The liquid Zr_(100-x)V_(x)(x=8.6,16.5,30)alloys were undercooled to the maximum undercooling of 364 K(0.18 T_(L)),405 K(0.21 T_(L)),and 375 K(0.21 T_(L)),respectively,by using electrostatic levitation technique.The Zr...The liquid Zr_(100-x)V_(x)(x=8.6,16.5,30)alloys were undercooled to the maximum undercooling of 364 K(0.18 T_(L)),405 K(0.21 T_(L)),and 375 K(0.21 T_(L)),respectively,by using electrostatic levitation technique.The Zr_(91.4)V_(8.6) and Zr_(83.5)V_(16.5) alloys present only one recalescence during liquid/solid phase transition,while the Zr_(70)V_(30) alloy presents a transformation from two recalescence to one recalescence phenomenon with a critical undercooling of approximately 300 K.According to the LKT/BCT model,the calculated results of the primary β-Zr dendrite growth velocity in undercooled liquid Zr_(91.4)V_(8.6) and Zr_(83.5)V_(16.5) alloys agree well with the experiments.The velocity inflection points at 119 K of Zr_(91.4)V_(8.6) alloy and 201 K of Zr_(83.5)V_(16.5) alloy could be explained by the competition between solutal undercooling control and thermal undercooling control modes.For Zr_(70)V_(30) alloy solidified in the P1 with twice recalescence,a critical second undercooling of 253 K and corresponding undercooling of 65 and 244 K are obtained.When the un-dercooling is in the range of 65-244 K,the second undercooling would be greater than 253 K,and the residual liquid phase would solidify into anomalous eutectic microstructure for Zr_(70)V_(30) alloy.The Vickers hardness of Zr_(100-x)V_(x)(x=8.6,16.5,30)alloys all show a quadratic relationship with undercooling.Under electrostatic levitation condition,the mechanical property of Zr-V alloys could be significantly regulated through solidifying the alloys at different undercoolings.展开更多
The undercooling dependence of the solidification mechanism was systematically explored by the electrostatic levitation(ESL)facility.During the experiments,the maximum undercooling reached up to 406 K(0.26 T_L)and the...The undercooling dependence of the solidification mechanism was systematically explored by the electrostatic levitation(ESL)facility.During the experiments,the maximum undercooling reached up to 406 K(0.26 T_L)and the growth velocity of the primary TiNi phase was in-situ determined at various undercoolings.At the initial increase of alloy undercooling,the value of growth velocity sluggishly rose followed by a power function.In this case,the primary TiNi phase preferentially developed as the equiaxed dendrite,then the remnant liquid participated as Ti_(2)Ni andα-Ti phases on the grain boundary.Once the undercooling exceeded the critical value of 350 K,the growth velocity of the primary phase displayed a sharply increase tendency.Meanwhile,the TEM results demonstrated that the precipitation of the intermetallic Ti_(2)Ni compound was gradually restrained during the rapid solidification and the R-phase existing in the TiNi matrix at large undercooling implied that the martensitic transformation was incomplete.展开更多
The density of liquid Incone1718 alloy was experimentally measured by electrostatic levitation technique, where the maximum undercooling of 100 K was realized for the commercial sample. The measured density of liquid ...The density of liquid Incone1718 alloy was experimentally measured by electrostatic levitation technique, where the maximum undercooling of 100 K was realized for the commercial sample. The measured density of liquid lnconel 718 alloy is 7.39 g cm^-3 at the liquidus temperature of 1663 K which was confirmed by DSC experiment, with the linear temperature coefficient of -6.89 × 10^-4 gcm^-3 K^-1. Correspondingly, four ternary Ni-Cr-Fe compositions were designed to simulate the density of liquid lnconel 718 alloy with 16000 atoms, from which the liquid structure is revealed by pair distribution function, The predicted result shows a remarkable enhancement with the decrease of temperature at the first neighbor distance.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.52088101)the Space Utilization System of China Manned Space Engineering(Grant No.KJZ-YY-NCL02)+1 种基金the National Key R&D Program of China(Grant No.2021YFA0716301)the Shannxi Key Science and Technology Program(Grant Nos.2023-ZDLGY-36,2024JC-ZDXM-24).
文摘The liquid Zr_(100-x)V_(x)(x=8.6,16.5,30)alloys were undercooled to the maximum undercooling of 364 K(0.18 T_(L)),405 K(0.21 T_(L)),and 375 K(0.21 T_(L)),respectively,by using electrostatic levitation technique.The Zr_(91.4)V_(8.6) and Zr_(83.5)V_(16.5) alloys present only one recalescence during liquid/solid phase transition,while the Zr_(70)V_(30) alloy presents a transformation from two recalescence to one recalescence phenomenon with a critical undercooling of approximately 300 K.According to the LKT/BCT model,the calculated results of the primary β-Zr dendrite growth velocity in undercooled liquid Zr_(91.4)V_(8.6) and Zr_(83.5)V_(16.5) alloys agree well with the experiments.The velocity inflection points at 119 K of Zr_(91.4)V_(8.6) alloy and 201 K of Zr_(83.5)V_(16.5) alloy could be explained by the competition between solutal undercooling control and thermal undercooling control modes.For Zr_(70)V_(30) alloy solidified in the P1 with twice recalescence,a critical second undercooling of 253 K and corresponding undercooling of 65 and 244 K are obtained.When the un-dercooling is in the range of 65-244 K,the second undercooling would be greater than 253 K,and the residual liquid phase would solidify into anomalous eutectic microstructure for Zr_(70)V_(30) alloy.The Vickers hardness of Zr_(100-x)V_(x)(x=8.6,16.5,30)alloys all show a quadratic relationship with undercooling.Under electrostatic levitation condition,the mechanical property of Zr-V alloys could be significantly regulated through solidifying the alloys at different undercoolings.
基金the National Natural Science Foundation of China(Grant Nos.51734008,51522102 and 51327901)the National Key R&D Program of China(Grant No.2018YFB2001800)the Shannxi Key Industry Chain Program(Grant No.2019ZDLGY05-10)。
文摘The undercooling dependence of the solidification mechanism was systematically explored by the electrostatic levitation(ESL)facility.During the experiments,the maximum undercooling reached up to 406 K(0.26 T_L)and the growth velocity of the primary TiNi phase was in-situ determined at various undercoolings.At the initial increase of alloy undercooling,the value of growth velocity sluggishly rose followed by a power function.In this case,the primary TiNi phase preferentially developed as the equiaxed dendrite,then the remnant liquid participated as Ti_(2)Ni andα-Ti phases on the grain boundary.Once the undercooling exceeded the critical value of 350 K,the growth velocity of the primary phase displayed a sharply increase tendency.Meanwhile,the TEM results demonstrated that the precipitation of the intermetallic Ti_(2)Ni compound was gradually restrained during the rapid solidification and the R-phase existing in the TiNi matrix at large undercooling implied that the martensitic transformation was incomplete.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 51327901, 51474175, 51522102 and 51734008)
文摘The density of liquid Incone1718 alloy was experimentally measured by electrostatic levitation technique, where the maximum undercooling of 100 K was realized for the commercial sample. The measured density of liquid lnconel 718 alloy is 7.39 g cm^-3 at the liquidus temperature of 1663 K which was confirmed by DSC experiment, with the linear temperature coefficient of -6.89 × 10^-4 gcm^-3 K^-1. Correspondingly, four ternary Ni-Cr-Fe compositions were designed to simulate the density of liquid lnconel 718 alloy with 16000 atoms, from which the liquid structure is revealed by pair distribution function, The predicted result shows a remarkable enhancement with the decrease of temperature at the first neighbor distance.
