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测定手性有机酸对映体纯度的新试剂 被引量:4
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作者 尤田耙 H.S.Mosher +1 位作者 k.okamoto 王炎 《有机化学》 SCIE CAS CSCD 北大核心 1990年第6期498-503,共6页
用NMR技术测定微量手性化合物的对映体纯度,已有多种方法。其中,加手性镧化物位移试剂法适用面最广,但对有机酸,结果常不理想。另一种使用较广的方法是加手性试剂,将样品中两对映体转变成非对映异构体,然后比较非对映基因NMR信号的强度... 用NMR技术测定微量手性化合物的对映体纯度,已有多种方法。其中,加手性镧化物位移试剂法适用面最广,但对有机酸,结果常不理想。另一种使用较广的方法是加手性试剂,将样品中两对映体转变成非对映异构体,然后比较非对映基因NMR信号的强度,确定原样品中对映体的组成比例。 展开更多
关键词 手性有机酸 对映体 纯度 手性胺
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Temperature and Nitric Oxide Generation in a Pulsed Arc Discharge Plasma 被引量:1
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作者 T.NAMIHIRA S.SAKAI +5 位作者 M.MATSUDA D.WANG T.KIYAN H.AKIYAMA k.okamoto K.TODA 《Plasma Science and Technology》 SCIE EI CAS CSCD 2007年第6期747-751,共5页
Nitric oxide (NO) is increasingly being used in medical treatments of high blood pressure, acute respiratory distress syndrome and other illnesses related to the lungs. Currently a NO inhalation system consists of a... Nitric oxide (NO) is increasingly being used in medical treatments of high blood pressure, acute respiratory distress syndrome and other illnesses related to the lungs. Currently a NO inhalation system consists of a gas cylinder of N2 mixed with a high concentration of NO. This arrangement is potentially risky due to the possibility of an accidental leak of NO from the cylinder. The presence of NO in the air leads to the formation of nitric dioxide (NO2), which is toxic to the lungs. Therefore, an on-site generator of NO would be highly desirable for medical doctors to use with patients with lung disease. To develop the NO inhalation system without a gas cylinder, which would include a high concentration of NO, NAMIHIRA et al have recently reported on the production of NO from room air using a pulsed arc discharge. In the present work, the temperature of the pulsed arc discharge plasma used to generate NO was measured to optimize the discharge condition. The results of the temperature measurements showed the temperature of the pulsed arc discharge plasma reached about 10,000 K immediately after discharge initiation and gradually decreased over tens of microseconds. In addition, it was found that NO was formed in a discharge plasma having temperatures higher than 9,000 K and a smaller input energy into the discharge plasma generates NO more efficiently than a larger one. 展开更多
关键词 pulsed arc discharge plasma temperature nitric oxide medical application
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自组织生长CdSe-ZnSe量子点的光致发光
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作者 郑著宏 k.okamoto +2 位作者 H.C.Ko Y.Kawakami Sg.Fujita 《中国科学(A辑)》 CSCD 2000年第4期342-346,共5页
利用不同温度下的光致发光和时间分辨光谱研究了生长在GaAs( 1 1 0 )衬底上的CdSe ZnSe自组织量子点的发光特性 ,发现浸润层量子阱的激子发光淬灭比量子点的淬灭过程快得多 ,量子点的激子辐射复合寿命远大于浸润层量子阱的激子复合寿命 ... 利用不同温度下的光致发光和时间分辨光谱研究了生长在GaAs( 1 1 0 )衬底上的CdSe ZnSe自组织量子点的发光特性 ,发现浸润层量子阱的激子发光淬灭比量子点的淬灭过程快得多 ,量子点的激子辐射复合寿命远大于浸润层量子阱的激子复合寿命 .根据不同尺寸的量子点复合寿命的差异 。 展开更多
关键词 自组织生长 光致发光 硒化镉 硒化锌 量子点
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