[5,15-Di(4-aminophenyl)-10,20-diphenylporphyrinato]zinc(II) was found to electropolymerize on electrodes such as glassy carbon (GC), indium tin oxide (ITO), and tin oxide, to form a redox-active, stable, and reproduci...[5,15-Di(4-aminophenyl)-10,20-diphenylporphyrinato]zinc(II) was found to electropolymerize on electrodes such as glassy carbon (GC), indium tin oxide (ITO), and tin oxide, to form a redox-active, stable, and reproducible π-conjugated polymer. Electrochemical and UV/vis spectroscopic studies showed that the electropolymerization involves azobenzene linkage formation via radical intermediates. The electrode modified with the porphyrinic wire featured strong light absorptions in the visible region, thereby serving as a photoanode for a photocurrent generation system.展开更多
基金acknowledge Grants-in-Aid from MEXT of Japan(no.26708005,26107510,26620039,15H00862,26220801,26110505,areas 2406[All Nippon Artificial Photosynthesis Project for Living Earth]2506[Science of Atomic Layers]and 2509[Molecular Architectonics])JSPS fellowship for young scientists.
文摘[5,15-Di(4-aminophenyl)-10,20-diphenylporphyrinato]zinc(II) was found to electropolymerize on electrodes such as glassy carbon (GC), indium tin oxide (ITO), and tin oxide, to form a redox-active, stable, and reproducible π-conjugated polymer. Electrochemical and UV/vis spectroscopic studies showed that the electropolymerization involves azobenzene linkage formation via radical intermediates. The electrode modified with the porphyrinic wire featured strong light absorptions in the visible region, thereby serving as a photoanode for a photocurrent generation system.
