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SiO_(2)纳米粒子对CO_(2)地质封存页岩盖层突破压力的影响 被引量:1
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作者 李颖 梁浩 +5 位作者 李海涛 周军平 李可 leonhard ganzer 黄天杰 潘若生 《中国石油大学学报(自然科学版)》 北大核心 2025年第3期108-115,共8页
以鄂尔多斯盆地刘家沟组页岩盖层为研究对象,在页岩盖层所处的温压条件下,试验研究随CO_(2)拌注不同质量分数纳米SiO_(2)(SNPs)对页岩盖层突破压力的影响,并对页岩盖层岩石在突破试验前后的孔隙度、渗透率进行对比分析。采用扫描电镜对... 以鄂尔多斯盆地刘家沟组页岩盖层为研究对象,在页岩盖层所处的温压条件下,试验研究随CO_(2)拌注不同质量分数纳米SiO_(2)(SNPs)对页岩盖层突破压力的影响,并对页岩盖层岩石在突破试验前后的孔隙度、渗透率进行对比分析。采用扫描电镜对比试验前后岩样的微观孔隙结构与微观形貌,计算试验过程中SNPs-CO_(2)流体密度和黏度,明确随CO_(2)拌注不同质量分数SNPs对盖层封堵能力的影响,以深入揭示SNPs强化盖层封堵能力的潜力及机制。结果表明:SNPs能有效封堵页岩盖层中的孔隙和裂缝,降低岩石的孔隙度和渗透率,增大盖层岩石突破压力,增强盖层封堵能力;随纳米流体中SNPs的质量分数增加,含裂缝和不含裂缝岩心的突破压力增大,孔隙度与渗透率均减小;SNPs在一定注入质量分数范围内分布较为均匀,可在盖层孔隙表面形成有效保护层,增强盖层封堵能力;SNPs-CO_(2)流体密度较纯CO_(2)大,会限制CO_(2)向盖层岩石的迁移,减少CO_(2)与盖层岩石的相互作用;SNPs-CO_(2)流体黏度较纯CO_(2)大,会降低流体在盖层中的渗透能力并增加其在盖层中的流动阻力;储层孔隙度与渗透率均高于盖层,且SNPs-CO_(2)流体黏度与密度增大对流体在储层和盖层中的运移影响不大,因此SNPs对CO_(2)在储层中的运移情况影响较小。 展开更多
关键词 CO_(2)地质封存 纳米SiO_(2) 突破压力 盖层 封堵能力
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CO_(2)注入提高深部煤层气采收率多因机制试验
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作者 陈掌星 梁浩 +7 位作者 李颖 刘子民 李海涛 金志雄 leonhard ganzer 李可 李虹 秦海洋 《中国石油大学学报(自然科学版)》 北大核心 2025年第5期82-92,共11页
模拟现场注入和开采流程,采用在线可视化核磁共振技术开展超临界CO_(2)驱替煤层气(CO_(2)-ECBM)物理模拟试验,系统分析压力、温度、注入量、含水饱和度及孔隙特征对CH_(4)解吸及置换的影响。结果表明:随着注入压力从10 MPa增至20 MPa,CH... 模拟现场注入和开采流程,采用在线可视化核磁共振技术开展超临界CO_(2)驱替煤层气(CO_(2)-ECBM)物理模拟试验,系统分析压力、温度、注入量、含水饱和度及孔隙特征对CH_(4)解吸及置换的影响。结果表明:随着注入压力从10 MPa增至20 MPa,CH_(4)单位吸附量下降32.6%,显示压力对CO_(2)竞争吸附能力有显著促进作用;温度升高导致CH_(4)单位吸附量降幅达30%,呈线性负相关;CO_(2)注入量增加使CH_(4)吸附量降低27.6%,呈一定线性关系;含水饱和度增加会削弱CO_(2)驱替效能,吸附量降幅随饱和度升高而递减,表明水分占据吸附点位抑制置换反应;平均孔径增大时CH_(4)吸附量上升但增速趋缓,而CO_(2)驱替效率随孔径增大而增强。试验验证了超临界CO_(2)在深部煤层的优先吸附特性,其竞争置换机制受多因素耦合调控。 展开更多
关键词 超临界CO_(2) CH_(4) 核磁共振技术 竞争吸附 单位吸附量
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纳米SiO_(2)强化CO_(2)地质封存页岩盖层封堵能力机制试验 被引量:8
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作者 李颖 李茂茂 +4 位作者 李海涛 周军平 leonhard ganzer 罗红文 康夫馨 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第2期92-98,共7页
页岩为CO_(2)盐水层地质封存常见盖层岩石类型,强化盖层封堵能力有利于提高CO_(2)地质埋存量和安全性。为探究随CO_(2)混注纳米SiO_(2)(SNPs)强化盖层封堵能力的有效性和可行性,对CO_(2)地质封存页岩盖层样品开展原地条件下的超临界CO_... 页岩为CO_(2)盐水层地质封存常见盖层岩石类型,强化盖层封堵能力有利于提高CO_(2)地质埋存量和安全性。为探究随CO_(2)混注纳米SiO_(2)(SNPs)强化盖层封堵能力的有效性和可行性,对CO_(2)地质封存页岩盖层样品开展原地条件下的超临界CO_(2)酸蚀反应试验,基础组为页岩样品-地层水、对照组为页岩样品-地层水+超临界CO_(2)、优化组为页岩样品-地层水+SNPs+超临界CO_(2),并采用核磁共振测试、场发射扫描电镜可视化观测、X射线衍射测试和岩石力学试验,探究CO_(2)酸蚀反应前后的页岩孔隙结构、表面形貌、矿物成分及力学性质特征。结果表明:优化组的大孔孔隙分量及孔隙度和渗透率增大幅度低于对照组;与对照组相比,优化组黏土矿物与碳酸盐岩矿物相对含量损失少,表明随CO_(2)混注SNPs可使岩样内部酸蚀作用减弱;SNPs在岩石端面吸附聚集或进入岩心孔喉,可使优化组页岩样品力学性能损伤程度降低;随CO_(2)混注SNPs有利于强化CO_(2)盐水层地质封存盖层封堵能力。 展开更多
关键词 CO_(2)地质封存 纳米二氧化硅 超临界CO_(2) 盖层封堵能力
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Qualitative and Quantitative Evaluation of Permeability Changes during EOR Polymer Flooding Using Micromodels 被引量:1
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作者 Lucas Oliver Knobloch Rafael E. Hincapie +2 位作者 Hendrik Fö disch leonhard ganzer 《World Journal of Engineering and Technology》 2018年第2期332-349,共18页
Polymer solutions are used in chemical EOR processes to achieve incremental oil recoveries through obtaining favorable mobility ratios. In the process, the?in-situ?viscosity is a key parameter for the polymer flood de... Polymer solutions are used in chemical EOR processes to achieve incremental oil recoveries through obtaining favorable mobility ratios. In the process, the?in-situ?viscosity is a key parameter for the polymer flood design, as well as the changes in permeability due to the retention or adsorption (e.g.: plugging). Understanding the major causes of the plugging effects allows?predicting injectivity problems as well as optimizing project design. The objective of this work is to use glass-silicon-glass micromodels in combination with tracer particles—attached to the flooded fluids—to qualitatively and quantitatively describe the extent of permeability changes?after polymer injection. Laboratory work is performed in order to determine the physical properties of the polymer solutions when they flow through porous media, such as the presence of permeability reduction/plugging of the micromodel. A statistical analysis of the distribution and extent of plugged areas?is performed and a study of the pressure response during various injection stages will complement the study. A biopolymer (Scleroglucan) was tested and compared to a commonly used polymer, giving a direct insight into their pros and cons. Five different concentrations of polymers were tested and put into relation with their quantitative and qualitative amount of sort of called retention. The amount of adsorption was determined?experimentally in one case in order to draw the significance. By exploiting the potential of GSG-micromodels in combination with tracer particles, it was possible to visualize the reduction of flow paths and its increase during various injections for the first time. Expanding the working principle proposed in this work could provide further understanding of the behavior of any polymers.?The results obtained and workflow presented in this work allow for additional understanding of polymer solutions behavior in flooding applications. Furthermore, the definition of optimized workflows to?assess any kind of solutions in porous media and permeability changes is?supported. 展开更多
关键词 Enhanced Oil Recovery Polymer FLOODING Micromodels RETENTION Plugging ADSORPTION BIOPOLYMER
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A Comprehensive Combination of Apparent and Shear Viscoelastic Data during Polymer Flooding for EOR Evaluations
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作者 Muhammad Tahir Rafael E. Hincapie +1 位作者 Michael Be leonhard ganzer 《World Journal of Engineering and Technology》 2017年第4期585-600,共16页
We present a comprehensive workflow to obtain the best insights into the viscoelastic behavior of polymers. Viscoelasticity is depicted in most cases by the current commercially available polymers used for EOR applica... We present a comprehensive workflow to obtain the best insights into the viscoelastic behavior of polymers. Viscoelasticity is depicted in most cases by the current commercially available polymers used for EOR applications. The phenomenon is debated to be one of the reasons for additional oil recovery during polymer flooding applications. It is somehow accepted that polymer increases volumetric sweep efficiency owing to improved mobility ratio. Recently researches have explained that flooding polymers in porous media with elastic characteristics could recover additional oil, due to the improved microscale oil displacement (pore-scale). This study focuses on the analysis of polymer viscoelasticity based on single-phase core, sand-pack and capillary tube (CT) experiments coupled with their detailed rheological characterization, in order to evaluate polymer behavior in porous media. A combination of hydrolyzed polyacrylamides (HPAM) polymers as well as a bio polymer is presented throughout this evaluation. The evaluation of the data is addressed on the basis of pressure drop across the pores, separating the shear associated pressure by the extensional thickening associated pressure. Apart from that, viscoelastic dependence of the converging-diverging geometry has been experimented. Based on the observed behavior through porous media, HPAM polymers are compared with bio polymers. Moreover, the behavior of solutions with induced mechanical degradation (pre-sheared) is compared with non-sheared solutions. Similarly, concentrations with different polymer solutions are evaluated. The results obtained in this work allow for additional understanding of polymer solutions behavior in flooding applications. Furthermore?The results support?the definition of optimized workflows to assess their behavior under flow through porous media. Finally this evaluation helps to describe the parameter that defines polymer viscoelastic properties. 展开更多
关键词 VISCOELASTICITY Mechanical Degradation Elongational VISCOSITY Weissenberg Number
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