This article mainly summarizes various aspects of hydrogen peroxide(H2O2)production through the anthraquinone route,including hydrogenation catalysts,working solution,regeneration technique,hydrogenation reactors,and ...This article mainly summarizes various aspects of hydrogen peroxide(H2O2)production through the anthraquinone route,including hydrogenation catalysts,working solution,regeneration technique,hydrogenation reactors,and environmental protection.The advances and breakthrough of SINOPEC in the production of H2O2 through the anthraquinone route is presented in this review,highlighting recent innovative technology on these aspects developed independently.The technical prospect and scientific challenges associated with the direct synthesis method from hydrogen and oxygen are also briefly discussed.展开更多
After two decades＇ endeavor, the Research Institute of Petroleum Processing （RIPP） has successfully de- veloped a green caprolactam （CPL） production technology. This technology is based on the integration of tita...After two decades＇ endeavor, the Research Institute of Petroleum Processing （RIPP） has successfully de- veloped a green caprolactam （CPL） production technology. This technology is based on the integration of titanium silicate （TS）-I zeolite with the slurry-bed reactor for the ammoximation of cyclohexanone, the integration of silicalite-1 zeolite with the moving-bed reactor for the gas-phase rearrangement of cyclohex- anone oxime, and the integration of an amorphous nickel （Ni） catalyst with the magnetically stabilized bed reactor for the purification of caprolactam. The world＇s first industrial plant based on this green CPL produc- tion technology has been built and possesses a capacity of 200 kt·a-1. Compared with existing technologies, the plant investment is pronouncedly reduced, and the nitrogen （N） atom utilization is drastically improved. The waste emission is reduced significantly; for example, no ammonium sulfate byproduct is produced. As a result, the price difference between CPL and benzene drops. In 2015, the capacity of the green CPL produc- tion technology reached 3 ×10-6 t·a-1, making China the world＇s largest CPL producer, with a global market share exceeding 50%.展开更多
文摘This article mainly summarizes various aspects of hydrogen peroxide(H2O2)production through the anthraquinone route,including hydrogenation catalysts,working solution,regeneration technique,hydrogenation reactors,and environmental protection.The advances and breakthrough of SINOPEC in the production of H2O2 through the anthraquinone route is presented in this review,highlighting recent innovative technology on these aspects developed independently.The technical prospect and scientific challenges associated with the direct synthesis method from hydrogen and oxygen are also briefly discussed.
文摘After two decades＇ endeavor, the Research Institute of Petroleum Processing （RIPP） has successfully de- veloped a green caprolactam （CPL） production technology. This technology is based on the integration of titanium silicate （TS）-I zeolite with the slurry-bed reactor for the ammoximation of cyclohexanone, the integration of silicalite-1 zeolite with the moving-bed reactor for the gas-phase rearrangement of cyclohex- anone oxime, and the integration of an amorphous nickel （Ni） catalyst with the magnetically stabilized bed reactor for the purification of caprolactam. The world＇s first industrial plant based on this green CPL produc- tion technology has been built and possesses a capacity of 200 kt·a-1. Compared with existing technologies, the plant investment is pronouncedly reduced, and the nitrogen （N） atom utilization is drastically improved. The waste emission is reduced significantly; for example, no ammonium sulfate byproduct is produced. As a result, the price difference between CPL and benzene drops. In 2015, the capacity of the green CPL produc- tion technology reached 3 ×10-6 t·a-1, making China the world＇s largest CPL producer, with a global market share exceeding 50%.
