A new intercalation compound,Fe_(0.85)PS_(3)(4,4-bipyH)_(0.30)(4,4-bipy=4,4-bipyridine),is obtained by the intercalation of 4,4-bipyridine-2HCl with lamellar FePS_(3),which is characterized by elemental analysis,powde...A new intercalation compound,Fe_(0.85)PS_(3)(4,4-bipyH)_(0.30)(4,4-bipy=4,4-bipyridine),is obtained by the intercalation of 4,4-bipyridine-2HCl with lamellar FePS_(3),which is characterized by elemental analysis,powder X-ray diffraction,infrared spectroscopy.By comparison with the pure FePS_(3),the lattice spacing of Fe0.85PS_(3)(4,4-bipyH)0.30 is expanded by~5.7,indicating that the ring plane of the vip is perpendicular to the layer of the host.The magnetic property of Fe0.85PS_(3)(4,4-bipyH)0.30 is studied with SQUID.It exhibits an antiferromagnetic phase transition with TN of about 70 K.展开更多
Single carbon nanotubes (CNTs) have the sorption states at around 200 K, and show the poor desorption characteristics at around 300 K. The bamboo-like CNTs, HP1050 and the ground HP1050 (HP-1050G), show the desorption...Single carbon nanotubes (CNTs) have the sorption states at around 200 K, and show the poor desorption characteristics at around 300 K. The bamboo-like CNTs, HP1050 and the ground HP1050 (HP-1050G), show the desorption peaks at around 100 K and 140 K, respectively. Furthermore, HP1050G has the sorption states at around 300 - 400 K. On the basis of the sorption process, the ground bamboo-like CNT has a possibility for application to the room temperature storage of methane, which has utility for energy technologies such as fuel cells.展开更多
The adsorption states of hydrogen at around 300 K are found on carbons by means of thermal desorption measurements. This sorption ability has utility for energy technologies such as fuel cells.
Noble interactions between Ar and carbons are observed for carbons, such as carbon nanotubes and carbon blacks by means of mass-analyzed thermal desorption. The absorption states exist at around 300 K as well as at ar...Noble interactions between Ar and carbons are observed for carbons, such as carbon nanotubes and carbon blacks by means of mass-analyzed thermal desorption. The absorption states exist at around 300 K as well as at around 100 K. X-ray photoelectron spectroscopy reveals that Ar2p shows the chemical shifts. These results suggest that Ar is in charge and it is in valence state, or gives the evidence of the chemical interaction.展开更多
基金the National Natural Science Foundation of China for financial support.
文摘A new intercalation compound,Fe_(0.85)PS_(3)(4,4-bipyH)_(0.30)(4,4-bipy=4,4-bipyridine),is obtained by the intercalation of 4,4-bipyridine-2HCl with lamellar FePS_(3),which is characterized by elemental analysis,powder X-ray diffraction,infrared spectroscopy.By comparison with the pure FePS_(3),the lattice spacing of Fe0.85PS_(3)(4,4-bipyH)0.30 is expanded by~5.7,indicating that the ring plane of the vip is perpendicular to the layer of the host.The magnetic property of Fe0.85PS_(3)(4,4-bipyH)0.30 is studied with SQUID.It exhibits an antiferromagnetic phase transition with TN of about 70 K.
文摘Single carbon nanotubes (CNTs) have the sorption states at around 200 K, and show the poor desorption characteristics at around 300 K. The bamboo-like CNTs, HP1050 and the ground HP1050 (HP-1050G), show the desorption peaks at around 100 K and 140 K, respectively. Furthermore, HP1050G has the sorption states at around 300 - 400 K. On the basis of the sorption process, the ground bamboo-like CNT has a possibility for application to the room temperature storage of methane, which has utility for energy technologies such as fuel cells.
文摘The adsorption states of hydrogen at around 300 K are found on carbons by means of thermal desorption measurements. This sorption ability has utility for energy technologies such as fuel cells.
文摘Noble interactions between Ar and carbons are observed for carbons, such as carbon nanotubes and carbon blacks by means of mass-analyzed thermal desorption. The absorption states exist at around 300 K as well as at around 100 K. X-ray photoelectron spectroscopy reveals that Ar2p shows the chemical shifts. These results suggest that Ar is in charge and it is in valence state, or gives the evidence of the chemical interaction.
