau age of 1420 ± 16 Ma and 250 ± 8 Ma and an isochron age of 1425 ± 19 Ma and 269 ± 16 Ma. These ages indicate that the eastern Liaoning area happened around 1900 Ma, an important tectonomagmatic event, which is consistent with the worldwide Mid-Proterozoic tectonomagmatic event. During this period, the Proterozoic Liaohe Group was folded and underwent strong normal metamorphism, and the (hydrothermal) sedimentary boron deposits (or source beds) formed earlier were strongly superimposed by mineralization, resulting in enrichment of boron; later regional geological processes made little contribution to the formation of the boron deposits. Lead isotopic components show that the U-Pb and Th-Pb isotopic system reached homogenization in the ores whereas only the U-Pb isotopic system reached homogenization in the marble from the Xiquegou district, which indicates that the boron deposits superimposed in the studied area endured a relatively strong process of hydrothermal migmatization during the end phase of early Proterozoic metamorphism.展开更多
基金the State Key BasicResearch Program ofChina(TG1999043203 ,TG1999043201) the Geological Survey Program(K1.4-3-4)under the Ministry of Land and Resources.
文摘The Dachang superlarge Sn-polymetal deposit in Guangxi, China, is one of the largest tin deposit all over the world. However, this deposit has long been in debate as to its origin. One of the opinions is that the Dachang deposit was formed by replacement of hydrothermal solution originating from Yanshanian granites, and the other is that this deposit was formed by submarine exhalation in the Devonian. This paper presents some new isotopic geochronology data obtained with the 40Ar-39Ar method for quartz and sanidine from massive ore in the No. 91 and No. 100 orebodies. Analytic results show that the No. 91 orebody was formed at 94.52±0.33 Ma (the plateau age obtained with the 40Ar-39Ar method for quartz) or 91.4±2.9 Ma (the plateau age obtained with the 40Ar-39Ar method for feldspar), while the No. 100 orebody was formed at 94.56±0.45 Ma (the plateau age obtained with the 40Ar-39Ar method for quartz), suggesting that both the No. 91 and the No. 100 orebodies were formed at the Late Yanshanian instead of the Devonian. The No. 100 orebody might be formed by filling of ore materials into caves in Devonian reef limestone. Because the ore-bearing solution released its pressure and lowered its temperature suddenly in a cave environment, ore minerals were formed concentratedly while water and other materials such as CO2 evaporated quickly, resulting less alteration of host rocks.
基金supported by the National 973 Project of China(G1999043201)
文摘Lead isotopic analytic data of 30 ores gathered from the Zhuanmiao boron deposit, Wengquangou boron (iron) deposit and its Dongtaizi Ore Member constitute three isochrons, the corresponding ages of which are 1902 ± 12 Ma, 1852 ± 9 Ma and 1917 ± 48 Ma. Lead isotopic analyses of marble from the Xiquegou Member of the Qingchenzi orefield yield a Pb-Pb isochron age of 1844 ± 27 Ma. 40Ar-39Ar quick neutron activation dating of phlogopites and microclines coexisting with ore minerals in the Wengquangou boron (iron) and Zhuanmiao boron deposits shows that: (1) the phlogopite from the Wengquangou has a plateau age of 1923 ± 1.5 Ma and an isochron age of 1924 ± 2.5 Ma; (2) the microcline from the Wengquangou has the plateau age of 1407 ± 5.4 Ma and 220 ± 12 Ma and an isochron age of 1403 ± 19 Ma; (3) the phlogopites from the Zhuanmiao yield a plateau age 1918 ± 1.3 Ma and an isochron age of 1918 ± 2.9 Ma; (4) the microclines from the Zhuanmiao yield the plateau age of 1420 ± 16 Ma and 250 ± 8 Ma and an isochron age of 1425 ± 19 Ma and 269 ± 16 Ma. These ages indicate that the eastern Liaoning area happened around 1900 Ma, an important tectonomagmatic event, which is consistent with the worldwide Mid-Proterozoic tectonomagmatic event. During this period, the Proterozoic Liaohe Group was folded and underwent strong normal metamorphism, and the (hydrothermal) sedimentary boron deposits (or source beds) formed earlier were strongly superimposed by mineralization, resulting in enrichment of boron; later regional geological processes made little contribution to the formation of the boron deposits. Lead isotopic components show that the U-Pb and Th-Pb isotopic system reached homogenization in the ores whereas only the U-Pb isotopic system reached homogenization in the marble from the Xiquegou district, which indicates that the boron deposits superimposed in the studied area endured a relatively strong process of hydrothermal migmatization during the end phase of early Proterozoic metamorphism.