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Cu_(x)Zn_(y)双金属负载TiO_(2)纳米棒强化光催化制氢性能研究 被引量:2
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作者 贾海平 刘衡 +4 位作者 李磊 程诚 师进文 敬登伟 刘杰 《天然气与石油》 2024年第5期70-78,共9页
金属助催化剂负载对提高二氧化钛(TiO_(2))的光催化制氢性能起着关键作用,金属负载TiO_(2)形成肖特基结能有效促进载流子的分离和迁移,双金属相比单一金属通常具有更优越的助催化性能,不同金属的组合提供了克服单一金属局限性的方法。... 金属助催化剂负载对提高二氧化钛(TiO_(2))的光催化制氢性能起着关键作用,金属负载TiO_(2)形成肖特基结能有效促进载流子的分离和迁移,双金属相比单一金属通常具有更优越的助催化性能,不同金属的组合提供了克服单一金属局限性的方法。制备了系列Cu_(x)Zn_(y)双金属负载的TiO_(2)(Cu_(x)Zn_(y)/TiO_(2))催化剂材料,并进行光催化制氢研究。锌(Zn)可以延长光激发电子的寿命;铜(Cu)不仅可以提高载流子迁移效率,表面等离子体共振效应还可有效捕获太阳光中的红外光,将红外光转化为热能用于促进制氢反应。此外,Cu和Zn的协同效应使Cu_(x)Zn_(y)双金属的助催化效果显著优于单一金属Cu或Zn,更有效抑制了TiO_(2)光生载流子的复合,提高了载流子的利用率,进一步提高了对太阳光的利用率。Cu_(3)Zn_(3)/TiO_(2)的光催化制氢速率最高,达到了3726μmol·g^(-1)·h^(-1),是纯TiO_(2)光催化制氢速率的5.9倍。研究结果为设计双金属助催化剂和光热耦合催化提供了重要的研究思路。 展开更多
关键词 太阳能 制氢 光热催化 双金属助催化剂
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A Comprehensive Review on Multi-Dimensional Heat Conduction of Multi-Layer and Composite Structures:Analytical Solutions 被引量:1
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作者 AMIRI DELOUEI Amin EMAMIAN Amin +5 位作者 SAJJADI Hasan ATASHAFROOZ Meysam LI Yueming WANG Lian-Ping jing dengwei XIE Gongnan 《Journal of Thermal Science》 SCIE EI CAS CSCD 2021年第6期1875-1907,共33页
Heat conduction in multi-layer and composite materials is one of the fundamental heat transfer problems in many industrial applications.Due to different materials types,interface conditions,and various geometries of t... Heat conduction in multi-layer and composite materials is one of the fundamental heat transfer problems in many industrial applications.Due to different materials types,interface conditions,and various geometries of these laminates,the heat conduction mechanism is more complicated than that of one-layer isotropic media.Analytical solutions are the best ways to study and understand such problems in depth.In this study,different existing analytical solutions for heat conduction in multi-layer and composite materials are reviewed and classified in rectangular,cylindrical,spherical,and conical coordinates.Applied boundary conditions,internal heat source,and thermal contact resistance as the most critical parameters in the solution complexity investigated in the literature,are discussed and summarized in different tables.Various types of multi-layer structures such as isotropic,anisotropic,orthotropic,and reinforced laminates are included in this study.It is found that although more than half a century has passed since the beginning of the research on heat transfer in multi-layer composites,new researches that can help with a better understanding in this area are still being offered.The challenges and shortcomings in this area are also discussed to guide future researches. 展开更多
关键词 multi-dimensional heat conduction composite laminates multi-layer structures analytical solutions interface contact resistance
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