One of the strategies to tune current-voltage behaviors in organic diodes is to combine field-induced charge transfer processes with schottky barrier.According to this principle,a rectifying diode with hysteresis effe...One of the strategies to tune current-voltage behaviors in organic diodes is to combine field-induced charge transfer processes with schottky barrier.According to this principle,a rectifying diode with hysteresis effect was fabricated utilizing a hybrid of electroactive polystyrene derivative covalently tethered with electron-donor carbazole moieties and electrostatic linked with electron-acceptor CdTe nanocrystals.Current-voltage characteristics show an electrical switching behavior with some hysteresis is only observed under a negative bias,with three orders of On/Off current ratio.The hybrid material based rectifier exhibits a rectification ratio of six and its maximum rectified output current is about 5 × 10-5 A.The asymmetric switching is interpreted as the result of both field induced charge transfer and schottky barrier,capable of reducing the misreading of cross-bar memory.Meanwhile,chemical doping of CdTe nanocrystals instead of physical blend favor their uniform dispersion in matrix and stable operation of device.展开更多
Triarylboron compounds are significant optoelectronic materials due to their excellent emissive and electron-transport properties,and could be applied in organic light-emitting diodes as emissive and/or electron-trans...Triarylboron compounds are significant optoelectronic materials due to their excellent emissive and electron-transport properties,and could be applied in organic light-emitting diodes as emissive and/or electron-transport layers.Triarylboron compounds have vacant pπorbital and have received increasing interest as fluoride ion and cyanide ion sensors utilizing specific Lewis acid-base interaction.This review summarizes their structural characteristics,optical properties and applications in chemosensors for anions and optoelectronic devices developed in recent years and discusses the problems and prospects.展开更多
基金supported by the National Basic Research Pro-gram of China (973 projeet) (2009CB930600)National Natural Science Foundation of China (Grants 90406021,20704023,60876010,60706017,and 20774043)+3 种基金the Key Project of Chinese Ministry of Education (No. 104246, 208050, 707032, NCET-07-0446)the NSF of Jiangsu Province (Grants BK2008053, 08KJB510013, SJ209003and TJ207035)Research Fund for Postgraduate Innovation Project of Jiangsu Province (No. CX08B_083Z)STITP (No. 2009120)
文摘One of the strategies to tune current-voltage behaviors in organic diodes is to combine field-induced charge transfer processes with schottky barrier.According to this principle,a rectifying diode with hysteresis effect was fabricated utilizing a hybrid of electroactive polystyrene derivative covalently tethered with electron-donor carbazole moieties and electrostatic linked with electron-acceptor CdTe nanocrystals.Current-voltage characteristics show an electrical switching behavior with some hysteresis is only observed under a negative bias,with three orders of On/Off current ratio.The hybrid material based rectifier exhibits a rectification ratio of six and its maximum rectified output current is about 5 × 10-5 A.The asymmetric switching is interpreted as the result of both field induced charge transfer and schottky barrier,capable of reducing the misreading of cross-bar memory.Meanwhile,chemical doping of CdTe nanocrystals instead of physical blend favor their uniform dispersion in matrix and stable operation of device.
基金supported by the National Basic Research Program of China(973 Program,2009CB930601)the National Natural Science Foundation of China(50803028,20804019,20774043&60976019)+6 种基金Program for New Century Excellent Talents in University(NCET-07-0446)Natural Science Foundation of Jiangsu Province of China(BK2009427)Natural Science Fund for Colleges and Universities in Jiangsu Province(08KJD430017)Scientific and Technological Innovation Teams of Colleges and Universities in Jiangsu Province(TJ207035)Scientific and Technological Activities for Returned Personnel in Nanjing City(NJ209001&TJ208027)Nanjing University of Posts and Telecommunications(NY208045&NY207161)Program for Postgraduates Research Innovation of Colleges and Universities in Jiangsu Province(CX09S_011Z)
文摘Triarylboron compounds are significant optoelectronic materials due to their excellent emissive and electron-transport properties,and could be applied in organic light-emitting diodes as emissive and/or electron-transport layers.Triarylboron compounds have vacant pπorbital and have received increasing interest as fluoride ion and cyanide ion sensors utilizing specific Lewis acid-base interaction.This review summarizes their structural characteristics,optical properties and applications in chemosensors for anions and optoelectronic devices developed in recent years and discusses the problems and prospects.
