The palladium（o）-catalyzed nitrogen insertion into cyclic Si-Si bonds has been realized by using N-tosylhydrazones/diazo compounds as the nitrogen source. The palladium（Ⅱ） nitrene formation and subsequent migrato...The palladium（o）-catalyzed nitrogen insertion into cyclic Si-Si bonds has been realized by using N-tosylhydrazones/diazo compounds as the nitrogen source. The palladium（Ⅱ） nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction.展开更多
基金The project is supported by the National Basic Research Pro- gram of China （973 Program, No. 2015CB856600） and the Natio- anal Natural Science Foundation of China （Grant 21332002, 21472004）.
文摘The palladium（o）-catalyzed nitrogen insertion into cyclic Si-Si bonds has been realized by using N-tosylhydrazones/diazo compounds as the nitrogen source. The palladium（Ⅱ） nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction.
