Polysynthetic twinned(PST)TiAl single crystal specifically refers to a fully lamellar TiAl single crystal with parallel phase interfaces and twin interfaces grown by directional solidification.In this paper,PST single...Polysynthetic twinned(PST)TiAl single crystal specifically refers to a fully lamellar TiAl single crystal with parallel phase interfaces and twin interfaces grown by directional solidification.In this paper,PST single crystals with different phase ratios are obtained by annealing at specific temperatures and holding times.The results show that the diffusion rates of Ti and Al elements at various temperatures directly trigger and propel the surface recrystallization and variation in the internal phase ratio.When the temperature is lower than 1448 K,the diffusion rate of Ti is obviously higher than that of Al,which causes one denseα_(2)recrystallized layer to form on the surface of TiAl single crystals.Meanwhile,as more Ti elements migrate to the surface,theα_(2)phase ratio inside the TiAl single crystal thereby decreases.When the temperature exceeds 1448 K,the diffusion rate of Al gradually reverses to exceed that of Ti,which forms the surface sandwiched recrystallization dominated byγphase and simultaneously increasesα_(2)phase ratio inside the TiAl single crystal.The variation in the two-phase ratio directly induces a significant change in the lamellae thickness,which exhibits different tensile behaviors of PST-TiAl single crystal.When theα_(2)phase content is less than 20%,widerγlamellae make it easier for dislocations to be activated within its lamellae and continuously move across theγ/α_(2)interfaces,thereby obtaining better tensile plasticity.As theα_(2)phase content exceeds 30%,finerγlamellae inhibit the dislocation initiation,resulting in the fracture occurrence of TiAl single crystal before yielding.No matter how the phase ratio changes,the crack preferentially initiates withinα_(2)lamellae.However,the crack propagation follows different paths based on variousγlamella thicknesses.The fracture mode of PST-TiAl single crystal also changes from shear fracture along slip bands within theγlamella to brittle fracture along the{1¯100}planes withinα_(2)lamella.展开更多
Under-deposit corrosion(UDC)due to the presence of deposits has become a major concern threatening the safe service of pipelines in oil and gas fields,causing economic loss and even irreversible damage to life and env...Under-deposit corrosion(UDC)due to the presence of deposits has become a major concern threatening the safe service of pipelines in oil and gas fields,causing economic loss and even irreversible damage to life and environment.Herein,we provide a critical review of UDC in terms of testing methods,corrosion mechanisms and mitigation strategies,so as to better understand and prevent UDC.Two deposit simulation methods and three UDC testing systems are summarized.Two popular UDC mechanisms are discussed based on the coverage and protectiveness of deposits,and the galvanic couple caused by the uneven distribution of deposits is found to be the root cause for the prevailed localized corrosion under deposits.The mitigation strategies for UDC are reviewed from the aspects of scale controlling and corrosion inhibition.In the last,the demands for developing accurate deposit simulation methods,effective UDC inhibitors and advanced on-site scale monitoring technologies are proposed.展开更多
基金supported by the National Natural Science Foundation of China(NSFC)under Grant Nos.52288102,52322101,92163215,52174364,52101143,U23A20542the Fundamental Research Funds for the Central Universities under Grant No.30922010202+1 种基金the 100 Talents Plan of Hebei Province under Grant No.E2020100005the Natural Science Foundation of Hebei Province under Grant No.E2022203109.
文摘Polysynthetic twinned(PST)TiAl single crystal specifically refers to a fully lamellar TiAl single crystal with parallel phase interfaces and twin interfaces grown by directional solidification.In this paper,PST single crystals with different phase ratios are obtained by annealing at specific temperatures and holding times.The results show that the diffusion rates of Ti and Al elements at various temperatures directly trigger and propel the surface recrystallization and variation in the internal phase ratio.When the temperature is lower than 1448 K,the diffusion rate of Ti is obviously higher than that of Al,which causes one denseα_(2)recrystallized layer to form on the surface of TiAl single crystals.Meanwhile,as more Ti elements migrate to the surface,theα_(2)phase ratio inside the TiAl single crystal thereby decreases.When the temperature exceeds 1448 K,the diffusion rate of Al gradually reverses to exceed that of Ti,which forms the surface sandwiched recrystallization dominated byγphase and simultaneously increasesα_(2)phase ratio inside the TiAl single crystal.The variation in the two-phase ratio directly induces a significant change in the lamellae thickness,which exhibits different tensile behaviors of PST-TiAl single crystal.When theα_(2)phase content is less than 20%,widerγlamellae make it easier for dislocations to be activated within its lamellae and continuously move across theγ/α_(2)interfaces,thereby obtaining better tensile plasticity.As theα_(2)phase content exceeds 30%,finerγlamellae inhibit the dislocation initiation,resulting in the fracture occurrence of TiAl single crystal before yielding.No matter how the phase ratio changes,the crack preferentially initiates withinα_(2)lamellae.However,the crack propagation follows different paths based on variousγlamella thicknesses.The fracture mode of PST-TiAl single crystal also changes from shear fracture along slip bands within theγlamella to brittle fracture along the{1¯100}planes withinα_(2)lamella.
基金financially supported by the Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province(No.2017CL18)
文摘Under-deposit corrosion(UDC)due to the presence of deposits has become a major concern threatening the safe service of pipelines in oil and gas fields,causing economic loss and even irreversible damage to life and environment.Herein,we provide a critical review of UDC in terms of testing methods,corrosion mechanisms and mitigation strategies,so as to better understand and prevent UDC.Two deposit simulation methods and three UDC testing systems are summarized.Two popular UDC mechanisms are discussed based on the coverage and protectiveness of deposits,and the galvanic couple caused by the uneven distribution of deposits is found to be the root cause for the prevailed localized corrosion under deposits.The mitigation strategies for UDC are reviewed from the aspects of scale controlling and corrosion inhibition.In the last,the demands for developing accurate deposit simulation methods,effective UDC inhibitors and advanced on-site scale monitoring technologies are proposed.
