Phase change materials have a key role for wearable thermal management,but suffer from poor water vapor permeability,low enthalpy value and weak shape stability caused by liquid phase leakage and intrinsic rigidity of...Phase change materials have a key role for wearable thermal management,but suffer from poor water vapor permeability,low enthalpy value and weak shape stability caused by liquid phase leakage and intrinsic rigidity of solid–liquid phase change materials.Herein,we report for the first time a versatile strategy for designed assembly of high-enthalpy flexible phase change nonwovens(GB-PCN)by wet-spinning hybrid grapheneboron nitride(GB)fiber and subsequent impregnating paraffins(e.g.,eicosane,octadecane).As a result,our GB-PCN exhibited an unprecedented enthalpy value of 206.0 J g^(−1),excellent thermal reliability and anti-leakage capacity,superb thermal cycling ability of 97.6%after 1000 cycles,and ultrahigh water vapor permeability(close to the cotton),outperforming the reported PCM films and fibers to date.Notably,the wearable thermal management systems based on GB-PCN for both clothing and face mask were demonstrated,which can maintain the human body at a comfortable temperature range for a significantly long time.Therefore,our results demonstrate huge potential of GB-PCN for human-wearable passive thermal management in real scenarios.展开更多
Phase change materials(PCMs)have attracted much attention in the field of solar thermal utilization recently,due to their outstanding thermal energy storage performance.However,PCMs usually release their stored latent...Phase change materials(PCMs)have attracted much attention in the field of solar thermal utilization recently,due to their outstanding thermal energy storage performance.However,PCMs usually release their stored latent heat spontaneously as the temperature below the phase transition temperature,rendering thermal energy storage and release uncontrollable,thus hindering their practical application in time and space.Herein,we developed erythritol/sodium carboxymethylcellulose/tetrasodium ethylenediaminetetraacetate(ERY/CMC/EDTA-4Na)composite PCMs with novel spatiotemporal thermal energy storage properties,defined as spatiotemporal PCMs(STPCMs),which exhibit the capacity of thermal energy long-term storage and controllable release.Our results show that the composite PCMs are unable to lose latent heat due to spontaneous crystallization during cooling,but can controllably release thermal energy through cold crystallization during reheating.The cold-crystallization temperature and enthalpy of composite PCMs can be adjusted by proportional addition of EDTA-4Na to the composite.When the mass fractions of CMC and EDTA-4Na are both 10%,the composite PCMs can exhibit the optical coldcrystallization temperature of 51.7℃ and enthalpy of 178.1 J/g.The supercooled composite PCMs without latent heat release can be maintained at room temperature(10-25℃)for up to more than two months,and subsequently the stored latent heat can be controllably released by means of thermal triggering or heterogeneous nucleation.Our findings provide novel insights into the design and construction of new PCMs with spatiotemporal performance of thermal energy long-term storage and controllable release,and consequently open a new door for the development of advanced solar thermal utilization techniques on the basis of STPCMs.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21903082,22003065,22125903,51872283,22075279,21805273,22273100)Dalian Innovation Support Plan for High Level Talents(2019RT09)+3 种基金Dalian National Laboratory For Clean Energy(DNL),CAS,DNL Cooperation Fund,CAS(DNL201912,DNL201915,DNL202016,DNL202019)DICP(DICP I2020032,DICP I202036,I202218)The Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy(YLU-DNL Fund 2021002,YLU-DNL 2021007,YLU-DNL 2021009)Q.Shi would like to thank Dalian Outstanding Young Scientific Talent Program(Grant 2019RJ10).
文摘Phase change materials have a key role for wearable thermal management,but suffer from poor water vapor permeability,low enthalpy value and weak shape stability caused by liquid phase leakage and intrinsic rigidity of solid–liquid phase change materials.Herein,we report for the first time a versatile strategy for designed assembly of high-enthalpy flexible phase change nonwovens(GB-PCN)by wet-spinning hybrid grapheneboron nitride(GB)fiber and subsequent impregnating paraffins(e.g.,eicosane,octadecane).As a result,our GB-PCN exhibited an unprecedented enthalpy value of 206.0 J g^(−1),excellent thermal reliability and anti-leakage capacity,superb thermal cycling ability of 97.6%after 1000 cycles,and ultrahigh water vapor permeability(close to the cotton),outperforming the reported PCM films and fibers to date.Notably,the wearable thermal management systems based on GB-PCN for both clothing and face mask were demonstrated,which can maintain the human body at a comfortable temperature range for a significantly long time.Therefore,our results demonstrate huge potential of GB-PCN for human-wearable passive thermal management in real scenarios.
基金the financial support from the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy(YLU-DNL Fund 2021007)the National Nature Science Foundation of China(21903082 and 22273100)+2 种基金the Dalian Institute of Chemical Physics(DICP I202036,and I202218)the DNL Cooperation Fund,CAS(DNL202012)Liaoning Provincial Natural Science Foundation of China under grant 2022-MS-020。
文摘Phase change materials(PCMs)have attracted much attention in the field of solar thermal utilization recently,due to their outstanding thermal energy storage performance.However,PCMs usually release their stored latent heat spontaneously as the temperature below the phase transition temperature,rendering thermal energy storage and release uncontrollable,thus hindering their practical application in time and space.Herein,we developed erythritol/sodium carboxymethylcellulose/tetrasodium ethylenediaminetetraacetate(ERY/CMC/EDTA-4Na)composite PCMs with novel spatiotemporal thermal energy storage properties,defined as spatiotemporal PCMs(STPCMs),which exhibit the capacity of thermal energy long-term storage and controllable release.Our results show that the composite PCMs are unable to lose latent heat due to spontaneous crystallization during cooling,but can controllably release thermal energy through cold crystallization during reheating.The cold-crystallization temperature and enthalpy of composite PCMs can be adjusted by proportional addition of EDTA-4Na to the composite.When the mass fractions of CMC and EDTA-4Na are both 10%,the composite PCMs can exhibit the optical coldcrystallization temperature of 51.7℃ and enthalpy of 178.1 J/g.The supercooled composite PCMs without latent heat release can be maintained at room temperature(10-25℃)for up to more than two months,and subsequently the stored latent heat can be controllably released by means of thermal triggering or heterogeneous nucleation.Our findings provide novel insights into the design and construction of new PCMs with spatiotemporal performance of thermal energy long-term storage and controllable release,and consequently open a new door for the development of advanced solar thermal utilization techniques on the basis of STPCMs.
