Photocatalysis is a promising technology for purification of indoor air by oxidation of volatile organic compounds.This study provides a comprehensive analysis of the adsorption and photo-oxidation of surface-adsorbed...Photocatalysis is a promising technology for purification of indoor air by oxidation of volatile organic compounds.This study provides a comprehensive analysis of the adsorption and photo-oxidation of surface-adsorbed acetone on three SrTiO_(3)morphologies:cubes(for which exclusively{100}facets are exposed),{110}-truncated cubes,and{100}-truncated rhombic dodecahedrons,respectively,all prepared by hydrothermal synthesis.In situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy shows that cubic crystals contain a high quantity of surface-OH groups,enabling significant quantities of adsorbed acetone in the form ofη^(1)-enolate when exposed to gas phase acetone.Contrary,{110}facets exhibit fewer surface-OH groups,resulting in relatively small quantities of adsorbedη^(1)-acetone,without observable quantities of enolate.Interestingly,acetate and formate signatures appear in the spectra of cubic,surfaceη^(1)-enolate containing,SrTiO_(3)upon illumination,while besides acetate and formate,the formation of(surface)formaldehyde was observed on truncated cubes,and dodecahedrons,by conversion of adsorbedη^(1)-acetone.Time-Resolved Photoluminescence studies demonstrate that the lifetimes of photogenerated charge carriers vary with crystal morphology.The shortest carrier lifetime(τ_(1)=33±0.1 ps)was observed in{110}-truncated cube SrTiO_(3),likely due to a relatively strong built-in electric field promoting electron transport to{100}facets and hole transport to{110}facets.The second lifetime(τ_(2)=259±1 ps)was also the shortest for this morphology,possibly due to a higher amount of surface trap states.Our results demonstrate that SrTiO_(3)crystal morphology can be tuned to optimize performance in photocatalytic oxidation.展开更多
基金Advanced Research Center for Chemical Building Blocks,ARC CBBC,which is co-foundedco-financed by the Dutch Research Council(NWO)and the Netherlands Ministry of Economic Affairs and Climate Policy.
文摘Photocatalysis is a promising technology for purification of indoor air by oxidation of volatile organic compounds.This study provides a comprehensive analysis of the adsorption and photo-oxidation of surface-adsorbed acetone on three SrTiO_(3)morphologies:cubes(for which exclusively{100}facets are exposed),{110}-truncated cubes,and{100}-truncated rhombic dodecahedrons,respectively,all prepared by hydrothermal synthesis.In situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy shows that cubic crystals contain a high quantity of surface-OH groups,enabling significant quantities of adsorbed acetone in the form ofη^(1)-enolate when exposed to gas phase acetone.Contrary,{110}facets exhibit fewer surface-OH groups,resulting in relatively small quantities of adsorbedη^(1)-acetone,without observable quantities of enolate.Interestingly,acetate and formate signatures appear in the spectra of cubic,surfaceη^(1)-enolate containing,SrTiO_(3)upon illumination,while besides acetate and formate,the formation of(surface)formaldehyde was observed on truncated cubes,and dodecahedrons,by conversion of adsorbedη^(1)-acetone.Time-Resolved Photoluminescence studies demonstrate that the lifetimes of photogenerated charge carriers vary with crystal morphology.The shortest carrier lifetime(τ_(1)=33±0.1 ps)was observed in{110}-truncated cube SrTiO_(3),likely due to a relatively strong built-in electric field promoting electron transport to{100}facets and hole transport to{110}facets.The second lifetime(τ_(2)=259±1 ps)was also the shortest for this morphology,possibly due to a higher amount of surface trap states.Our results demonstrate that SrTiO_(3)crystal morphology can be tuned to optimize performance in photocatalytic oxidation.
