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1-丁烯/丙烯共聚物的合成及结晶行为
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作者 娄昱星 杜改平 +1 位作者 陈明 陈江波 《石油化工》 CAS CSCD 北大核心 2024年第9期1281-1287,共7页
使用最新开发的负载型Ziegler-Natta催化剂合成1-丁烯/丙烯共聚物,催化剂活性可达9 kg/(g·h)以上。采用13C NMR,IR,XRD,DSC等方法对所得共聚物的组成、链结构和结晶行为进行表征。实验结果表明,1-丁烯/丙烯共聚物中连续排列的丙烯... 使用最新开发的负载型Ziegler-Natta催化剂合成1-丁烯/丙烯共聚物,催化剂活性可达9 kg/(g·h)以上。采用13C NMR,IR,XRD,DSC等方法对所得共聚物的组成、链结构和结晶行为进行表征。实验结果表明,1-丁烯/丙烯共聚物中连续排列的丙烯单元结构含量少,IR谱图和XRD谱图中未出现聚丙烯晶体对应的特征峰,表明丙烯很好地参与了共聚反应;^(13)C NMR谱图分析计算结果表明,共聚物中丙烯含量为3.3%~18.9%(x)。在实验条件范围内,共聚单体丙烯的引入可加速共聚物由晶型Ⅱ向晶型Ⅰ转变,当丙烯含量不低于7.8%(x)时,晶型Ⅱ在48 h内基本转变为晶型Ⅰ(占比不低于96.2%);当丙烯含量不低于12.6%(x)时,晶型Ⅱ在24 h内基本转变为晶型Ⅰ(占比不低于96.1%)。 展开更多
关键词 1-丁烯 丙烯 共聚 结晶行为
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地质调查成果信息化建设方法探索--基于数字填图技术 被引量:10
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作者 杨星辰 叶梦旎 +4 位作者 叶培盛 蔡茂堂 娄玉行 张绪教 刘浩 《地质力学学报》 CSCD 2020年第2期263-270,共8页
地质调查项目信息化建设是实现地质调查有效服务国家生态文明建设重大需求的支撑体系之一。数字填图技术是地质调查项目信息化建设中的关键技术,使得野外数据采集、数据处理、成果输出等全流程信息化得以实现。文章针对地质调查项目信... 地质调查项目信息化建设是实现地质调查有效服务国家生态文明建设重大需求的支撑体系之一。数字填图技术是地质调查项目信息化建设中的关键技术,使得野外数据采集、数据处理、成果输出等全流程信息化得以实现。文章针对地质调查项目信息化建设过程中的技术难点,应用最新的数字填图系统平台,总结出一套简明实用的地质调查项目信息化建设方法:首先,优选符合地质调查精度要求的数据源,并采用2000国家大地坐标系;而后,运用数字填图技术系统中DGSGIS工具下载、配准所选取数据源影像作为地理底图;最后,使用数字填图系统建设完成地质调查项目空间数据库。该方法技术流程简洁、实用性强,对地质调查项目信息化建设具有一定指导意义。 展开更多
关键词 信息化建设 数字填图 地理底图 坐标系 地质调查 DGSGIS
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Phase Equilibria of Hornblende-Bearing Eclogite in the Western Dabie Mountain,Central China 被引量:7
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作者 ZHANG Jingsen WEI Chunjing +1 位作者 lou yuxing SU Xiangli 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2009年第1期57-69,共13页
The high-pressure (HP) eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in disp... The high-pressure (HP) eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in dispute. Generally, HP eclogite involves garnet, omphacite, hornblendes and quartz, with or without glaucophane, zoisite and phengite. The garnet has compositional zoning with XMg increase, XCa and XMn decrease from core to rim, which indicates a progressive metamorphism. The phase equilibria of the HP eclogite modeled by the P-T pseudosection method developed recently showed the following: (1) the growth zonation of garnet records a progressive metamorphic PT path from pre-peak condition of 1.9-2.1 GPa at 508~C-514~C to a peak one of 2.3-2.5 GPa at 528~C-531~C for the HP eclogite; (2) the peak mineral assemblage is garnet+omphacite+glaucophane+quartz_+phengite, likely paragenetic with lawsonite; (3) the extensive hornblendes derive mainly from glaucophane, partial omphacite and even a little garnet due to the decompression with some heating during the post-peak stage, mostly representing the conditions of about 1.4-1.6 GPa and 580~C-640~C, and their growth is favored by the dehydration of lawsonite into zoisite or epidote, but most of the garnet, omphacite or phengite in the HP eclogite still preserve their compositions at peak condition, and they are not obviously equilibrious with the hornblendes. 展开更多
关键词 ECLOGITE HORNBLENDE peak P-T condition phase equilibrium PT path western Dabie Mountain
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The Key Influence of Fluid in the Preserves, Mineral Assemblages, Compositionsand Structures: Study from High-Pressure Eclogite and Its Amphibolization in the Western Dabie Mountains,Central China
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作者 lou yuxing ZHANG Cong +1 位作者 WEI Chunjing LIU Xiaochun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第S1期227-,共1页
Pseudosection modeling for the garnet amphibolite samples from the Western Dabie Mountains show they have experienced similar HP metamorphic evolution with that of the adjected eclogites.The common assemblage of
关键词 UHP Compositionsand Structures Mineral Assemblages Study from High-Pressure Eclogite and Its Amphibolization in the Western Dabie Mountains Central China The Key Influence of Fluid in the Preserves
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The Key Influence of Fluid in Metamorphic Rock Preserves, Mineral Assemblages, Compositions and Structures: Study from High-Pressure Eclogite and Its Amphibolization in the Western Dabie Mountains,Central China
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作者 lou yuxing ZHANG Cong +2 位作者 WEI Chunjing LIU Xiaochun WANG W-(RZ) 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第S1期228-230,共3页
The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Z... The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Zhang et al.,2003;and references there in).Field and petrological features suggest that amphibolites should 展开更多
关键词 UHP Mineral Assemblages Study from High-Pressure Eclogite and Its Amphibolization in the Western Dabie Mountains Central China The Key Influence of Fluid in Metamorphic Rock Preserves Compositions and Structures
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亚临床库欣综合征患者ACTH水平异质性及血清DHEAS的诊断价值评估
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作者 赵文霁 杨佳蔚 +5 位作者 娄宇星 张韦 李诗曼 张子为 杨帆 李平 《中华内分泌代谢杂志》 2025年第10期830-836,共7页
目的探究促肾上腺皮质激素(adrenocorticotropic hormone,ACTH)抑制与非抑制的亚临床库欣综合征(subclinical Cushing′s syndrome,SCS)患者临床特征和激素水平变化,评估ACTH影响因素以及血清肾上腺雄激素硫酸脱氢表雄酮(dehydroepiandr... 目的探究促肾上腺皮质激素(adrenocorticotropic hormone,ACTH)抑制与非抑制的亚临床库欣综合征(subclinical Cushing′s syndrome,SCS)患者临床特征和激素水平变化,评估ACTH影响因素以及血清肾上腺雄激素硫酸脱氢表雄酮(dehydroepiandrosterone sulfate,DHEAS)水平在ACTH抑制与非抑制SCS患者中的诊断效率。方法回顾性收集2014年6月至2023年10月在南京大学医学院附属鼓楼医院内分泌科确诊SCS患者的临床资料,最终纳入194例。根据晨8:00血浆ACTH水平,分为ACTH抑制组(ACTH<2.2 pmol/L)及非抑制组(ACTH≥2.2 pmol/L)。同时纳入性别、年龄、体重指数匹配的194例肾上腺无功能瘤(non-functional adrenal tumor,NFA)患者。比较各组临床特征和激素水平。Logistic回归分析SCS患者ACTH水平是否被抑制的影响因素。进一步进行受试者工作特征(receiver operating characteristic,ROC)曲线分析血清DHEAS水平在ACTH抑制与非抑制的SCS患者中的诊断效率。结果ACTH抑制及非抑制组患者超重/肥胖、高血压病、糖代谢异常、骨代谢异常的比例无统计学差异。ACTH非抑制组1 mg-隔夜地塞米松抑制试验(dexamethasone suppression test,DST)血清皮质醇水平低于抑制组,DHEAS水平高于抑制组(均P<0.01)。血清DHEAS诊断ACTH非抑制SCS患者及ACTH抑制SCS患者的ROC曲线下面积分别为0.779(95%CI 0.721~0.837)和0.874(95%CI 0.831~0.918)。以血清DHEAS水平60.0μg/dL为切点,诊断ACTH非抑制SCS患者的灵敏度为66.7%,特异度为76.1%;诊断ACTH抑制SCS患者的灵敏度为84.9%,特异度为75.5%。结论ACTH抑制与非抑制SCS患者代谢特征无明显差异。1 mg-DST血清皮质醇水平是SCS患者ACTH水平是否被抑制的独立影响因素。低水平的DHEAS是诊断SCS的敏感指标,在ACTH非抑制的SCS患者中同样有诊断价值。 展开更多
关键词 亚临床库欣综合征 促肾上腺皮质激素 硫酸脱氢表雄酮
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Confirmation of pelitic granulite in the Altai orogen and its geological significance 被引量:14
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作者 WANG Wei WEI ChunJing +2 位作者 WANG Tao lou yuxing CHU Hang 《Chinese Science Bulletin》 SCIE EI CAS 2009年第14期2543-2548,共6页
The existence of pelitic granulite in the Altai orogen was confirmed for the first time by detailed petrographic research and P-T pseudosection modeling. The pelitic granulite has the assemblage of garnet + cordierite... The existence of pelitic granulite in the Altai orogen was confirmed for the first time by detailed petrographic research and P-T pseudosection modeling. The pelitic granulite has the assemblage of garnet + cordierite + K-feldspar + biotite + sillimanite + plagioclase + quartz with some samples containing the paragenesis of cordierite + spinel. Peak conditions of the pelitic granulite determined from the P-T pseudosection involved P = 0.5―0.6 GPa, T = 780―800℃, belonging to medium-to low-pressure type. SHRIMP U-Pb dating of zircon presented a metamorphic age of 292.8 ± 2.3 Ma. The discovery of pelitic granulite reflects an extensional environment with high heat flow in the southern margin of the Altai orogen during the Early Permian, which provides an important petrological constraint on the evolution of the Altai orogen. 展开更多
关键词 阿尔泰造山带 麻粒岩 泥质 地质意义 SHRIMP 锆石年龄 早二叠世 堇青石
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