Silica glasses doped with Eu3＋ ions prepared by sol-gel methods were investigated. The X-ray diffraction （XRD） was used to verify the nature of the studied systems. Excitation and emission spectra of Eu3＋ ions in ...Silica glasses doped with Eu3＋ ions prepared by sol-gel methods were investigated. The X-ray diffraction （XRD） was used to verify the nature of the studied systems. Excitation and emission spectra of Eu3＋ ions in sol-gel glass materials were detected. Red-to-orange luminescence intensity ratios R/O related to integrated intensities of 5D0→TF2 to 5D0→7TF1 transitions and luminescence lifetimes for 5D0 state of Eu3＋ ions were determined. The results indicated that spectroscopic parameters for Eu3＋ ions strongly de- pended on reagents and their relative ratios used for sol-gel glass preparation.展开更多
Lead phosphate glasses singly doped with Dy^3＋ ions were studied. The samples were prepared in a glove box in order to eliminate hydroxyl groups. Local structures were examined using FT-IR. Excitation and luminescenc...Lead phosphate glasses singly doped with Dy^3＋ ions were studied. The samples were prepared in a glove box in order to eliminate hydroxyl groups. Local structures were examined using FT-IR. Excitation and luminescence spectra for Dy^3＋ ions in inves- tigated lead phosphate glasses were registered. Luminescence intensity ratio Y/B related to 4F9/2→^6HJ/2 （where J=15, 13） transitions was determined and luminescence lifetime （ζm） for the 4F9/2 state of Dy^3＋ions were also measured.展开更多
Local structure and luminescent properties of lead phosphate glasses containing rare earth ions were studied. Optically active ions such as Eu^3＋, Dy^3＋, Tb^3＋ and Er^3＋ were chosen as dopants. The local structure...Local structure and luminescent properties of lead phosphate glasses containing rare earth ions were studied. Optically active ions such as Eu^3＋, Dy^3＋, Tb^3＋ and Er^3＋ were chosen as dopants. The local structure was verified using X-ray diffraction and Fourier transform inflared （FT-IR） spectroscopy. The visible luminescence bands recorded for the studied samples corresponded to ^5D0→^7Fj （J=0÷4） transitions of Eu^3＋, ^4F9/2→^6Hj/2 （J=11÷15） transitions of Dy^3＋, ^5D3→^7FJ, （J＇=1÷6） and ^5Da→^7FJ （J=3÷6） transitions of Tb^3＋, and ^4S1/2→^4I15/2 transitions of Er^3＋.展开更多
Compositional-dependent heavy metal lead borate glasses doped with Tb^3＋ ions were investigated. Green luminescence related to main ^5D4→^7F5 （543 nm） transition was registered under excitation of ^5D3 state of T...Compositional-dependent heavy metal lead borate glasses doped with Tb^3＋ ions were investigated. Green luminescence related to main ^5D4→^7F5 （543 nm） transition was registered under excitation of ^5D3 state of Tb^3＋ ions. Based on excitation and luminescence measurements, several spectroscopic parameters for Tb3＋ ions were examined as a function of heavy metal PbO content. Luminescence decay analysis indicated that the ^5D4 luminescence lifetime of Tb^3＋ reduced from 2.83 to 1.42 ms, when PbO：B203 ratio was changed from 1：1 to 4：1.展开更多
文摘Silica glasses doped with Eu3＋ ions prepared by sol-gel methods were investigated. The X-ray diffraction （XRD） was used to verify the nature of the studied systems. Excitation and emission spectra of Eu3＋ ions in sol-gel glass materials were detected. Red-to-orange luminescence intensity ratios R/O related to integrated intensities of 5D0→TF2 to 5D0→7TF1 transitions and luminescence lifetimes for 5D0 state of Eu3＋ ions were determined. The results indicated that spectroscopic parameters for Eu3＋ ions strongly de- pended on reagents and their relative ratios used for sol-gel glass preparation.
基金Project supported by National Science Centre(Poland)(2011/01/B/ST5/00978)
文摘Lead phosphate glasses singly doped with Dy^3＋ ions were studied. The samples were prepared in a glove box in order to eliminate hydroxyl groups. Local structures were examined using FT-IR. Excitation and luminescence spectra for Dy^3＋ ions in inves- tigated lead phosphate glasses were registered. Luminescence intensity ratio Y/B related to 4F9/2→^6HJ/2 （where J=15, 13） transitions was determined and luminescence lifetime （ζm） for the 4F9/2 state of Dy^3＋ions were also measured.
基金Project supported by the Science and Higher Education (N N204 313937)
文摘Local structure and luminescent properties of lead phosphate glasses containing rare earth ions were studied. Optically active ions such as Eu^3＋, Dy^3＋, Tb^3＋ and Er^3＋ were chosen as dopants. The local structure was verified using X-ray diffraction and Fourier transform inflared （FT-IR） spectroscopy. The visible luminescence bands recorded for the studied samples corresponded to ^5D0→^7Fj （J=0÷4） transitions of Eu^3＋, ^4F9/2→^6Hj/2 （J=11÷15） transitions of Dy^3＋, ^5D3→^7FJ, （J＇=1÷6） and ^5Da→^7FJ （J=3÷6） transitions of Tb^3＋, and ^4S1/2→^4I15/2 transitions of Er^3＋.
基金Project supported by the Ministry of Science and Higher Education (N N204 313937)
文摘Compositional-dependent heavy metal lead borate glasses doped with Tb^3＋ ions were investigated. Green luminescence related to main ^5D4→^7F5 （543 nm） transition was registered under excitation of ^5D3 state of Tb^3＋ ions. Based on excitation and luminescence measurements, several spectroscopic parameters for Tb3＋ ions were examined as a function of heavy metal PbO content. Luminescence decay analysis indicated that the ^5D4 luminescence lifetime of Tb^3＋ reduced from 2.83 to 1.42 ms, when PbO：B203 ratio was changed from 1：1 to 4：1.
