A bifunctional catalyst Pt/HY-β was prepared from a bimicroporous composite zeolite Y-β. Characterization results showed that the specific surface area, pore volume, and acid amount of the catalyst Pt/HY-β all decr...A bifunctional catalyst Pt/HY-β was prepared from a bimicroporous composite zeolite Y-β. Characterization results showed that the specific surface area, pore volume, and acid amount of the catalyst Pt/HY-β all decreased compared to the original zeolite. The catalytic performance of this catalyst in n-octane hydroisomerization was investigated in a fixed bed stainless steel tubular reactor. The results showed that at a hydrogen/n-octane volume ratio of 1000, pressure of 0.6 MPa, temperature of 230 ℃ and LHSV of 3 h^-1, the conversion of n-octane, yield of liquid, hydrocracking rate and yield of iso-octane were 52.32%, 88.66%, 12.60%, 39.51%, respectively.展开更多
China's requisition-compensation balance strategy has dramatically reshaped cropland spatial patterns,drawing multidisciplinary research attention.However,existing studies predominantly emphasize horizontal distri...China's requisition-compensation balance strategy has dramatically reshaped cropland spatial patterns,drawing multidisciplinary research attention.However,existing studies predominantly emphasize horizontal distribution,overlooking the significant influence of slope gradient on cropland spatial patterns.This paper proposes a slope location quotient(SLQ)index that reflects the relative advantage of cropland distribution and explores the slope grade difference of cropland spatial patterns in China at the county scale.The analysis adopts 30-m resolution digital elevation model with land cover data,taking 2672 counties with cropland ratio>1%as study units.The temporal scope covers 1990 and 2020,with slope gradients categorized into five grades:0°~2°,2°~6°,6°~15°,15°~25°,and 25°~90°.Results show that:1)The inverse correlation between cropland area and slope gradient remained stable throughout the study period,with the variation in cropland area frequency across slope grades being less than 1%.2)The spatial patterns of SLQ in 1990 and 2020 both transited stepwise with slope gradient,while≤2°and>6°slopes exhibited opposing patterns.3)The mean absolute variation of SLQ during 1990-2020 increased with slope gradient(R2=0.926,p<0.01).Particularly for slope grades>15°,the mean absolute variation reached 0.26(for 15°~25°)and 0.43(for 25°~90°),respectively,and displayed a distinct southward-increasing and northwarddecreasing pattern.This study offers novel slopegradient perspectives for analyzing cropland spatial patterns.To enhance cropland protection benefits,reversing the steep cropland SLQ surge in southern China is recommended.展开更多
基金sponsored by China Petroleumand Chemical Corporation(No.:090701)
文摘A bifunctional catalyst Pt/HY-β was prepared from a bimicroporous composite zeolite Y-β. Characterization results showed that the specific surface area, pore volume, and acid amount of the catalyst Pt/HY-β all decreased compared to the original zeolite. The catalytic performance of this catalyst in n-octane hydroisomerization was investigated in a fixed bed stainless steel tubular reactor. The results showed that at a hydrogen/n-octane volume ratio of 1000, pressure of 0.6 MPa, temperature of 230 ℃ and LHSV of 3 h^-1, the conversion of n-octane, yield of liquid, hydrocracking rate and yield of iso-octane were 52.32%, 88.66%, 12.60%, 39.51%, respectively.
基金supported by the project of the National Natural Science Foundation of China entitled“Distribution and change characteristics of construction land on slope gradient in mountainous cities of southern China”(No.41961039)。
文摘China's requisition-compensation balance strategy has dramatically reshaped cropland spatial patterns,drawing multidisciplinary research attention.However,existing studies predominantly emphasize horizontal distribution,overlooking the significant influence of slope gradient on cropland spatial patterns.This paper proposes a slope location quotient(SLQ)index that reflects the relative advantage of cropland distribution and explores the slope grade difference of cropland spatial patterns in China at the county scale.The analysis adopts 30-m resolution digital elevation model with land cover data,taking 2672 counties with cropland ratio>1%as study units.The temporal scope covers 1990 and 2020,with slope gradients categorized into five grades:0°~2°,2°~6°,6°~15°,15°~25°,and 25°~90°.Results show that:1)The inverse correlation between cropland area and slope gradient remained stable throughout the study period,with the variation in cropland area frequency across slope grades being less than 1%.2)The spatial patterns of SLQ in 1990 and 2020 both transited stepwise with slope gradient,while≤2°and>6°slopes exhibited opposing patterns.3)The mean absolute variation of SLQ during 1990-2020 increased with slope gradient(R2=0.926,p<0.01).Particularly for slope grades>15°,the mean absolute variation reached 0.26(for 15°~25°)and 0.43(for 25°~90°),respectively,and displayed a distinct southward-increasing and northwarddecreasing pattern.This study offers novel slopegradient perspectives for analyzing cropland spatial patterns.To enhance cropland protection benefits,reversing the steep cropland SLQ surge in southern China is recommended.
