Dose inter-comparison studies for Co γ-ray and 10 MeV electron beam irradiation were carried out 60 from July to October in 2002. The purpose of the studies was to check the reliability of the alanine-PE film dosime-...Dose inter-comparison studies for Co γ-ray and 10 MeV electron beam irradiation were carried out 60 from July to October in 2002. The purpose of the studies was to check the reliability of the alanine-PE film dosime- ters made by CIAE, which will be used as transfer standard dosimetry system mainly for electron beam irradiation. The expanded uncertainty of CIAE alanine/EPR dosimetry system was 4.1% for doses not higher than 10 kGy and 5.4% for those above 10 kGy (k=2). CIAE alanine-PE film dosimeters were sent to JAERI, RISO (National Labora- tory in Denmark) and INCT respectively, which were irradiated by Co gamma-rays or electron beams in each labo- 60 ratory. The irradiated dosimeters were then sent back to CIAE for electron paramagnetic resonance (EPR) analysis. The agreements were obtained to be ±1.9% for gamma-ray dose measurement and ±4.3% for electron beam dose measurement, which were all within the combined uncertainty of the reference and CIAE alanine/EPR dosimetry system. Furthermore, the overall mean ratio was found to be 0.995 with 1.8% in the coefficient of variation (CV). The preliminary inter-comparison studies indicated that CIAE film alanine/EPR dosimetry system had the potential to be used as a transfer dosimetry system for high dose measurement.展开更多
Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when...Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when the molar ratio of the reactants was n(ArOH)∶n(NaOH)∶n(ClCH 2CO 2H) =1∶2.5∶1.2 with microwave irradiation power of 640 W for 65—85 s.展开更多
The ^Si and ^1H high-resolution liquid-phase NMR has been used to investigate the hydrolysis process of the tetraethyl orthosilicate(TEOS).^1H-NMR spectroscopy shows that the hydrolysis of TEOS in TPA is faster than i...The ^Si and ^1H high-resolution liquid-phase NMR has been used to investigate the hydrolysis process of the tetraethyl orthosilicate(TEOS).^1H-NMR spectroscopy shows that the hydrolysis of TEOS in TPA is faster than in TEA.The impacts of TPA and TEA on the TOES hydrolysis process and its hydrolyzed product distribution have been observed by ^29Si-NMR respectively.The influences of water and the isopropyl alcohol on hydrolysis have also been diseussed.The presence of TBOT marks an evident differentiation between TPA and TEA for hydrolysis in ^29Si-NMR spectra.展开更多
文摘Dose inter-comparison studies for Co γ-ray and 10 MeV electron beam irradiation were carried out 60 from July to October in 2002. The purpose of the studies was to check the reliability of the alanine-PE film dosime- ters made by CIAE, which will be used as transfer standard dosimetry system mainly for electron beam irradiation. The expanded uncertainty of CIAE alanine/EPR dosimetry system was 4.1% for doses not higher than 10 kGy and 5.4% for those above 10 kGy (k=2). CIAE alanine-PE film dosimeters were sent to JAERI, RISO (National Labora- tory in Denmark) and INCT respectively, which were irradiated by Co gamma-rays or electron beams in each labo- 60 ratory. The irradiated dosimeters were then sent back to CIAE for electron paramagnetic resonance (EPR) analysis. The agreements were obtained to be ±1.9% for gamma-ray dose measurement and ±4.3% for electron beam dose measurement, which were all within the combined uncertainty of the reference and CIAE alanine/EPR dosimetry system. Furthermore, the overall mean ratio was found to be 0.995 with 1.8% in the coefficient of variation (CV). The preliminary inter-comparison studies indicated that CIAE film alanine/EPR dosimetry system had the potential to be used as a transfer dosimetry system for high dose measurement.
文摘Several aryloxy acetic acids were synthesized under microwave irradiation. The factors, which affect the reaction, were investigated and optimized. It was revealed that the best yields(92.7%—97.4%) were obtained when the molar ratio of the reactants was n(ArOH)∶n(NaOH)∶n(ClCH 2CO 2H) =1∶2.5∶1.2 with microwave irradiation power of 640 W for 65—85 s.
文摘The ^Si and ^1H high-resolution liquid-phase NMR has been used to investigate the hydrolysis process of the tetraethyl orthosilicate(TEOS).^1H-NMR spectroscopy shows that the hydrolysis of TEOS in TPA is faster than in TEA.The impacts of TPA and TEA on the TOES hydrolysis process and its hydrolyzed product distribution have been observed by ^29Si-NMR respectively.The influences of water and the isopropyl alcohol on hydrolysis have also been diseussed.The presence of TBOT marks an evident differentiation between TPA and TEA for hydrolysis in ^29Si-NMR spectra.
基金This work was supported by the National Basic Research Program of China(Grant No.2001CB108904)the Hi-Tech Research and Development Program of China(Grant No.2001AA214021).
