Co_(3)S_(4)electrocatalysts with mixed valences of Co ions and excellent structural stability possess favorable oxygen evolution reaction(OER)activity,yet challenges remain in fabricating rechargeable lithiumoxygen ba...Co_(3)S_(4)electrocatalysts with mixed valences of Co ions and excellent structural stability possess favorable oxygen evolution reaction(OER)activity,yet challenges remain in fabricating rechargeable lithiumoxygen batteries(LOBs)due to their poor OER performance,resulting from poor electrical conductivity and overly strong intermediate adsorption.In this work,fancy double heterojunctions on 1T/2H-MoS_(2)@Co_(3)S_(4)(1T/2H-MCS)were constructed derived from the charge donation from Co to Mo ions,thus inducing the phase transformation of Mo S_(2)from 2H to 1T.The unique features of these double heterojunctions endow the1T/2H-MCS with complementary catalysis during charging and discharging processes.It is worth noting that 1T-Mo S2@Co3S4could provide fast Co-S-Mo electron transport channels to promote ORR/OER kinetics,and 2H-MoS_(2)@Co_(3)S_(4)contributed to enabling moderate egorbital occupancy when adsorbed with oxygen-containing intermediates.On the basis,the Li_(2)O_(2)nucleation route was changed to solution and surface dual pathways,improving reversible deposition and decomposition kinetics.As a result,1T/2H-MCS cathodes exhibit an improved electrocatalytic performance compared with those of Co_(3)S_(4)and Mo S2cathodes.This innovative heterostructure design provides a reliable strategy to construct efficient transition metal sulfide catalysts by improving electrical conductivity and modulating adsorption toward oxygenated intermediates for LOBs.展开更多
Acute respiratory tract infections(ARTIs)are among the leading causes of morbidity and mortality in children worldwide.Human adenovirus(HAdV)infections are estimated to account for at least 5%of pediatric ARTIs.The ci...Acute respiratory tract infections(ARTIs)are among the leading causes of morbidity and mortality in children worldwide.Human adenovirus(HAdV)infections are estimated to account for at least 5%of pediatric ARTIs.The circulated genotypes of HAdV and the correlation between genotype and clinical manifestations in Wuhan,China,before and after the complete relaxation of nonpharmaceutical interventions against severe acute respiratory syndrome coronavirus 2,remain unknown.Here,101 HAdV strains were isolated from throat swab samples collected from hospitalized children with ARTIs who tested positive for HAdV nucleic acid.Of these,sixty-six strains from 2022 to twenty-three strains from 2023 were successfully genotyped and subjected to phylogenetic analysis based on the hexon,penton base,and fiber genes.Six genotypes,B3,C1,C2,C5,C104,and C108 were identified.HAdV-B3(84.85%)was the most prevalent type in 2022,while HAdV-C(86.96%),including C1,C2,C108,and C104,was the most prevalent in 2023.These strains were phylogenetically related to strains from Japan,China,and the United States in recent years.When comparing clinical characteristics,pediatric patients infected with B3,C1,C2,C5,C104,or C108 exhibited similar clinical manifestations,primarily fever and cough,but varying interleukin(IL)-10 levels.In conclusion,from June 2022 to September 2023,the circulated genotypes of HAdV in Wuhan included B3,C1,C2,C108,C5,and C104.The endemic pattern of HAdV in Wuhan,China,shifted from species B as the dominant type in 2022 to species C in 2023.展开更多
PbSe materials,with their narrow bandgap,excellent optical absorption and outstanding optical response,are ideal for infrared photodetectors,exhibiting unique advantages in optical communication,infrared imaging and t...PbSe materials,with their narrow bandgap,excellent optical absorption and outstanding optical response,are ideal for infrared photodetectors,exhibiting unique advantages in optical communication,infrared imaging and thermal detection.Nevertheless,PbSe typically has a non-layered crystal structure and inherent isotropy,making the synthesis of low-dimensional nanomaterials challenging.Besides,PbSe photoconductive detectors suffer from high dark current due to intrinsic defects and thermally excited carriers,which is detrimental to device performance.Here,we utilized physical vapor deposition(PVD)method to grow high-quality PbSe nanosheets and combined them with two-dimensional(2D)transition metal dichalcogenides(TMDs)material WSe_(2)to fabricate a self-powered PbSe/WSe_(2)p-n heterostructure photodetector.Under illumination with a 650 nm laser at a power density of 128.97 mW/cm^(2)and 0 V bias,the PbSe/WSe_(2)heterojunction device exhibited significant photovoltaic characteristics and generated a short-circuit current of 161.7 nA.Furthermore,under 0.02 mW/cm^(2)of 650 nm laser illumination at 0 V bias,the device achieved an excellent responsivity(R)of 15.6 A/W and a specific detectivity(D^(*))of 1.08×10^(11)Jones.And the response speed of the heterojunction device at 0 V(511µs/74µs)was three orders of magnitude faster than that of PbSe nanosheets(93 ms/104 ms).The device also demonstrated broadband detection capabilities from 405 nm to 1550 nm and excellent imaging performance in the near-infrared region at 0 V bias.In summary,the outstanding photoelectric detection performance and imaging capabilities of the PbSe/WSe_(2)heterojunction nanosheet detector indicate its significant potential for applications in miniaturized,low-noise,broadband,high-speed and high-performance photodetectors.展开更多
Constructing S-scheme heterojunctions preserves the intrinsic redox capabilities of both semiconductors while promoting the separation of photogenerated electrons and holes,making it a promising approach for enhancing...Constructing S-scheme heterojunctions preserves the intrinsic redox capabilities of both semiconductors while promoting the separation of photogenerated electrons and holes,making it a promising approach for enhancing the properties of semiconductors.In this study,an S-scheme Cd_(0.8)Zn_(0.2)S-CeO_(2)(CZS-CeO_(2))heterojunction was successfully fabricated via the in-situ growth of CZS nanowires on CeO_(2)nanocubes.The S-scheme charge-transfer mechanism of the CZS-CeO_(2)composites during photocatalytic reactions was confirmed through in-situ X-ray photoelectron spectroscopy and density functional theory calculations.These results demonstrate that the interfacial electric field(IEF)significantly facilitates charge separation and transport within the heterojunction.Consequently,the CZS-CeO_(2)composites exhibited excellent photocatalytic hydrogen production performance under simulated sunlight irradiation,surpassing that of blank CZS.Particularly,the optimal photocatalytic hydrogen generation rate for CZS-15%CeO_(2)reached 58 mmol·g^(-1)·h^(-1),approximately 8.8 times higher than that of blank CZS.After five consecutive cycles of testing,CZS-15%CeO_(2)retained a relatively high level of activity.This enhanced stability can be attributed to the fabrication of S-scheme heterojunctions,which effectively suppressed hole-induced photocorrosion of CZS.This investigation provides a beneficial reference for the rational design of S-scheme heterojunction photocatalysts for efficient and stable photocatalytic hydrogen production.展开更多
We investigate the possible Josephson diode effect(JDE)in a two-dimensional(2D)nonmagnetic planar s-wave superconductor junction,which is constructed on a spin-collinear d-wave altermagnet(AM)material in the presence ...We investigate the possible Josephson diode effect(JDE)in a two-dimensional(2D)nonmagnetic planar s-wave superconductor junction,which is constructed on a spin-collinear d-wave altermagnet(AM)material in the presence of Rashba spin-orbit interaction.It is demonstrated that the JDE is critically dependent on the crystalline axis of the AM relative to the current direction.The d_(x^(2)-y^(2))magnetization symmetry can support a JDE whereas the dxy symmetry does not facilitate it.The JDE efficiency can reach up to 40%and can be adjusted by an additional asymmetric gate voltage applied to the non-superconducting region of the junction,including control of its polarity.Our findings provide an electrical means to control the JDE within a non-magnetic AM-based superconducting junction.展开更多
In this study,we present the fabrication of vertical SnO/β-Ga_(2)O_(3) heterojunction diode(HJD)via radio frequency(RF)reactive magnetron sputtering.The valence and conduction band offsets betweenβ-Ga_(2)O_(3) and S...In this study,we present the fabrication of vertical SnO/β-Ga_(2)O_(3) heterojunction diode(HJD)via radio frequency(RF)reactive magnetron sputtering.The valence and conduction band offsets betweenβ-Ga_(2)O_(3) and SnO are determined to be 2.65and 0.75 eV,respectively,through X-ray photoelectron spectroscopy,showing a type-Ⅱband alignment.Compared to its Schottky barrier diode(SBD)counterpart,the HJD presents a comparable specific ON-resistances(R_(on,sp))of 2.8 mΩ·cm^(2) and lower reverse leakage current(I_R),leading to an enhanced reverse blocking characteristics with breakdown voltage(BV)of 1675 V and power figure of merit(PFOM)of 1.0 GW/cm~2.This demonstrates the high quality of the SnO/β-Ga_(2)O_(3) heterojunction interface.Silvaco TCAD simulation further reveals that electric field crowding at the edge of anode for the SBD was greatly depressed by the introduction of SnO film,revealing the potential application of SnO/β-Ga_(2)O_(3) heterojunction in the futureβ-Ga_(2)O_(3)-based power devices.data mining,AI training,and similar technologies,are reserved.展开更多
Microorganisms are crucial for the breakdown of proteins and lipids in dry-fermented sausages and are intimately associated with the flavor profile of sausages.In this study,we used a mixed starter culture to ferment ...Microorganisms are crucial for the breakdown of proteins and lipids in dry-fermented sausages and are intimately associated with the flavor profile of sausages.In this study,we used a mixed starter culture to ferment sausages and investigated the flavor turnover.During the fermentation of salami,the data from free amino acids(FAAs),free fatty acids(FFAs)and volatile flavor substances were used to assess the quality of salami.At the end of fermentation,the total FAAs increased from 1171.32 to 4582.48 mg/kg in the control group and 5053.25 mg/kg in the experimental group.Additionally,following inoculation with the mixed starter culture,the levels of glutamic acid,lysine,methionine,valine and leucine were significantly higher(P<0.05)than those in the control group.Oleic acid(C_(18:1))and chondritic acid(C_(16:0))were the two most abundant FFAs in both salami samples with 45.86%and 26.07%on the 23^(th)day in mixed culture inoculated salami.The mixed starter inoculated group had significantly lower saturated fatty acids and higher percentage levels of monounsaturated fatty acids than the control group(P<0.05).In the volatile flavor substance analysis,a total of 61 volatile compounds were found.Ester compounds were progressively enriched with drying time,significantly increasing the flavor substances,like ethyl diphosgene,1-octen-3-ol,and 2,3-butanediol at P<0.05.The correlation analysis between the core flora and volatile flavor compounds during fermentation and maturation of salami indicates Lactobacillus sakei and Lactobacillus rhamnosus were significantly higher and positively correlated with the major volatile organic compounds,which are the key core microorganisms affecting the flavor quality of fermented sausages.展开更多
Rapidly improving infertile croplands and enhancing their soil organic carbon(SOC)pool necessitate substantial organic materials incorporation.Converting loose crop straw into granulated form facilitates uniform incor...Rapidly improving infertile croplands and enhancing their soil organic carbon(SOC)pool necessitate substantial organic materials incorporation.Converting loose crop straw into granulated form facilitates uniform incorporation within the plough soil layer.As an innovative soil amelioration approach,the efficiency and patterns of SOC accumulation remain unclear.Two field experiments were conducted in infertile subtropical upland and paddy soils with 0,30,60,and 90 Mg ha^(-1)granulated straw incorporation.After one year,SOC accumulation efficiency from straw input remained stable in upland(30.8–37.5%)with increasing amounts of straw incorporation,while declined from 60.0 to 38.3%in paddy.In both croplands,the contributions of lignin phenols to SOC increased with increasing straw incorporation,while the contributions from amino sugars remained constant at higher straw input levels.Subsequently,the ratios of lignin phenols to amino sugars increased with increasing straw incorporation,indicating faster plant residue accumulation compared to microbial necromass,as the granulation approach limited microbial involvement in straw transformation.Thus,single-time incorporation of substantial granulated straw presents an effective agricultural strategy for rapid amelioration of infertile croplands.展开更多
To address the issue of residual pollution caused by polyethylene mulch,this study explored the effects of different mulching methods on the soil environment of the yam field,as well as on yam yield and quality.The ex...To address the issue of residual pollution caused by polyethylene mulch,this study explored the effects of different mulching methods on the soil environment of the yam field,as well as on yam yield and quality.The experiment comprised six treatments in total:one non-mulched treatment served as the control(CK),along with five different film-mulched treatments,namely PE,FZS12,FZS15,FC12,and FC15.The degradation of these films and their effects on soil physicochemical properties,microbial community,yam yield and quality were compared.The results showed that the FZS12 treatment achieved grade 5 degradation by the end of the planting period.Compared with PE treatment,the total soluble sugar content and yield of yam treated with FZS12 were significantly increased by 35.78%and 74.97%,respectively(p<0.05).Compared with CK and PE treatments,FZS12 significantly increased soil available nitrogen by 31.62%and 6.20%,respectively(p<0.05),and significantly increased soil available phosphorus by 8.58%and 4.45%,respectively(p<0.05).Soil pH,available nitrogen,and available phosphorus were the main environmental factors affecting the soil bacterial community.The FZS12 treatment significantly increased the relative abundances of soil bacteria phylum including Acidobacteriota,Myxococcota,Patescibacteria,and Proteobacteria compared with the CK and PE treatments.Functional prediction using Picrust2 revealed that the FZS12 treatment had significantly higher levels of signal transduction and amino acid metabolism than the CK and PE treatments.In conclusion,covering with 12μm PBAT/PLA humic acid biodegradable film enhances yam yield and total soluble sugar content by shaping beneficial soil microbial communities,activating soil nutrients.展开更多
Background The cellular basis of testicular development and spermatogenesis for the extreme sperm density in chickens(100-fold higher than mammals)remains poorly defined.A comprehensive understanding of the molecular ...Background The cellular basis of testicular development and spermatogenesis for the extreme sperm density in chickens(100-fold higher than mammals)remains poorly defined.A comprehensive understanding of the molecular characteristics driving poultry testicular development is crucial for explaining this enhanced spermatogenic capacity.Results Here,we first established a single-cell transcriptome profile of chicken testes from hatching to maturity,identifying the dynamic transcriptional characteristics of germ cell fate transition and exploring the developmental characteristics of Sertoli cells and Leydig cells.Multi-species comparisons revealed a higher proportion of germ cells and the unique adaptations of Sertoli cells in chicken testes.Most importantly,our results demonstrated that Sertoli cells dominated in somatic composition of mature chicken testes,and proliferating Sertoli cells persisted in chicken testes even after sexual maturity,while no proliferating Sertoli cells in mammals.We also found a richer interaction network between chicken testicular cells,especially the specific activation of Sertoli cell interaction signals,such as TGF-β,BMP,EGF,and activin.These adaptations of Sertoli cells may support the spermatogenic superiority in chickens.Additionally,our results indicated that cAMP responsive element binding protein 5(CREB5)played a crucial role in maintaining the maturation and function of chicken Sertoli cells,and circadian rhythm promoted testosterone secretion and the development of Leydig cells.Conclusion Our study revealed that the sustained proliferative capacity of Sertoli cells,their enriched signaling network,and the regulatory roles of CREB5 and circadian rhythms collectively represented unique testicular adaptations in chickens.These findings may hold extraordinary significance in understanding the molecular characteristics of poultry testicular development,and provide a plausible framework for explaining enhanced spermatogenesis in poultry.展开更多
Fractal assembly in discrete structures,especially for artificial supramolecular species,has attracted significantly increased interest over the past two decades.In this study,we present the precisely controlled fract...Fractal assembly in discrete structures,especially for artificial supramolecular species,has attracted significantly increased interest over the past two decades.In this study,we present the precisely controlled fractal expanding synthesis of a novel triangular prism supramolecule featuring Sierpiński triangular face,which was achieved through a module-intervened self-expansion strategy.The homoleptic S1 was firstly synthesized through the assembly of ligand L1 with Zn^(2+)ions.Based on the triangular-faced prism S1,we further introduced Sierpiński triangular faces on the section of the heteroleptic supramolecular cage S2 with an expanded inner cavity and more abundant active sites for photocatalytic properties.The topotactic architectures for both S1 and S2 were fully characterized by nuclear magnetic resonance spectroscopy,high-resolution electrospray ionization mass spectrometry,transmission electron microscopy,and atomic force microscopy.Furthermore,the enhanced photocatalytic activity of the fractal expanded S2 was performed via the superior amine oxidative efficiency over S1.This study proposes the unprecedented fractal expanding strategy for three-dimensional supramolecular species with higher complexity,potentially opening new avenues for structural regulation of artificial fractal molecules.展开更多
Theintegration of human factors into artificial intelligence(AI)systems has emerged as a critical research frontier,particularly in reinforcement learning(RL),where human-AI interaction(HAII)presents both opportunitie...Theintegration of human factors into artificial intelligence(AI)systems has emerged as a critical research frontier,particularly in reinforcement learning(RL),where human-AI interaction(HAII)presents both opportunities and challenges.As RL continues to demonstrate remarkable success in model-free and partially observable environments,its real-world deployment increasingly requires effective collaboration with human operators and stakeholders.This article systematically examines HAII techniques in RL through both theoretical analysis and practical case studies.We establish a conceptual framework built upon three fundamental pillars of effective human-AI collaboration:computational trust modeling,system usability,and decision understandability.Our comprehensive review organizes HAII methods into five key categories:(1)learning from human feedback,including various shaping approaches;(2)learning from human demonstration through inverse RL and imitation learning;(3)shared autonomy architectures for dynamic control allocation;(4)human-in-the-loop querying strategies for active learning;and(5)explainable RL techniques for interpretable policy generation.Recent state-of-the-art works are critically reviewed,with particular emphasis on advances incorporating large language models in human-AI interaction research.To illustrate some concepts,we present three detailed case studies:an empirical trust model for farmers adopting AI-driven agricultural management systems,the implementation of ethical constraints in roboticmotion planning through human-guided RL,and an experimental investigation of human trust dynamics using a multi-armed bandit paradigm.These applications demonstrate how HAII principles can enhance RL systems’practical utility while bridging the gap between theoretical RL and real-world human-centered applications,ultimately contributing to more deployable and socially beneficial intelligent systems.展开更多
Long-term manure application has the potential to alleviate soil acidification, and increase carbon sequestration and nutrient availability, thus improving cropland fertility. However, the mechanisms behind greenhouse...Long-term manure application has the potential to alleviate soil acidification, and increase carbon sequestration and nutrient availability, thus improving cropland fertility. However, the mechanisms behind greenhouse gas N_(2)O emissions from acidic soil mediated by long-term manure application remain poorly understood. Herein, we investigated N_(2)O emission and its linkage with gross N mineralization and nitrification rates, as well as nitrifying and denitrifying microbes in an acidic upland soil subjected to 36-year fertilization treatments, including an unfertilized control(CK), inorganic fertilizer(F), 2× rate of inorganic fertilizer(2F), manure(M), and the combination of inorganic fertilizer and manure(FM) treatments. Compared to the CK treatment(1.34 μg N kg^(-1) d^(-1)), fertilization strongly increased N_(2)O emissions by 34-fold on average, with more pronounced increases in the manure-amendment(10.6-169 μg N kg^(-1) d^(-1)) than those in the inorganic fertilizer treatments(3.26-5.51 μg N kg^(-1) d^(-1)). The manure amendment-stimulated N_(2)O emissions were highly associated with increased soil pH, mean weight diameter of soil aggregates, substrate availability(e.g., particulate organic carbon, NO_(3)^(-)and available phosphorus), gross N mineralization rates, denitrifier abundances and the(nirK+nirS)/nosZ ratio. These findings suggest that the increased N_(2)O emissions primarily resulted from alleviated acidification, increased substrate availability and improved soil structure, thus enhancing microbial N mineralization and favoring N_(2)O^(-)producing denitrifiers over N_(2)O consumers. Moreover, ammonia-oxidizing bacteria(AOB) rather than ammonia-oxidizing archaea(AOA) positively correlated with soil NO_(3)^(-)concentration and N_(2)O emissions, indicating that nitrification indirectly contributed to N_(2)O production by supplying NO_(3)^(-)for denitrification. Collectively, manure amendment potentially stimulates N_(2)O emissions, primarily resulting from alleviated soil acidification and increased substrate availability, thus enhancing N mineralization and denitrifier-mediated N_(2)O production. Our findings suggest that consideration should be given to the greenhouse gas budgets of agricultural ecosystems when applying manure for managing the pH and fertility of acidic soils.展开更多
Thermally activated delayed fluorescence(TADF) emitters show great potential in photodynamic therapy(PDT) and bioimaging,leveraging their structural adaptability,efficient reverse intersystem crossing(RISC),robust pho...Thermally activated delayed fluorescence(TADF) emitters show great potential in photodynamic therapy(PDT) and bioimaging,leveraging their structural adaptability,efficient reverse intersystem crossing(RISC),robust photosensitizing capability,and high photoluminescence quantum yields(PLQYs).Herein,we developed a new class of donor-acceptor-donor(D-A-D)-type TADF materials by connecting the highly twisted indolizine-benzophenone electron acceptors with a series of electron donors including phenoxazine,phenothiazine and 9,9-dimethyl-9,10-dihydroacridine.These materials exhibit enhanced TADF properties,aggregation-induced emission(AIE),alongside high reactive oxygen species(ROS) generation efficiency,effectively mitigating aggregation-caused quenching observed in traditional fluorophores.Among them,IDP-p-PXZ,incorporating the phenoxazine donor,stands out with the smallest singlet-triplet splitting energy(ΔE_(ST)) and the highest spin-orbit coupling matrix elements(SOCMEs).Upon encapsulation into 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000](DSPE-PEG2000) nanoparticles(NPs),IDP-p-PXZ demonstrates extended delayed fluorescence lifetimes in air,an exceptionally fast intersystem crossing(ISC) rate constant(k_(ISC)) of 3.4×10^(7)s^(-1),and a radiative rate constant(k_(r)) of 5.05×10^(6)s^(-1).These NPs exhibit superior biocompatibility,efficient cellular internalization,and potent ROS production,enabling effective simultaneous PDT and confocal fluorescence imaging in HeLa cells.展开更多
This study extends the self-propelled particle(SPP)model by incorporating a limited vision cone and local density sensing.The results reveal that clusters can simultaneously exhibit velocity polarization and spatial c...This study extends the self-propelled particle(SPP)model by incorporating a limited vision cone and local density sensing.The results reveal that clusters can simultaneously exhibit velocity polarization and spatial cohesion within specific ranges of vision angle and density threshold.The dependence of the dynamical features,including the order parameter and density variation,on the threshold and visual cone is investigated.Furthermore,a critical threshold is identified,which governs the transition between ordered and disordered states and is closely linked to density fluctuations and noise intensity.The clustering results show that the model is explained by the chasing mechanism responsible for cluster formation,density,and shape.These results may stimulate practical applications in swarm maneuvering.展开更多
A series of leaching and electrochemical experiments were conducted to elucidate the critical role of hydrogen sulfide(H_(2)S)in copper-driven reduction of chalcopyrite.Results demonstrate that in the absence of H_(2)...A series of leaching and electrochemical experiments were conducted to elucidate the critical role of hydrogen sulfide(H_(2)S)in copper-driven reduction of chalcopyrite.Results demonstrate that in the absence of H_(2)S,metallic copper converts chalcopyrite into bornite(Cu_(5)FeS_(4)).However,the introduction of H_(2)S promotes the formation of chalcocite(Cu_(2)S)by altering the oxidation pathway of copper.Electrochemical analysis demonstrates that the presence of H₂S significantly reduces the corrosion potential of copper from 0.251 to−0.223 V(vs SHE),reaching the threshold necessary for the formation of Cu_(2)S.Nevertheless,excessive H_(2)S triggers sulfate reduction via the reaction of 8Cu+H_(2)SO_(4)+3H_(2)S=4Cu_(2)S+4H_(2)O(ΔG=−519.429 kJ/mol at 50℃),leading to inefficient copper utilization.展开更多
The environmental wind tunnel of high-speed railway trains serves as a crucial experimental facility for the research and development of high-speed railway technology.The refrigeration system within the wind tunnel is...The environmental wind tunnel of high-speed railway trains serves as a crucial experimental facility for the research and development of high-speed railway technology.The refrigeration system within the wind tunnel is an important subsystem.However,the design of the wind tunnel refrigeration system management program presents significant scientific challenges and limitations.Traditional management approaches in wind tunnel refrigeration systems suffer from prolonged decision-making times and reliance on experiential knowledge,necessitating the need for intelligent transformation.This paper aims to address these issues by exploring existing intelligent management methodologies and defining the concept of a wind tunnel intelligent laboratory along with its primary modules.Furthermore,we propose a water cooler failure prediction model based on the existing equipment model of the wind tunnel's refrigeration system.This model effectively predicts the Remaining Useful Life(RUL) of the water cooler in the case of fouling failure,contributing to enhanced efficiency,cost reduction,and safety improvements in laboratories.展开更多
Magnetorheological(MR)bearings,with their field-controllable rheological properties,offer new possibilities for control of rotor instabilities.However,their nonlinear dynamic behaviors and the underlying physical mech...Magnetorheological(MR)bearings,with their field-controllable rheological properties,offer new possibilities for control of rotor instabilities.However,their nonlinear dynamic behaviors and the underlying physical mechanisms governing these instabilities remain insufficiently understood.This work develops a coupled MR bearingrotor system model,where the oil film force is derived from a novel bilinear constitutive equation to capture the field-sensitive shear behaviors of MR fluids.Complex nonlinear dynamic behaviors including period doubling,quasi-period,and chaos are revealed,which emerge from the interaction between oil film vortex dynamics and magnetic excitation.The critical instability mechanism is identified from the evolution of intrinsic dynamic characteristics of MR bearings.When the whirl speed within the oil film reaches approximately half of the rotor speed,the damping force balances the destabilizing force,thereby defining a critical threshold beyond which the system transitions to instability.This threshold can be effectively tuned by adjusting the excitation current,which modifies the yield stress of MR fluids and consequently regulates the damping force.As a result,the nonlinear vibrations of oil whirl and whip can be suppressed,and the system stability can be significantly enhanced.These findings provide both theoretical insight and practical guidance for the design and control of MR bearing supported rotor systems.展开更多
High-performance photodetectors are expected to open up revolutionary opportunities in many application fields, such as environment monitoring, military, optical communication and biomedical science. Combining two-dim...High-performance photodetectors are expected to open up revolutionary opportunities in many application fields, such as environment monitoring, military, optical communication and biomedical science. Combining two-dimensional materials(which have tunable optical absorption and high carrier mobility) with organic materials(which are abundant with low cost, high flexibility and large-area scalability) to form thin-film heterojunctions, high-responsivity photodetectors could be predicted with fast response speed in a wide spectra region.In this review, we give a comprehensive summary of photodetectors based on two-dimensional materials and organic thin-film heterojunctions, which includes hybrid assisted enhanced devices, single-layer enhanced devices, vertical heterojunction devices and tunable vertical heterojunction devices. We also give a systematic classification and perspectives on the future development of these types of photodetectors.展开更多
基金financially supported by the National Natural Science Foundation of China(U21A20311,U24A2040,52171141,52272117)the Natural Science Foundation of Shandong Province(ZR2022JQ19)+3 种基金the Key Technology Research Project of Shandong Province(2023CXGC010202)the Taishan Industrial Experts Program(TSCX202306142)the Core Facility Sharing Platform of Shandong Universitythe Foundation of Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education),Nankai University。
文摘Co_(3)S_(4)electrocatalysts with mixed valences of Co ions and excellent structural stability possess favorable oxygen evolution reaction(OER)activity,yet challenges remain in fabricating rechargeable lithiumoxygen batteries(LOBs)due to their poor OER performance,resulting from poor electrical conductivity and overly strong intermediate adsorption.In this work,fancy double heterojunctions on 1T/2H-MoS_(2)@Co_(3)S_(4)(1T/2H-MCS)were constructed derived from the charge donation from Co to Mo ions,thus inducing the phase transformation of Mo S_(2)from 2H to 1T.The unique features of these double heterojunctions endow the1T/2H-MCS with complementary catalysis during charging and discharging processes.It is worth noting that 1T-Mo S2@Co3S4could provide fast Co-S-Mo electron transport channels to promote ORR/OER kinetics,and 2H-MoS_(2)@Co_(3)S_(4)contributed to enabling moderate egorbital occupancy when adsorbed with oxygen-containing intermediates.On the basis,the Li_(2)O_(2)nucleation route was changed to solution and surface dual pathways,improving reversible deposition and decomposition kinetics.As a result,1T/2H-MCS cathodes exhibit an improved electrocatalytic performance compared with those of Co_(3)S_(4)and Mo S2cathodes.This innovative heterostructure design provides a reliable strategy to construct efficient transition metal sulfide catalysts by improving electrical conductivity and modulating adsorption toward oxygenated intermediates for LOBs.
基金supported by the projects of National Virus Resource Center(NVRC-PY-03,E1YZ020501)Natural Science Foundation of Hubei Province(2022CFB564)+4 种基金Foundation of Hubei Provincial Health Commission(WJ2023M108)National Basic Science Data Sharing Platform(no.2018ZX10101004)National Basic Science Data Sharing Service Platform(no.NBSDC-DB-13)the International Cooperation Base of Hubei Province for Infection and Immunitysupported by Outstanding Medical Young Scholars of Hubei Province and Wuhan Young and Middle-aged Medical Backbone Talent Program.
文摘Acute respiratory tract infections(ARTIs)are among the leading causes of morbidity and mortality in children worldwide.Human adenovirus(HAdV)infections are estimated to account for at least 5%of pediatric ARTIs.The circulated genotypes of HAdV and the correlation between genotype and clinical manifestations in Wuhan,China,before and after the complete relaxation of nonpharmaceutical interventions against severe acute respiratory syndrome coronavirus 2,remain unknown.Here,101 HAdV strains were isolated from throat swab samples collected from hospitalized children with ARTIs who tested positive for HAdV nucleic acid.Of these,sixty-six strains from 2022 to twenty-three strains from 2023 were successfully genotyped and subjected to phylogenetic analysis based on the hexon,penton base,and fiber genes.Six genotypes,B3,C1,C2,C5,C104,and C108 were identified.HAdV-B3(84.85%)was the most prevalent type in 2022,while HAdV-C(86.96%),including C1,C2,C108,and C104,was the most prevalent in 2023.These strains were phylogenetically related to strains from Japan,China,and the United States in recent years.When comparing clinical characteristics,pediatric patients infected with B3,C1,C2,C5,C104,or C108 exhibited similar clinical manifestations,primarily fever and cough,but varying interleukin(IL)-10 levels.In conclusion,from June 2022 to September 2023,the circulated genotypes of HAdV in Wuhan included B3,C1,C2,C108,C5,and C104.The endemic pattern of HAdV in Wuhan,China,shifted from species B as the dominant type in 2022 to species C in 2023.
基金supported financially by National Key Research and Development Program of China(No.2023YFB3611400)National Natural Science Foundation of China(Nos.62175026,62305047)+4 种基金China National Postdoctoral Program for Innovative Talents(No.BX20230059)China Postdoctoral Science Foundation(No.2023M740509)Guangdong Basic and Applied Basic Research Foundation(No.2024A1515010005)National Key Laboratory of Intense Pulsed Radiation Simulation and Effect Research Foundation(No.NKLIPR2315)Natural Science Foundation of Sichuan Province(No.24NSFSC1465).
文摘PbSe materials,with their narrow bandgap,excellent optical absorption and outstanding optical response,are ideal for infrared photodetectors,exhibiting unique advantages in optical communication,infrared imaging and thermal detection.Nevertheless,PbSe typically has a non-layered crystal structure and inherent isotropy,making the synthesis of low-dimensional nanomaterials challenging.Besides,PbSe photoconductive detectors suffer from high dark current due to intrinsic defects and thermally excited carriers,which is detrimental to device performance.Here,we utilized physical vapor deposition(PVD)method to grow high-quality PbSe nanosheets and combined them with two-dimensional(2D)transition metal dichalcogenides(TMDs)material WSe_(2)to fabricate a self-powered PbSe/WSe_(2)p-n heterostructure photodetector.Under illumination with a 650 nm laser at a power density of 128.97 mW/cm^(2)and 0 V bias,the PbSe/WSe_(2)heterojunction device exhibited significant photovoltaic characteristics and generated a short-circuit current of 161.7 nA.Furthermore,under 0.02 mW/cm^(2)of 650 nm laser illumination at 0 V bias,the device achieved an excellent responsivity(R)of 15.6 A/W and a specific detectivity(D^(*))of 1.08×10^(11)Jones.And the response speed of the heterojunction device at 0 V(511µs/74µs)was three orders of magnitude faster than that of PbSe nanosheets(93 ms/104 ms).The device also demonstrated broadband detection capabilities from 405 nm to 1550 nm and excellent imaging performance in the near-infrared region at 0 V bias.In summary,the outstanding photoelectric detection performance and imaging capabilities of the PbSe/WSe_(2)heterojunction nanosheet detector indicate its significant potential for applications in miniaturized,low-noise,broadband,high-speed and high-performance photodetectors.
文摘Constructing S-scheme heterojunctions preserves the intrinsic redox capabilities of both semiconductors while promoting the separation of photogenerated electrons and holes,making it a promising approach for enhancing the properties of semiconductors.In this study,an S-scheme Cd_(0.8)Zn_(0.2)S-CeO_(2)(CZS-CeO_(2))heterojunction was successfully fabricated via the in-situ growth of CZS nanowires on CeO_(2)nanocubes.The S-scheme charge-transfer mechanism of the CZS-CeO_(2)composites during photocatalytic reactions was confirmed through in-situ X-ray photoelectron spectroscopy and density functional theory calculations.These results demonstrate that the interfacial electric field(IEF)significantly facilitates charge separation and transport within the heterojunction.Consequently,the CZS-CeO_(2)composites exhibited excellent photocatalytic hydrogen production performance under simulated sunlight irradiation,surpassing that of blank CZS.Particularly,the optimal photocatalytic hydrogen generation rate for CZS-15%CeO_(2)reached 58 mmol·g^(-1)·h^(-1),approximately 8.8 times higher than that of blank CZS.After five consecutive cycles of testing,CZS-15%CeO_(2)retained a relatively high level of activity.This enhanced stability can be attributed to the fabrication of S-scheme heterojunctions,which effectively suppressed hole-induced photocorrosion of CZS.This investigation provides a beneficial reference for the rational design of S-scheme heterojunction photocatalysts for efficient and stable photocatalytic hydrogen production.
基金supported by the National Natural Science Foundation of China(Grant No.12174051)the Fundamental Research Funds for Central Universities。
文摘We investigate the possible Josephson diode effect(JDE)in a two-dimensional(2D)nonmagnetic planar s-wave superconductor junction,which is constructed on a spin-collinear d-wave altermagnet(AM)material in the presence of Rashba spin-orbit interaction.It is demonstrated that the JDE is critically dependent on the crystalline axis of the AM relative to the current direction.The d_(x^(2)-y^(2))magnetization symmetry can support a JDE whereas the dxy symmetry does not facilitate it.The JDE efficiency can reach up to 40%and can be adjusted by an additional asymmetric gate voltage applied to the non-superconducting region of the junction,including control of its polarity.Our findings provide an electrical means to control the JDE within a non-magnetic AM-based superconducting junction.
基金supported by the National Natural Science Foundation of China(NSFC,No.62074048)the Key Research and Development Plan of Anhui Province(No.2022f04020007)the Natural Science Foundation of Anhui Province(No.2208085MF177)。
文摘In this study,we present the fabrication of vertical SnO/β-Ga_(2)O_(3) heterojunction diode(HJD)via radio frequency(RF)reactive magnetron sputtering.The valence and conduction band offsets betweenβ-Ga_(2)O_(3) and SnO are determined to be 2.65and 0.75 eV,respectively,through X-ray photoelectron spectroscopy,showing a type-Ⅱband alignment.Compared to its Schottky barrier diode(SBD)counterpart,the HJD presents a comparable specific ON-resistances(R_(on,sp))of 2.8 mΩ·cm^(2) and lower reverse leakage current(I_R),leading to an enhanced reverse blocking characteristics with breakdown voltage(BV)of 1675 V and power figure of merit(PFOM)of 1.0 GW/cm~2.This demonstrates the high quality of the SnO/β-Ga_(2)O_(3) heterojunction interface.Silvaco TCAD simulation further reveals that electric field crowding at the edge of anode for the SBD was greatly depressed by the introduction of SnO film,revealing the potential application of SnO/β-Ga_(2)O_(3) heterojunction in the futureβ-Ga_(2)O_(3)-based power devices.data mining,AI training,and similar technologies,are reserved.
基金supported by the National Key Research and Development Program of China(2023YFD2100104)Henan Provincial Major Science and Technology Special Fund(231100110400).
文摘Microorganisms are crucial for the breakdown of proteins and lipids in dry-fermented sausages and are intimately associated with the flavor profile of sausages.In this study,we used a mixed starter culture to ferment sausages and investigated the flavor turnover.During the fermentation of salami,the data from free amino acids(FAAs),free fatty acids(FFAs)and volatile flavor substances were used to assess the quality of salami.At the end of fermentation,the total FAAs increased from 1171.32 to 4582.48 mg/kg in the control group and 5053.25 mg/kg in the experimental group.Additionally,following inoculation with the mixed starter culture,the levels of glutamic acid,lysine,methionine,valine and leucine were significantly higher(P<0.05)than those in the control group.Oleic acid(C_(18:1))and chondritic acid(C_(16:0))were the two most abundant FFAs in both salami samples with 45.86%and 26.07%on the 23^(th)day in mixed culture inoculated salami.The mixed starter inoculated group had significantly lower saturated fatty acids and higher percentage levels of monounsaturated fatty acids than the control group(P<0.05).In the volatile flavor substance analysis,a total of 61 volatile compounds were found.Ester compounds were progressively enriched with drying time,significantly increasing the flavor substances,like ethyl diphosgene,1-octen-3-ol,and 2,3-butanediol at P<0.05.The correlation analysis between the core flora and volatile flavor compounds during fermentation and maturation of salami indicates Lactobacillus sakei and Lactobacillus rhamnosus were significantly higher and positively correlated with the major volatile organic compounds,which are the key core microorganisms affecting the flavor quality of fermented sausages.
基金financially supported by the National Key R&D Program of China(2021YFD1901203 and 2021YFD1901204)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0440404)+2 种基金the National Natural Science Foundation of China(42377348)the Science Foundation for Distinguished Young Scholars of Hunan Province,China(2024JJ2052)the Natural Science Foundation of Guangxi,China(2025GXNSFAA069337)。
文摘Rapidly improving infertile croplands and enhancing their soil organic carbon(SOC)pool necessitate substantial organic materials incorporation.Converting loose crop straw into granulated form facilitates uniform incorporation within the plough soil layer.As an innovative soil amelioration approach,the efficiency and patterns of SOC accumulation remain unclear.Two field experiments were conducted in infertile subtropical upland and paddy soils with 0,30,60,and 90 Mg ha^(-1)granulated straw incorporation.After one year,SOC accumulation efficiency from straw input remained stable in upland(30.8–37.5%)with increasing amounts of straw incorporation,while declined from 60.0 to 38.3%in paddy.In both croplands,the contributions of lignin phenols to SOC increased with increasing straw incorporation,while the contributions from amino sugars remained constant at higher straw input levels.Subsequently,the ratios of lignin phenols to amino sugars increased with increasing straw incorporation,indicating faster plant residue accumulation compared to microbial necromass,as the granulation approach limited microbial involvement in straw transformation.Thus,single-time incorporation of substantial granulated straw presents an effective agricultural strategy for rapid amelioration of infertile croplands.
基金supported by the Wencheng County Science and Technology Plan Project(2023NKY03)Earmarked Fund for Modern Agro-industry Technology Research System(Grant Number CARS-24-B04,CARS-23-B05)Additional support was provided by Key Laboratory of Biology and Genetic Improvement of Horticultural Crops(Vegetables),Ministry of Agriculture and Rural Affairs,China.
文摘To address the issue of residual pollution caused by polyethylene mulch,this study explored the effects of different mulching methods on the soil environment of the yam field,as well as on yam yield and quality.The experiment comprised six treatments in total:one non-mulched treatment served as the control(CK),along with five different film-mulched treatments,namely PE,FZS12,FZS15,FC12,and FC15.The degradation of these films and their effects on soil physicochemical properties,microbial community,yam yield and quality were compared.The results showed that the FZS12 treatment achieved grade 5 degradation by the end of the planting period.Compared with PE treatment,the total soluble sugar content and yield of yam treated with FZS12 were significantly increased by 35.78%and 74.97%,respectively(p<0.05).Compared with CK and PE treatments,FZS12 significantly increased soil available nitrogen by 31.62%and 6.20%,respectively(p<0.05),and significantly increased soil available phosphorus by 8.58%and 4.45%,respectively(p<0.05).Soil pH,available nitrogen,and available phosphorus were the main environmental factors affecting the soil bacterial community.The FZS12 treatment significantly increased the relative abundances of soil bacteria phylum including Acidobacteriota,Myxococcota,Patescibacteria,and Proteobacteria compared with the CK and PE treatments.Functional prediction using Picrust2 revealed that the FZS12 treatment had significantly higher levels of signal transduction and amino acid metabolism than the CK and PE treatments.In conclusion,covering with 12μm PBAT/PLA humic acid biodegradable film enhances yam yield and total soluble sugar content by shaping beneficial soil microbial communities,activating soil nutrients.
基金supported by“National Key Research and Development Program of China”(Grant No.2021YFF1000701)“National Natural Science Foundation of China”(Grant No.U22A20509)。
文摘Background The cellular basis of testicular development and spermatogenesis for the extreme sperm density in chickens(100-fold higher than mammals)remains poorly defined.A comprehensive understanding of the molecular characteristics driving poultry testicular development is crucial for explaining this enhanced spermatogenic capacity.Results Here,we first established a single-cell transcriptome profile of chicken testes from hatching to maturity,identifying the dynamic transcriptional characteristics of germ cell fate transition and exploring the developmental characteristics of Sertoli cells and Leydig cells.Multi-species comparisons revealed a higher proportion of germ cells and the unique adaptations of Sertoli cells in chicken testes.Most importantly,our results demonstrated that Sertoli cells dominated in somatic composition of mature chicken testes,and proliferating Sertoli cells persisted in chicken testes even after sexual maturity,while no proliferating Sertoli cells in mammals.We also found a richer interaction network between chicken testicular cells,especially the specific activation of Sertoli cell interaction signals,such as TGF-β,BMP,EGF,and activin.These adaptations of Sertoli cells may support the spermatogenic superiority in chickens.Additionally,our results indicated that cAMP responsive element binding protein 5(CREB5)played a crucial role in maintaining the maturation and function of chicken Sertoli cells,and circadian rhythm promoted testosterone secretion and the development of Leydig cells.Conclusion Our study revealed that the sustained proliferative capacity of Sertoli cells,their enriched signaling network,and the regulatory roles of CREB5 and circadian rhythms collectively represented unique testicular adaptations in chickens.These findings may hold extraordinary significance in understanding the molecular characteristics of poultry testicular development,and provide a plausible framework for explaining enhanced spermatogenesis in poultry.
基金supported by the Major Science and Technology Projects of Yunnan Province(No.202302AB080016)the National Natural Science Foundation of China(Nos.22101060,22371056,and 52303269)the Science and Technology Research Project of Guangzhou(Nos.202201020201 and 2023A03J0624)。
文摘Fractal assembly in discrete structures,especially for artificial supramolecular species,has attracted significantly increased interest over the past two decades.In this study,we present the precisely controlled fractal expanding synthesis of a novel triangular prism supramolecule featuring Sierpiński triangular face,which was achieved through a module-intervened self-expansion strategy.The homoleptic S1 was firstly synthesized through the assembly of ligand L1 with Zn^(2+)ions.Based on the triangular-faced prism S1,we further introduced Sierpiński triangular faces on the section of the heteroleptic supramolecular cage S2 with an expanded inner cavity and more abundant active sites for photocatalytic properties.The topotactic architectures for both S1 and S2 were fully characterized by nuclear magnetic resonance spectroscopy,high-resolution electrospray ionization mass spectrometry,transmission electron microscopy,and atomic force microscopy.Furthermore,the enhanced photocatalytic activity of the fractal expanded S2 was performed via the superior amine oxidative efficiency over S1.This study proposes the unprecedented fractal expanding strategy for three-dimensional supramolecular species with higher complexity,potentially opening new avenues for structural regulation of artificial fractal molecules.
基金funded by the U.S.Department of Education under Grant Number ED#P116S210005the National Science Foundation under Grant Numbers 2226936 and 2420405.
文摘Theintegration of human factors into artificial intelligence(AI)systems has emerged as a critical research frontier,particularly in reinforcement learning(RL),where human-AI interaction(HAII)presents both opportunities and challenges.As RL continues to demonstrate remarkable success in model-free and partially observable environments,its real-world deployment increasingly requires effective collaboration with human operators and stakeholders.This article systematically examines HAII techniques in RL through both theoretical analysis and practical case studies.We establish a conceptual framework built upon three fundamental pillars of effective human-AI collaboration:computational trust modeling,system usability,and decision understandability.Our comprehensive review organizes HAII methods into five key categories:(1)learning from human feedback,including various shaping approaches;(2)learning from human demonstration through inverse RL and imitation learning;(3)shared autonomy architectures for dynamic control allocation;(4)human-in-the-loop querying strategies for active learning;and(5)explainable RL techniques for interpretable policy generation.Recent state-of-the-art works are critically reviewed,with particular emphasis on advances incorporating large language models in human-AI interaction research.To illustrate some concepts,we present three detailed case studies:an empirical trust model for farmers adopting AI-driven agricultural management systems,the implementation of ethical constraints in roboticmotion planning through human-guided RL,and an experimental investigation of human trust dynamics using a multi-armed bandit paradigm.These applications demonstrate how HAII principles can enhance RL systems’practical utility while bridging the gap between theoretical RL and real-world human-centered applications,ultimately contributing to more deployable and socially beneficial intelligent systems.
基金financially supported by the National Science & Technology Fundamental Resources Investigation Project of China (2021FY100501)the Youth Innovation of Chinese Academy of Agricultural Sciences (Y2023QC16)。
文摘Long-term manure application has the potential to alleviate soil acidification, and increase carbon sequestration and nutrient availability, thus improving cropland fertility. However, the mechanisms behind greenhouse gas N_(2)O emissions from acidic soil mediated by long-term manure application remain poorly understood. Herein, we investigated N_(2)O emission and its linkage with gross N mineralization and nitrification rates, as well as nitrifying and denitrifying microbes in an acidic upland soil subjected to 36-year fertilization treatments, including an unfertilized control(CK), inorganic fertilizer(F), 2× rate of inorganic fertilizer(2F), manure(M), and the combination of inorganic fertilizer and manure(FM) treatments. Compared to the CK treatment(1.34 μg N kg^(-1) d^(-1)), fertilization strongly increased N_(2)O emissions by 34-fold on average, with more pronounced increases in the manure-amendment(10.6-169 μg N kg^(-1) d^(-1)) than those in the inorganic fertilizer treatments(3.26-5.51 μg N kg^(-1) d^(-1)). The manure amendment-stimulated N_(2)O emissions were highly associated with increased soil pH, mean weight diameter of soil aggregates, substrate availability(e.g., particulate organic carbon, NO_(3)^(-)and available phosphorus), gross N mineralization rates, denitrifier abundances and the(nirK+nirS)/nosZ ratio. These findings suggest that the increased N_(2)O emissions primarily resulted from alleviated acidification, increased substrate availability and improved soil structure, thus enhancing microbial N mineralization and favoring N_(2)O^(-)producing denitrifiers over N_(2)O consumers. Moreover, ammonia-oxidizing bacteria(AOB) rather than ammonia-oxidizing archaea(AOA) positively correlated with soil NO_(3)^(-)concentration and N_(2)O emissions, indicating that nitrification indirectly contributed to N_(2)O production by supplying NO_(3)^(-)for denitrification. Collectively, manure amendment potentially stimulates N_(2)O emissions, primarily resulting from alleviated soil acidification and increased substrate availability, thus enhancing N mineralization and denitrifier-mediated N_(2)O production. Our findings suggest that consideration should be given to the greenhouse gas budgets of agricultural ecosystems when applying manure for managing the pH and fertility of acidic soils.
基金supported by the National Natural Science Foundation of China (No.22405062)the Guangdong Basic and Applied Basic Research Foundation (No.2021A1515110869)+2 种基金the Shenzhen Science and Technology Program (No.ZDSYS20210623091813040)Innovation Program of Zhanjiang (No.2020LHJH005)Funds for Ph.D.researchers of Guangdong Medical University in 2025 (No.4SG25007G)。
文摘Thermally activated delayed fluorescence(TADF) emitters show great potential in photodynamic therapy(PDT) and bioimaging,leveraging their structural adaptability,efficient reverse intersystem crossing(RISC),robust photosensitizing capability,and high photoluminescence quantum yields(PLQYs).Herein,we developed a new class of donor-acceptor-donor(D-A-D)-type TADF materials by connecting the highly twisted indolizine-benzophenone electron acceptors with a series of electron donors including phenoxazine,phenothiazine and 9,9-dimethyl-9,10-dihydroacridine.These materials exhibit enhanced TADF properties,aggregation-induced emission(AIE),alongside high reactive oxygen species(ROS) generation efficiency,effectively mitigating aggregation-caused quenching observed in traditional fluorophores.Among them,IDP-p-PXZ,incorporating the phenoxazine donor,stands out with the smallest singlet-triplet splitting energy(ΔE_(ST)) and the highest spin-orbit coupling matrix elements(SOCMEs).Upon encapsulation into 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000](DSPE-PEG2000) nanoparticles(NPs),IDP-p-PXZ demonstrates extended delayed fluorescence lifetimes in air,an exceptionally fast intersystem crossing(ISC) rate constant(k_(ISC)) of 3.4×10^(7)s^(-1),and a radiative rate constant(k_(r)) of 5.05×10^(6)s^(-1).These NPs exhibit superior biocompatibility,efficient cellular internalization,and potent ROS production,enabling effective simultaneous PDT and confocal fluorescence imaging in HeLa cells.
基金Project supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX240139)funded by the Youth Independent Innovation Fund of PLA Army Engineering University(Grant No.KYJBJKQTZQ23006)。
文摘This study extends the self-propelled particle(SPP)model by incorporating a limited vision cone and local density sensing.The results reveal that clusters can simultaneously exhibit velocity polarization and spatial cohesion within specific ranges of vision angle and density threshold.The dependence of the dynamical features,including the order parameter and density variation,on the threshold and visual cone is investigated.Furthermore,a critical threshold is identified,which governs the transition between ordered and disordered states and is closely linked to density fluctuations and noise intensity.The clustering results show that the model is explained by the chasing mechanism responsible for cluster formation,density,and shape.These results may stimulate practical applications in swarm maneuvering.
基金financially supported by the National Key Research and Development Program of China (No. 2022YFC2105300)。
文摘A series of leaching and electrochemical experiments were conducted to elucidate the critical role of hydrogen sulfide(H_(2)S)in copper-driven reduction of chalcopyrite.Results demonstrate that in the absence of H_(2)S,metallic copper converts chalcopyrite into bornite(Cu_(5)FeS_(4)).However,the introduction of H_(2)S promotes the formation of chalcocite(Cu_(2)S)by altering the oxidation pathway of copper.Electrochemical analysis demonstrates that the presence of H₂S significantly reduces the corrosion potential of copper from 0.251 to−0.223 V(vs SHE),reaching the threshold necessary for the formation of Cu_(2)S.Nevertheless,excessive H_(2)S triggers sulfate reduction via the reaction of 8Cu+H_(2)SO_(4)+3H_(2)S=4Cu_(2)S+4H_(2)O(ΔG=−519.429 kJ/mol at 50℃),leading to inefficient copper utilization.
文摘The environmental wind tunnel of high-speed railway trains serves as a crucial experimental facility for the research and development of high-speed railway technology.The refrigeration system within the wind tunnel is an important subsystem.However,the design of the wind tunnel refrigeration system management program presents significant scientific challenges and limitations.Traditional management approaches in wind tunnel refrigeration systems suffer from prolonged decision-making times and reliance on experiential knowledge,necessitating the need for intelligent transformation.This paper aims to address these issues by exploring existing intelligent management methodologies and defining the concept of a wind tunnel intelligent laboratory along with its primary modules.Furthermore,we propose a water cooler failure prediction model based on the existing equipment model of the wind tunnel's refrigeration system.This model effectively predicts the Remaining Useful Life(RUL) of the water cooler in the case of fouling failure,contributing to enhanced efficiency,cost reduction,and safety improvements in laboratories.
基金Project supported by the National Natural Science Foundation of China(Nos.52575093 and 12202229)the China Postdoctoral Science Foundation(No.2025M771368)the Fundamental Research Funds for the Central Universities of China(Nos.buctrc202405 and JD2522)。
文摘Magnetorheological(MR)bearings,with their field-controllable rheological properties,offer new possibilities for control of rotor instabilities.However,their nonlinear dynamic behaviors and the underlying physical mechanisms governing these instabilities remain insufficiently understood.This work develops a coupled MR bearingrotor system model,where the oil film force is derived from a novel bilinear constitutive equation to capture the field-sensitive shear behaviors of MR fluids.Complex nonlinear dynamic behaviors including period doubling,quasi-period,and chaos are revealed,which emerge from the interaction between oil film vortex dynamics and magnetic excitation.The critical instability mechanism is identified from the evolution of intrinsic dynamic characteristics of MR bearings.When the whirl speed within the oil film reaches approximately half of the rotor speed,the damping force balances the destabilizing force,thereby defining a critical threshold beyond which the system transitions to instability.This threshold can be effectively tuned by adjusting the excitation current,which modifies the yield stress of MR fluids and consequently regulates the damping force.As a result,the nonlinear vibrations of oil whirl and whip can be suppressed,and the system stability can be significantly enhanced.These findings provide both theoretical insight and practical guidance for the design and control of MR bearing supported rotor systems.
基金Project supported by National Science Funds for Creative Research Groups of China(Grant No.61421002)
文摘High-performance photodetectors are expected to open up revolutionary opportunities in many application fields, such as environment monitoring, military, optical communication and biomedical science. Combining two-dimensional materials(which have tunable optical absorption and high carrier mobility) with organic materials(which are abundant with low cost, high flexibility and large-area scalability) to form thin-film heterojunctions, high-responsivity photodetectors could be predicted with fast response speed in a wide spectra region.In this review, we give a comprehensive summary of photodetectors based on two-dimensional materials and organic thin-film heterojunctions, which includes hybrid assisted enhanced devices, single-layer enhanced devices, vertical heterojunction devices and tunable vertical heterojunction devices. We also give a systematic classification and perspectives on the future development of these types of photodetectors.
