Well-aligned open-ended multi-walled carbon nanotube （MWCNT） arrays were prepared via chemical vapor deposition （CVD） method in porous anodic aluminum oxide （AAO） templates without depositing any transition meta...Well-aligned open-ended multi-walled carbon nanotube （MWCNT） arrays were prepared via chemical vapor deposition （CVD） method in porous anodic aluminum oxide （AAO） templates without depositing any transition metals as catalyst. Effects of the CVD temperature and heat treatment were studied in detail. Well-aligned open-ended MWCNT arrays were obtained at the CVD temperature above 600℃; when CVD temperature is reduced to around 550℃, CNTs, CNFs and other structures existed at the same time; no CNTs or carbon nanofibres （CNFs） could be fouad as the CVD temperature is below 500℃, and only amorphous carbon in the porous AAO template was found. Experimental results showed that the AAO template is catalytic during the CVD process, and it has the following two effects： to catalyze thermal decomposition of acetylene and to catalyze conversion of carbon decomposed from acetylene into CNTs or CNFs. Heat treatment could improve the graphitization degree, but it might also introduce new defects.展开更多
High catalytic efficiency is a fundamental prerequisite for the industrial adoption of catalytic transformations.However,reactions achieving turnover numbers(TONs)exceeding 10,000 remain rare in photocatalytic areas,w...High catalytic efficiency is a fundamental prerequisite for the industrial adoption of catalytic transformations.However,reactions achieving turnover numbers(TONs)exceeding 10,000 remain rare in photocatalytic areas,which is primarily attributed to insufficient photostability and light-absorption capacity of photocatalysts.Metalloporphyrins,featured by extendedπ-conjugation systems,exhibit distinct advantages including high molar extinction coefficients,long-lived triplet excited states,and exceptional photostability,alongside distinctive Soret and Q absorption bands.展开更多
基金This project was supported by the National High Technology Research and Development Program of China （863 Program, No. 2004AA302030） and Na- tional Natural Science Foundation of China （NSFC No. 60574095）. Tests and analysis are supported by the United Foundation for Testing ＆： Analysis in Hefei, Chi- nese Academy of Sciences.
文摘Well-aligned open-ended multi-walled carbon nanotube （MWCNT） arrays were prepared via chemical vapor deposition （CVD） method in porous anodic aluminum oxide （AAO） templates without depositing any transition metals as catalyst. Effects of the CVD temperature and heat treatment were studied in detail. Well-aligned open-ended MWCNT arrays were obtained at the CVD temperature above 600℃; when CVD temperature is reduced to around 550℃, CNTs, CNFs and other structures existed at the same time; no CNTs or carbon nanofibres （CNFs） could be fouad as the CVD temperature is below 500℃, and only amorphous carbon in the porous AAO template was found. Experimental results showed that the AAO template is catalytic during the CVD process, and it has the following two effects： to catalyze thermal decomposition of acetylene and to catalyze conversion of carbon decomposed from acetylene into CNTs or CNFs. Heat treatment could improve the graphitization degree, but it might also introduce new defects.
基金the Natural Science Foundation of China(Nos.22261019,22001101,22401116)the Science Foundation of Jiangxi Province(Nos.20224BAB213007,20224BAB203014,20212BAB203009,20212BAB213027,and 20212BAB213014)support from Jiangxi Provincial Key Laboratory of OrganicF unctional Molecules(No.2024SSY05141).
文摘High catalytic efficiency is a fundamental prerequisite for the industrial adoption of catalytic transformations.However,reactions achieving turnover numbers(TONs)exceeding 10,000 remain rare in photocatalytic areas,which is primarily attributed to insufficient photostability and light-absorption capacity of photocatalysts.Metalloporphyrins,featured by extendedπ-conjugation systems,exhibit distinct advantages including high molar extinction coefficients,long-lived triplet excited states,and exceptional photostability,alongside distinctive Soret and Q absorption bands.
