Organoplatinum（Ⅱ） compounds have received enormous attention over the past decades due to their square-planar geometry as well as intriguing photo-physical properties.Self-assembly has emerged as an excellent appro...Organoplatinum（Ⅱ） compounds have received enormous attention over the past decades due to their square-planar geometry as well as intriguing photo-physical properties.Self-assembly has emerged as an excellent approach to create well-ordered supramolecular architectures with tunable properties,which underpin the role of solvent-directed approach for the design of functional materials.In this minireview,the recent advances on supramolecular self-assembly of cyclometalated platinum（Ⅱ） complexes have been discussed.During the self-assembly process,non-covalent Pt-Pt and π-π interactions play crucial roles in controlling the structures and functions of the resulting assemblies.展开更多
Intelligent transportation system （ITS） is proposed as the most effective way to improve road safety and traffic efficiency. However, the future of ITS for large scale transportation infrastructures deployment highl...Intelligent transportation system （ITS） is proposed as the most effective way to improve road safety and traffic efficiency. However, the future of ITS for large scale transportation infrastructures deployment highly depends on the security level of vehicular communication systems （VCS）. Security applications in VCS are fulfilled through secured group broadcast. Therefore, secure key management schemes are considered as a critical research topic for network security. In this paper, we propose a framework for providing secure key management within heterogeneous network. The seeurity managers （SMs） play a key role in the framework by retrieving the vehicle departnre infi^rmation, encapsulating block to transport keys and then executing rekeying to vehicles within the same security domain. The first part of this framework is a novel Group Key Management （GKM） scheme basing on leaving probability （LP） of vehicles to depart current VCS region. Vehicle＇s LP factor is introduced into GKM scheme to achieve a more effieient rekeying scheme and less rekeying costs. The second component of the framework using the blockchain concept to simplify the distributed key management in heterogeneous VCS domains. Extensive simulations and analysis are provided to show the effectiveness and effieiency of the proposed framework： Our GKM results demonstrate that probability-based BR reduees rekeying eost compared to the benchmark scheme, while the blockchain deereases the time eost of key transmission over heterogeneous net-works.展开更多
23 compounds containing pyranone pharmacophore of territrem B were designed and synthesized. Some of the analogues showed IC50 values of AChE inhibition at 10^-5 mol/L.
基金supported by the National Natural Science Foundation of China(No.21274139)the Fundamental Research Funds for the Central Universities(Nos.WK3450000001,WK2060200012)
文摘Organoplatinum（Ⅱ） compounds have received enormous attention over the past decades due to their square-planar geometry as well as intriguing photo-physical properties.Self-assembly has emerged as an excellent approach to create well-ordered supramolecular architectures with tunable properties,which underpin the role of solvent-directed approach for the design of functional materials.In this minireview,the recent advances on supramolecular self-assembly of cyclometalated platinum（Ⅱ） complexes have been discussed.During the self-assembly process,non-covalent Pt-Pt and π-π interactions play crucial roles in controlling the structures and functions of the resulting assemblies.
文摘Intelligent transportation system （ITS） is proposed as the most effective way to improve road safety and traffic efficiency. However, the future of ITS for large scale transportation infrastructures deployment highly depends on the security level of vehicular communication systems （VCS）. Security applications in VCS are fulfilled through secured group broadcast. Therefore, secure key management schemes are considered as a critical research topic for network security. In this paper, we propose a framework for providing secure key management within heterogeneous network. The seeurity managers （SMs） play a key role in the framework by retrieving the vehicle departnre infi^rmation, encapsulating block to transport keys and then executing rekeying to vehicles within the same security domain. The first part of this framework is a novel Group Key Management （GKM） scheme basing on leaving probability （LP） of vehicles to depart current VCS region. Vehicle＇s LP factor is introduced into GKM scheme to achieve a more effieient rekeying scheme and less rekeying costs. The second component of the framework using the blockchain concept to simplify the distributed key management in heterogeneous VCS domains. Extensive simulations and analysis are provided to show the effectiveness and effieiency of the proposed framework： Our GKM results demonstrate that probability-based BR reduees rekeying eost compared to the benchmark scheme, while the blockchain deereases the time eost of key transmission over heterogeneous net-works.
文摘23 compounds containing pyranone pharmacophore of territrem B were designed and synthesized. Some of the analogues showed IC50 values of AChE inhibition at 10^-5 mol/L.
