In an alkaline 2-propanol solution with 5,10,15,20-tetra(4-methoxyl phenyl) porphyrin iron chloride(TOMPPFeCl) as a catalyst and oxygen as a cheap green oxidant, 2-naphthol was conversed to 2-hydroxy-\{1,4-naphthoquin...In an alkaline 2-propanol solution with 5,10,15,20-tetra(4-methoxyl phenyl) porphyrin iron chloride(TOMPPFeCl) as a catalyst and oxygen as a cheap green oxidant, 2-naphthol was conversed to 2-hydroxy-\{1,4-naphthoquinone(HNQ)\} with a yield of 62.17% and a selectivity of 100%, and the conversion number of TMOPPFeCl catalyst was 8.32/min. The catalytic oxidation products were characterized by means of UV-Vis, IR, GC-MS, ~ 1H NMR and melting point determination. In this catalytic oxidation, the catalytic activity of TMOPPFeCl was researched in detail and the reacting conditions were optimized. A possible reaction mechanism is summarized based on in situ EPR determination.展开更多
In an alkali-methanol solution, both 1- and 2-naphthol can be converted into 2-hydroxy-1,4-naphthoquinone(HNQ) with selectivity more than 95% by H_2O_2 over metalloporphyrin catalyst. The UV-Vis spectra indicate that ...In an alkali-methanol solution, both 1- and 2-naphthol can be converted into 2-hydroxy-1,4-naphthoquinone(HNQ) with selectivity more than 95% by H_2O_2 over metalloporphyrin catalyst. The UV-Vis spectra indicate that a high valence oxygen-ferreous porphyrin intermediate has been produced by addition of an aqueous solution of H_2O_2 into the catalytic system. This intermediate formation rate is influenced by the concentrations of low valence ferrous porphyrin, H_2O_2, and NaOH existing in the system. With the aid of the UV-Vis spectrum varieties, the rate equations and formation rate constants of the intermediate at different temperatures can be determined by changing the original concentration of each reactant. The formation activation energy of this intermediate was also determined by changing temperature.展开更多
Because it has the advantages of high sensitivity, and it is easy to demodulate and convenient to select in FDM system, the coherent optical fiber communication system is much suitable to be used in long distance opt...Because it has the advantages of high sensitivity, and it is easy to demodulate and convenient to select in FDM system, the coherent optical fiber communication system is much suitable to be used in long distance optical communication systems and in optical fiber WANs. There are two major patterns in coherent optical fiber communication: heterodyne and homodyne. Compared with the heterodyne scheme, the homodyne optical fiber communication system has the following advantages: (1) The sensitivity of the homodyne receiver is higher than that of the heterodyne receiver. As we know, the PSK homodyne optical fiber communication system has the highest sensitivity in coherent optical fiber communication systems. So it is much suitable to be used in long distance optical communication systems or in FDM systems. (2) Because the homodyne receiver only uses the baseband to demodulate the transmitted signals, it occupies much narrower frequency domain than the heterodyne receiver does, which makes it more suitable to be used in multichannel systems. (3) The demodulation pattern used in homodyne receiver is much easier than that used in the heterodyne receiver, since it only needs the baseband demodulation. Usually we construct a homodyne receiver with an optical phase locked loop (OPLL). The research of the OPLL began at 1960′s and the study of the homodyne receiver has been made gradually. In 1984, the first homodyne optical fiber communication system was demonstrated in BTRL, in which the signal laser and the local laser were all 1.5 μm He Ne gas lasers, and the OPLL used was a balanced one. In 1989, L.G.Kazovsky demonstrated experimentally a homodyne receiver in Bellcore using two 1.3 μm Nd:YAG lasers as the signal laser and the local laser and also using a balanced OPLL. Because the linewidth of the normal semiconductor laser is too large and its frequency stability is much poorer, it is very difficult to construct a homodyne receiver with the semiconductor lasers. At the end of 1989, the first Dissertation completed Jul. 1992homodyne optical fiber communication system using two 1.5 μm external cavity semiconductor lasers as the signal laser and the local laser, respectively, was finished in AT&T Bell Lab by J. M. Kahn, in which the OPLL was also a balanced one. In China, the research of the homodyne optical fiber communication system was funded by the National Seventh Five Year Program and by the National Natural Science Foundation. The difficulties to construct a homodyne optical fiber communication system are listed as follows: (1) In homodyne communication systems, the signal laser′s frequency should be stable to avoid the penalty of the receiver′s BER and the crosstalk to other channels in a FDM system, and the local laser could be tuned widely and easily to cover all the signal lasers′ frequency domain. Both the signal laser and the local laser should be narrow in linewidth to decrease the influence of the laser′s phase noise on the BER of the receiver. (2) The modulation pattern used should be studied and chosen carefully because the requirements of different kinds of modulation on the laser, the receiver and the channel are different. (3) Since the construction of the linear OPLL (the balanced) and the nonlinear OPLL (the Costas OPLL, or the Decision Driven OPLL) are rather different, their requirements on the linewidths of the lasers are different too, we should study the theory and the construction of the OPLL carefully to select the suitable scheme to realize. (4) In a multichannel system (such as a FDM system), the influence of crosstalk between channels on the homodyne system should be researched carefully. The technology used to stabilize the channel interval should also be studied. In this thesis, the homodyne optical fiber communication system has been theoretically analyzed, the technical difficulties of constructing the system have been studied. Several kinds of external cavity semiconductor laser have been researched experimentally. Compared展开更多
In this paper, a novel prioritized Optical Burst Switching (OCBS) scheme for the next-generation optical Internet is proposed and investigated systematically through theoretical analysis and network simulation. Analys...In this paper, a novel prioritized Optical Burst Switching (OCBS) scheme for the next-generation optical Internet is proposed and investigated systematically through theoretical analysis and network simulation. Analysis shows that the proposed scheme is able to achieve modestly fine traffic differentiation in a simple and easy way. The simulation results agree with the theoretical analysis and they are useful in traffic engineering of optical burst switching networks.展开更多
文摘In an alkaline 2-propanol solution with 5,10,15,20-tetra(4-methoxyl phenyl) porphyrin iron chloride(TOMPPFeCl) as a catalyst and oxygen as a cheap green oxidant, 2-naphthol was conversed to 2-hydroxy-\{1,4-naphthoquinone(HNQ)\} with a yield of 62.17% and a selectivity of 100%, and the conversion number of TMOPPFeCl catalyst was 8.32/min. The catalytic oxidation products were characterized by means of UV-Vis, IR, GC-MS, ~ 1H NMR and melting point determination. In this catalytic oxidation, the catalytic activity of TMOPPFeCl was researched in detail and the reacting conditions were optimized. A possible reaction mechanism is summarized based on in situ EPR determination.
文摘In an alkali-methanol solution, both 1- and 2-naphthol can be converted into 2-hydroxy-1,4-naphthoquinone(HNQ) with selectivity more than 95% by H_2O_2 over metalloporphyrin catalyst. The UV-Vis spectra indicate that a high valence oxygen-ferreous porphyrin intermediate has been produced by addition of an aqueous solution of H_2O_2 into the catalytic system. This intermediate formation rate is influenced by the concentrations of low valence ferrous porphyrin, H_2O_2, and NaOH existing in the system. With the aid of the UV-Vis spectrum varieties, the rate equations and formation rate constants of the intermediate at different temperatures can be determined by changing the original concentration of each reactant. The formation activation energy of this intermediate was also determined by changing temperature.
文摘Because it has the advantages of high sensitivity, and it is easy to demodulate and convenient to select in FDM system, the coherent optical fiber communication system is much suitable to be used in long distance optical communication systems and in optical fiber WANs. There are two major patterns in coherent optical fiber communication: heterodyne and homodyne. Compared with the heterodyne scheme, the homodyne optical fiber communication system has the following advantages: (1) The sensitivity of the homodyne receiver is higher than that of the heterodyne receiver. As we know, the PSK homodyne optical fiber communication system has the highest sensitivity in coherent optical fiber communication systems. So it is much suitable to be used in long distance optical communication systems or in FDM systems. (2) Because the homodyne receiver only uses the baseband to demodulate the transmitted signals, it occupies much narrower frequency domain than the heterodyne receiver does, which makes it more suitable to be used in multichannel systems. (3) The demodulation pattern used in homodyne receiver is much easier than that used in the heterodyne receiver, since it only needs the baseband demodulation. Usually we construct a homodyne receiver with an optical phase locked loop (OPLL). The research of the OPLL began at 1960′s and the study of the homodyne receiver has been made gradually. In 1984, the first homodyne optical fiber communication system was demonstrated in BTRL, in which the signal laser and the local laser were all 1.5 μm He Ne gas lasers, and the OPLL used was a balanced one. In 1989, L.G.Kazovsky demonstrated experimentally a homodyne receiver in Bellcore using two 1.3 μm Nd:YAG lasers as the signal laser and the local laser and also using a balanced OPLL. Because the linewidth of the normal semiconductor laser is too large and its frequency stability is much poorer, it is very difficult to construct a homodyne receiver with the semiconductor lasers. At the end of 1989, the first Dissertation completed Jul. 1992homodyne optical fiber communication system using two 1.5 μm external cavity semiconductor lasers as the signal laser and the local laser, respectively, was finished in AT&T Bell Lab by J. M. Kahn, in which the OPLL was also a balanced one. In China, the research of the homodyne optical fiber communication system was funded by the National Seventh Five Year Program and by the National Natural Science Foundation. The difficulties to construct a homodyne optical fiber communication system are listed as follows: (1) In homodyne communication systems, the signal laser′s frequency should be stable to avoid the penalty of the receiver′s BER and the crosstalk to other channels in a FDM system, and the local laser could be tuned widely and easily to cover all the signal lasers′ frequency domain. Both the signal laser and the local laser should be narrow in linewidth to decrease the influence of the laser′s phase noise on the BER of the receiver. (2) The modulation pattern used should be studied and chosen carefully because the requirements of different kinds of modulation on the laser, the receiver and the channel are different. (3) Since the construction of the linear OPLL (the balanced) and the nonlinear OPLL (the Costas OPLL, or the Decision Driven OPLL) are rather different, their requirements on the linewidths of the lasers are different too, we should study the theory and the construction of the OPLL carefully to select the suitable scheme to realize. (4) In a multichannel system (such as a FDM system), the influence of crosstalk between channels on the homodyne system should be researched carefully. The technology used to stabilize the channel interval should also be studied. In this thesis, the homodyne optical fiber communication system has been theoretically analyzed, the technical difficulties of constructing the system have been studied. Several kinds of external cavity semiconductor laser have been researched experimentally. Compared
文摘In this paper, a novel prioritized Optical Burst Switching (OCBS) scheme for the next-generation optical Internet is proposed and investigated systematically through theoretical analysis and network simulation. Analysis shows that the proposed scheme is able to achieve modestly fine traffic differentiation in a simple and easy way. The simulation results agree with the theoretical analysis and they are useful in traffic engineering of optical burst switching networks.
