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含锗煤烟尘中锗的浸出和精提制备高品位锗精矿 被引量:1
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作者 李海飞 罗波 +3 位作者 罗志军 王绍江 龙汉生 张勇民 《当代化工》 2025年第3期568-574,共7页
以含锗煤烟尘为原料,通过先用NaClO_(3)氧化,再用H_(2)SO_(4)-NH_(4)F混合酸浸出,最后用单宁沉锗的工艺对锗进行富集。最佳浸出工艺条件为:含锗煤烟尘5 g,NaClO_(3)0.2 g,H_(2)O 10 mL,氧化浸提2 h,将NH_(4)F 0.4 g、H_(2)SO_(4)4 mL先... 以含锗煤烟尘为原料,通过先用NaClO_(3)氧化,再用H_(2)SO_(4)-NH_(4)F混合酸浸出,最后用单宁沉锗的工艺对锗进行富集。最佳浸出工艺条件为:含锗煤烟尘5 g,NaClO_(3)0.2 g,H_(2)O 10 mL,氧化浸提2 h,将NH_(4)F 0.4 g、H_(2)SO_(4)4 mL先混合生成HF后,将混合酸加入浸提液中,酸化浸提4 h,过滤,滤渣进行二次提取。此方法锗浸出率为97.6%。对提取液中锗的精提,用提取液中锗计算含量40倍质量比的五倍子单宁与锗形成络合物,精提锗。选用温度为50℃,恒温振荡2 h,产生沉淀,自然沉降30 min,过滤得到单宁锗。经测定,锗的沉淀率为83.3%。单宁锗氧化焙烧处理后,得到锗精矿,锗精矿的品位达到11.4%。沉锗后液中尚有10%~20%的锗未被回收,并有部分单宁在其中,将沉锗后液套用至含锗烟尘的浸出工艺中,浸出液中的锗浓度可提高20.8%。同时降低单宁用量至20倍时,锗的沉淀率可达81.9%。 展开更多
关键词 含锗煤烟尘 五倍子单宁 单宁络合物 单宁沉锗 沉锗后液
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SHRIMP U-Pb zircon age of tuff at the bottom of the Lower Cambrian Niutitang Formation,Zunyi,South China 被引量:23
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作者 ZHOU MingZhong LUO TaiYi +3 位作者 LI ZhengXiang ZHAO Hui long hansheng YANG Yong 《Chinese Science Bulletin》 SCIE EI CAS 2008年第4期576-583,共8页
A SHRIMP U-Pb zircon geochronology study of the tuff at the bottom of the Lower Cambrian Niutitang Formation at Songlin,Zunyi,South China yielded a mean 206Pb/238U age of 518±5 Ma.It is significantly younger than... A SHRIMP U-Pb zircon geochronology study of the tuff at the bottom of the Lower Cambrian Niutitang Formation at Songlin,Zunyi,South China yielded a mean 206Pb/238U age of 518±5 Ma.It is significantly younger than the Re-Os ages of 537―542 Ma for the overlying polymetallic Ni-Mo-PGE-rich layer in the basal Niutitang Formation at Songlin,suggesting that the Re-Os ages might represent that of the original magma chamber for the Ni-Mo-PGE-rich layer rather than the formation age of the strata.The intra-basinal stratigraphic correlation also implies that the absolute age of the Chengjiang biota should be younger than 518±5 Ma.Our new result,together with the SHRIMP U-Pb zircon age for the K-bentonite in the Zhongyicun member of the Zhujiaqing Formation at the Meishucun section,Yunnan Province,provides a temporal constraint for the Lower Cambrian of the Yangtze Platform in South China. 展开更多
关键词 早寒武纪 凝灰岩 中国 合肥 地质年代学
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