The magnetic properties and Kondo effect in Ce3TiBi5 with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) underg...The magnetic properties and Kondo effect in Ce3TiBi5 with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) undergoes an antiferromagnetic(AFM)transition at T_(N)∼5 K.Under high pressures within 8.9 GPa,we find that Kondo scattering contributes differently to the high-temperature resistance,R(T),depending on the applied current direction,demonstrating a significantly anisotropic Kondo effect.The complete P–T phase diagram has been constructed,in which the pressure dependence of T_(N) exhibits a dome-like shape.The AFM order remains robust under pressure,even when the coherence temperature T^(*) far exceeds 300 K.We attribute the observed anisotropic Kondo effect and the robust AFM to the underlying anisotropy in electronic hybridization under high pressure.展开更多
Recent experiments at the National Ignition Facility and theoretical modeling suggest that side stimulated Raman scattering(SSRS)instability could reduce laser–plasma coupling and generate considerable fluxes of supr...Recent experiments at the National Ignition Facility and theoretical modeling suggest that side stimulated Raman scattering(SSRS)instability could reduce laser–plasma coupling and generate considerable fluxes of suprathermal hot electrons under interaction conditions envisaged for direct-drive schemes for inertial confinement fusion.Nonetheless,SSRS remains to date one of the least understood parametric instabilities.Here,we report the first angularly and spectrally resolved measurements of scattered light at laser intensities relevant for the shock ignition scheme(I×10^(16)W/cm^(2)),showing significant SSRS growth in the direction perpendicular to the laser polarization.Modification of the focal spot shape and orientation,obtained by using two different random phase plates,and of the density gradient of the plasma,by utilizing exploding foil targets of different thicknesses,clearly reveals a different dependence of backward SRS(BSRS)and SSRS on experimental parameters.While convective BSRS scales with plasma density scale length,as expected by linear theory,the growth of SSRS depends on the spot extension in the direction perpendicular to laser polarization.Our analysis therefore demonstrates that under current experimental conditions,with density scale lengths L_(n)≈60–120μm and spot sizes FWHM≈40–100μm,SSRS is limited by laser beam size rather than by the density scale length of the plasma.展开更多
The Ti-6Al-4V alloy is the most widely utilized titanium metal alloy globally,making the enhancement of its mechanical properties important.In this study,we achieved an ultimate tensile strength of 1.5 GPa through the...The Ti-6Al-4V alloy is the most widely utilized titanium metal alloy globally,making the enhancement of its mechanical properties important.In this study,we achieved an ultimate tensile strength of 1.5 GPa through the additive manufacturing(AM)of Ti-6Al-4V.Specifically,the Ti-6Al-4V alloy was fabricated via laser powder bed fusion(L-PBF)using Ti-6Al-4V powder subjected to cold plastic deformation(CPD Ti-6Al-4V).The microstructural evolution of the Ti-6Al-4V powder during CPD was analyzed in detail.The CPD Ti-6Al-4V powder exhibited a core-shell structure with subgrains and nanocrystals formed via high-density dislocations within the shell.In addition,the as-printed CPD Ti-6Al-4V alloy had an average grain size of approximately 1.9µm.The presence of interstitial elements and finer grains resulted in the formation of Ti-6Al-4V alloys with ultrahigh strengths(ultimate tensile strength of approximately 1500 MPa,yield strength of 1320 MPa,and elongation of 6%).This groundbreaking achievement paves the way for further advancements in AM technology and presents exciting opportunities for innovation across a range of high-strength materials,which are crucial for achieving optimal performance.展开更多
The directionally solidified samples of an ultra-high temperature Nb-Si-Ti-Hf-Cr-Al alloy have been prepared with the use of an electron beam floating zone melting (EBFZM) furnace, and their microstructural characteri...The directionally solidified samples of an ultra-high temperature Nb-Si-Ti-Hf-Cr-Al alloy have been prepared with the use of an electron beam floating zone melting (EBFZM) furnace, and their microstructural characteristics have been analyzed. All the primary dendrites of Nb solid solution (Nbss), eutectic colonies of Nba, plus (Nb, Ti)3 Si/(Nb, Ti)5 Si3 and chains of (Nb, Ti)3 Si/(Nb, Ti)5 Si3 plates align along the growth direction of the samples. With increasing of the withdrawing rate, the microstructure is refined, and the amounts of Nbss+ (Nb, Ti)3 Si/(Nb, Ti)5 Si3 eutectic colonies and (Nb, Ti)3 Si/(Nb, Ti)5 Si3 plates increase. There appear nodes in the (Nb, Ti)3 Si/(Nb, Ti)5 Si3 plates.展开更多
The effect of Mo addition on microstructural characteristics of a nickel-base single crystal superalloy containing 4 wt% Re was investigated. The γ/γ’ partitioning ratios determined by energy dispersive spectromete...The effect of Mo addition on microstructural characteristics of a nickel-base single crystal superalloy containing 4 wt% Re was investigated. The γ/γ’ partitioning ratios determined by energy dispersive spectrometer attached to a transmission electron microscope showed that the addition of Mo enhanced the partitioning of Re,W and Cr in the g matrix while decreased the concentration of Ta in the matrix. Synchrotron radiation diffraction was adopted to measure the γ/γ’ lattice misfit at room temperature. The results indicated that Mo addition changed the γ/γ’ lattice misfit towards larger negative as well as increased the tetragonal distortion of the γ lattice. Additionally,Mo addition led to microstructural instability and altered the precipitation behavior of topologically close-packed phases during 1100 C exposure. Instead of precipitating directly from the matrix,the μ phase was observed to be converted from the α phase which precipitated preferentially as a metastable intermediate in the alloy with high Mo content.展开更多
Porous Si3N4 was brazed to Invar alloy in this study, and Ag-Cu-Ti/Cu/Ag-Cu multi-layered filler was designed to inhibit the formation of Fe2Ti and Ni3Ti intermetallic compounds. The effects of the brazing temperature...Porous Si3N4 was brazed to Invar alloy in this study, and Ag-Cu-Ti/Cu/Ag-Cu multi-layered filler was designed to inhibit the formation of Fe2Ti and Ni3Ti intermetallic compounds. The effects of the brazing temperature and the thickness of Cu interlayer on the microstructure and mechanical properties of brazed joints were investigated. The typical microstructure of the joint brazed with multi-layered filler was porous Si3N4/TiN ＋ Ti5Si3/Ag-Cu eutectic[Cu[Ag-Cu eutectic/Cu-rich layer ＋ diffusion layer/Invar. When the brazing temperature increased, the reaction layer at the ceramic/filler interface grew thicker and the Cu interlayer turned thinner. As the thickness of Cu interlayer increased from 50 to 150 μm, the joint strength first increased and then decreased. In this research, the maximum shear strength （73 MPa） was obtained when being brazed at 1173 K with a 100 μm Cu interlayer applied in the filler, which was 55% higher than that brazed with single Ag-Cu-Ti brazing alloy and had reached 86% of the ceramic. The release of residual stress and the barrier effect of Cu interlayer to inhibit the formation of Fe2Ti and Ni3Ti intermetallics played the major role in the improvement of joint strength.展开更多
A novel structural damage detection method with a new damage index,i.e.,the statistical moment-based damage detection（SMBDD） method in the frequency domain,has been recently proposed.The aim of this study is to exte...A novel structural damage detection method with a new damage index,i.e.,the statistical moment-based damage detection（SMBDD） method in the frequency domain,has been recently proposed.The aim of this study is to extend the SMBDD method in the frequency domain to the time domain for building structures subjected to non-Gaussian and non-stationary excitations.The applicability and effectiveness of the SMBDD method in the time domainis verified both numerically and experimentally.Shear buildings with various damage scenarios are first numerically investigated in the time domain taking into account the effect of measurement noise.The applicability of the proposed method in the time domain to building structures subjected to non-Gaussian and non-stationary excitations is then experimentally investigated through a series of shaking table tests,in which two three-story shear building models with four damage scenarios aretested.The identified damage locations and severities are then compared with the preset values.The comparative results are found to be satisfactory,and the SMBDD method is shown to be feasible and effective for building structures subjected to non-Gaussian and non-stationary excitations.展开更多
The phase stability,elastic properties and electronic structures of three typical Mg-Y intermetallics including Mg_(24)Y_(5),Mg_(2)Y and MgY are systematically investigated using first-principles calculations based on...The phase stability,elastic properties and electronic structures of three typical Mg-Y intermetallics including Mg_(24)Y_(5),Mg_(2)Y and MgY are systematically investigated using first-principles calculations based on density functional theory.The optimized structural parameters including lattice constants and atomic coordinates are in good agreement with experimental values.The calculated cohesive energies and formation enthalpies show that either phase stability or alloying ability of the three intermetallics is gradually enhanced with increasing Y content.The single-crystal elastic constants C_(ij) of Mg-Y intermetallics are also calculated,and the bulk modulus B,shear modulus G,Young's modulus E,Poisson ratio v and anisotropy factor A of polycrystalline materials are derived.It is suggested that the resistances to volume and shear deformation as well as the stiffness of the three intermetallics are raised with increasing Y content.Besides,these intermetallics all exhibit ductile characteristics,and they are isotropic in compression but anisotropic to a certain degree in shear and stiffness.Comparatively,Mg_(24)Y_(5) presents a relatively higher ductility,while MgY has a relatively stronger anisotropy in shear and stiffness.Further analysis of electronic structures indicates that the phase stability of Mg-Y intermetallics is closely related with their bonding electrons numbers below Fermi level.Namely,the more bonding electrons number below Fermi level corresponds to the higher structural stability of Mg-Y intermetallics.展开更多
Silica-based ceramic cores have been widely used to fabricate aero-engine hollow blades due to their moderate high temperature mechanical properties and excellent leachability.In this study,silica-based ceramics with ...Silica-based ceramic cores have been widely used to fabricate aero-engine hollow blades due to their moderate high temperature mechanical properties and excellent leachability.In this study,silica-based ceramics with SiC fiber addition were prepared via stereolithography,and the influence of SiC fiber content on mechanical properties of the obtained silica-based ceramics was investigated.With the increase of SiC fiber content,linear shrinkage gradually decreased,while room temperature flexural strength and high temperature flexural strength first increased and then decreased.As SiC fiber content increased to 4.0 wt%,linear shrinkage was reduced to 0.62%resulting from the oxidation of SiC.Furthermore,room temperature flexural strength was improved from 11.79 MPa to 23.83 MPa and high temperature flexural strength was enhanced from 15.64 MPa to 34.62 MPa with 4.0 wt%SiC fiber addition due to the reinforcement of fibers and the enhancedβ-cristobalite content,which meets the need of ceramic cores.Therefore,it demonstrates the capability of fabricating high-performance and high-precision silica-based ceramic cores reinforced by SiC fibers via stereolithography for rapid manufacturing of hollow blades.展开更多
Micaceous soils are common in many tropical countries and regions,and in some locations with moderate climate.The soils are spongy and unstable when loaded and are not considered suitable as construction material in e...Micaceous soils are common in many tropical countries and regions,and in some locations with moderate climate.The soils are spongy and unstable when loaded and are not considered suitable as construction material in earth structures.To resolve the issue,this work examined performance of micaceous soil reinforced with a combination of jute fibers,hydrated lime or slag-lime.A total of 28 sample sets were prepared at various dosages.Unconfined compression tests were conducted on the samples cured for 7 d and 28 d,respectively.The test results suggested that the unconfined compressive strength(UCS)and material stiffness were increased with the inclusion of up to 1%fiber and decreased if additional fibers were used.The ductility was improved consistently with up to 1.5%fiber content.The inclusions of fibers combined with hydrated lime or slag-lime further enhanced strength and stiffness of micaceous soil,and the improvement depended on the dosages used.For the dosages examined,jute fibers outweighed lime and slag in gaining ductility,and the optimal fiber content was 1%where strength and ductility were considered.展开更多
Anneal hardening has been one of the approaches to improve mechanical properties of solid solution alloys with the face-centered cubic(FCC) structure,whereby a considerable strengthening can be attained by annealing o...Anneal hardening has been one of the approaches to improve mechanical properties of solid solution alloys with the face-centered cubic(FCC) structure,whereby a considerable strengthening can be attained by annealing of cold-worked alloys below the recrystallization temperature(T_(rx)).Microscopically,this hardening effect has been ascribed to several mechanisms,i.e.solute segregation to defects(dislocation and stacking fault) and short-range chemical ordering,etc.However,none of these mechanisms can well explain the anneal hardening recently observed in phase-pure and coarse-grained FCC-structured high-entropy alloys(HEAs).Here we report the observations,using high-resolution electron channeling contrast imaging and transmission electron microscopy,of profuse and stable dislocation substructures in a cold-rolled CoCrFeMnNi HEA subject to an annealing below T_(rx).The dislocation substructures are observed to be thermally stable up to T_(rx),which could arise from the chemical complexity of the high-entropy system where certain elemental diffusion retardation occurs.The microstructure feature is markedly different from that of conventional dilute solid solution alloys,in which dislocation substructures gradually vanish by recovery during annealing,leading to a strength drop.Furthermore,dilute addition of 2 at.% Al leads to a reduction in both microhardness and yield strength of the cold-rolled and subsequently annealed(≤500℃) HEA.This Al induced softening effect,could be associated with the anisotropic formation of dislocation substructure,resulting from enhanced dislocation planar slip due to glide plane softening effect.These findings suggest that the strength of HEAs can be tailored through the anneal hardening effect from dislocation substructure strengthening.展开更多
In this work, a direct green solid-phase reduction method for the fabrication of large yield of ordered phase Fe-Pt alloy nanoparticles was reported, in which inorganic salts were used as metal precursors and H_2-cont...In this work, a direct green solid-phase reduction method for the fabrication of large yield of ordered phase Fe-Pt alloy nanoparticles was reported, in which inorganic salts were used as metal precursors and H_2-containing atmosphere was used as reducer. Utilizing this method, the composition and chemical ordered phase, such as L1_2-Fe_3 Pt, L1_2-FePt_3, and L1_0-FePt phases can be easily achieved by one step reaction. The synthesized nanoparticles have clean surface because no organic precursors, no organic solutions or organic surfactants/ligands were used. Their magnetic performance and the formation mechanism of Fe-Pt alloy nanoparticles were also investigated. This strategy can be applied to synthesize many other types of alloy nanoparticles with desired composition and necessary crystal structure, which can be used for a variety of practical applications, such as in magnetism and catalyst research fields.展开更多
The low-cycle fatigue （LCF） properties of DD10 （single-crystal） and DZ53 （columnar-grained） superalloys solidified by liquid-metal cooling （LMC） and high-rate solidification （HRS） processes have been systema...The low-cycle fatigue （LCF） properties of DD10 （single-crystal） and DZ53 （columnar-grained） superalloys solidified by liquid-metal cooling （LMC） and high-rate solidification （HRS） processes have been systematically investi- gated. It was found that the LCF life of DZ53 solidified by LMC was obviously better than that solidified by HRS. In contrast, for DD10, LMC showed no remarkable influences on LCF properties at high temperature and only improved LCF properties at intermediate temperature. Microstructure examination showed that the cracks generally initiated at microp- ores in the subsurface at intermediate temperature. However, the cracks occurred on the surface due to oxidation, or persistent slip bands near script-MC at high temperature. Therefore, the benefits of LMC technique can be attributed to both of the reduced casting defects which significantly affect the LCF properties at intermediate temperature and the improved microstructural homogeneity which was strongly correlated to the LCF properties of alloys at high temperature.展开更多
Based on the experimental results of the ratcheting for SS304 stainless steel, a new visco-plastic cyclic constitutive model was established to describe the uniaxial and multiaxial ratcheting of the material at room a...Based on the experimental results of the ratcheting for SS304 stainless steel, a new visco-plastic cyclic constitutive model was established to describe the uniaxial and multiaxial ratcheting of the material at room and elevated temperatures within the framework of unified visco-plasticity. In the model, the temperature dependence of the ratcheting was emphasized, and the dynamic strain aging occurred in the temperature range of 4 00-600℃ for the material was taken into account particularly. Finally, the prediction capability of the developed model was checked by comparing to the corresponding experimental results.展开更多
In contrast to ion beams produced by conventional accelerators,ion beams accelerated by ultrashort intense laser pulses have advantages of ultrashort bunch duration and ultrahigh density,which are achieved in compact ...In contrast to ion beams produced by conventional accelerators,ion beams accelerated by ultrashort intense laser pulses have advantages of ultrashort bunch duration and ultrahigh density,which are achieved in compact size.However,it is still challenging to simultaneously enhance their quality and yield for practical applications such as fast ion ignition of inertial confinement fusion.Compared with other mechanisms of laser-driven ion acceleration,the hole-boring radiation pressure acceleration has a special advantage in generating high-fluence ion beams suitable for the creation of high energy density state of matters.In this paper,we present a review on some theoretical and numerical studies of the hole-boring radiation pressure acceleration.First we discuss the typical field structure associated with this mechanism,its intrinsic feature of oscillations,and the underling physics.Then we will review some recently proposed schemes to enhance the beam quality and the efficiency in the hole-boring radiation pressure acceleration,such as matching laser intensity profile with target density profile,and using two-ion-species targets.Based on this,we propose an integrated scheme for efficient high-quality hole-boring radiation pressure acceleration,in which the longitudinal density profile of a composite target as well as the laser transverse intensity profile are tailored according to the matching condition.展开更多
Sunlight-like lasers that have a continuous broad frequency spectrum,random phase spectrum,and random polarization are formulated theoretically.With a sunlight-like laser beam consisting of a sequence of temporal spec...Sunlight-like lasers that have a continuous broad frequency spectrum,random phase spectrum,and random polarization are formulated theoretically.With a sunlight-like laser beam consisting of a sequence of temporal speckles,the resonant three-wave coupling that underlies parametric instabilities in laser–plasma interactions can be greatly degraded owing to the limited duration of each speckle and the frequency shift between two adjacent speckles.The wave coupling can be further weakened by the random polarization of such beams.Numerical simulations demonstrate that the intensity threshold of stimulated Raman scattering in homogeneous plasmas can be doubled by using a sunlight-like laser beam with a relative bandwidth of∼1%as compared with a monochromatic laser beam.Consequently,the hot-electron generation harmful to inertial confinement fusion can be effectively controlled by using sunlight-like laser drivers.Such drivers may be realized in the next generation of broadband lasers by combining two or more broadband beams with independent phase spectra or by applying polarization smoothing to a single broadband beam.展开更多
Micaceous soil is a problematic soil due to its low strength and poor ductility.In this context,the performances of micaceous soils were improved by applying a combination of granulated blast furnace slag,fiber and po...Micaceous soil is a problematic soil due to its low strength and poor ductility.In this context,the performances of micaceous soils were improved by applying a combination of granulated blast furnace slag,fiber and polymer additive.The dosages examined included 0%e30%mica,3%e15%slag and 0.25%e1.25%fiber by weight,and 0.1e0.5 g/L polymer additive.Most of the combinations were found to increase the material strength and ductility,yet to be optimized.To refine the dosage,response surface method was used to conduct experimental design and develop predictive models for material strength.The developed models formulate the material strength as a nonlinear function of dosages and,by interrogating it,can optimize additive contents in terms of target requirements.The models were verified through trials and can be used to determine dosages to upscale micaceous soils to field conditions.展开更多
We report experimental discovery of tantalum polyhydride superconductor.It was synthesized under highpressure and high-temperature conditions using diamond anvil cell combined with in situ high-pressure laser heating ...We report experimental discovery of tantalum polyhydride superconductor.It was synthesized under highpressure and high-temperature conditions using diamond anvil cell combined with in situ high-pressure laser heating techniques.The superconductivity was investigated via resistance measurements at pressures.The highest superconducting transition temperature T_(c)was found to be~30 K at 197 GPa in the sample that was synthesized at the same pressure with~2000 K heating.The transitions are shifted to low temperature upon applying magnetic fields that support the superconductivity nature.The upper critical field at zero temperatureμ_0H_(c2)(0)of the superconducting phase is estimated to be~20 T that corresponds to Ginzburg-Landau coherent length~40 A.Our results suggest that the superconductivity may arise from 143d phase of TaH_(3).It is,for the first time to our best knowledge,experimental realization of superconducting hydrides for the VB group of transition metals.展开更多
基金supported by the National Key Research and Development Program of Chinathe National Natural Science Foundation of China (Grant Nos.2024YFA1408000,12474097,and2023YFA1406001)+2 种基金the Guangdong Provincial Quantum Science Strategic Initiative (Grant No.GDZX2201001)the Center for Computational Science and Engineering at Southern University of Science and Technology,the Major Science and Technology Infrastructure Project of Material Genome Big-science Facilities Platform supported by Municipal Development and Reform Commission of Shenzhen(for J.L.Z.and Y.L.)the Chinese funding sources applied via HPSTAR。
文摘The magnetic properties and Kondo effect in Ce3TiBi5 with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) undergoes an antiferromagnetic(AFM)transition at T_(N)∼5 K.Under high pressures within 8.9 GPa,we find that Kondo scattering contributes differently to the high-temperature resistance,R(T),depending on the applied current direction,demonstrating a significantly anisotropic Kondo effect.The complete P–T phase diagram has been constructed,in which the pressure dependence of T_(N) exhibits a dome-like shape.The AFM order remains robust under pressure,even when the coherence temperature T^(*) far exceeds 300 K.We attribute the observed anisotropic Kondo effect and the robust AFM to the underlying anisotropy in electronic hybridization under high pressure.
基金financial support from the LASERLAB-EUROPE Access to Research Infrastructure Activity (Application No. 23068)carried out within the framework of EUROfusion Enabling Research Projects AWP21-ENR-01-CEA02 and AWP24-ENR-IFE-02-CEA-02+3 种基金received funding from Euratom Research and Training Programme 2021–2025 under Grant No. 633053supported by the Ministry of Youth and Sports of the Czech Republic [Project No. LM2023068 (PALS RI)]by the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant Nos. XDA25030200 and XDA25010100)supported by COST (European Cooperation in Science and Technology) through Action CA21128 PROBONO (PROton BOron Nuclear Fusion: from energy production to medical applicatiOns)
文摘Recent experiments at the National Ignition Facility and theoretical modeling suggest that side stimulated Raman scattering(SSRS)instability could reduce laser–plasma coupling and generate considerable fluxes of suprathermal hot electrons under interaction conditions envisaged for direct-drive schemes for inertial confinement fusion.Nonetheless,SSRS remains to date one of the least understood parametric instabilities.Here,we report the first angularly and spectrally resolved measurements of scattered light at laser intensities relevant for the shock ignition scheme(I×10^(16)W/cm^(2)),showing significant SSRS growth in the direction perpendicular to the laser polarization.Modification of the focal spot shape and orientation,obtained by using two different random phase plates,and of the density gradient of the plasma,by utilizing exploding foil targets of different thicknesses,clearly reveals a different dependence of backward SRS(BSRS)and SSRS on experimental parameters.While convective BSRS scales with plasma density scale length,as expected by linear theory,the growth of SSRS depends on the spot extension in the direction perpendicular to laser polarization.Our analysis therefore demonstrates that under current experimental conditions,with density scale lengths L_(n)≈60–120μm and spot sizes FWHM≈40–100μm,SSRS is limited by laser beam size rather than by the density scale length of the plasma.
基金supported by the Guangdong Basic and Applied Basic Research Foundation(No.2020B1515120013)the National Natural Science Foundation of China(Nos.51971108 and 52271032)+1 种基金the Key Research and Development Program of Jiangsu Province(No.K22251901)the Shenzhen Science and Technology Innovation Commission(Nos.JCYJ20220818100612027 and JSGG20210420091802007).
文摘The Ti-6Al-4V alloy is the most widely utilized titanium metal alloy globally,making the enhancement of its mechanical properties important.In this study,we achieved an ultimate tensile strength of 1.5 GPa through the additive manufacturing(AM)of Ti-6Al-4V.Specifically,the Ti-6Al-4V alloy was fabricated via laser powder bed fusion(L-PBF)using Ti-6Al-4V powder subjected to cold plastic deformation(CPD Ti-6Al-4V).The microstructural evolution of the Ti-6Al-4V powder during CPD was analyzed in detail.The CPD Ti-6Al-4V powder exhibited a core-shell structure with subgrains and nanocrystals formed via high-density dislocations within the shell.In addition,the as-printed CPD Ti-6Al-4V alloy had an average grain size of approximately 1.9µm.The presence of interstitial elements and finer grains resulted in the formation of Ti-6Al-4V alloys with ultrahigh strengths(ultimate tensile strength of approximately 1500 MPa,yield strength of 1320 MPa,and elongation of 6%).This groundbreaking achievement paves the way for further advancements in AM technology and presents exciting opportunities for innovation across a range of high-strength materials,which are crucial for achieving optimal performance.
基金supported by the National Natural Science Foundation of China(No.50271056)National High Technical Research and Development Programme of China(No.2003AA305810)the Special Research Fund for Doctoral Disciplines in Colleges and Universities of M.0.E,China(No.20020699025).
文摘The directionally solidified samples of an ultra-high temperature Nb-Si-Ti-Hf-Cr-Al alloy have been prepared with the use of an electron beam floating zone melting (EBFZM) furnace, and their microstructural characteristics have been analyzed. All the primary dendrites of Nb solid solution (Nbss), eutectic colonies of Nba, plus (Nb, Ti)3 Si/(Nb, Ti)5 Si3 and chains of (Nb, Ti)3 Si/(Nb, Ti)5 Si3 plates align along the growth direction of the samples. With increasing of the withdrawing rate, the microstructure is refined, and the amounts of Nbss+ (Nb, Ti)3 Si/(Nb, Ti)5 Si3 eutectic colonies and (Nb, Ti)3 Si/(Nb, Ti)5 Si3 plates increase. There appear nodes in the (Nb, Ti)3 Si/(Nb, Ti)5 Si3 plates.
基金the Shanghai Synchrotron Radiation Facility (SSRF)the financial support of the project from the National Basic Research Program of China (No.2010CB631201)the National High Technology Research and Development Program of China (No.2012AA03A511 and No.2012AA03A513)
文摘The effect of Mo addition on microstructural characteristics of a nickel-base single crystal superalloy containing 4 wt% Re was investigated. The γ/γ’ partitioning ratios determined by energy dispersive spectrometer attached to a transmission electron microscope showed that the addition of Mo enhanced the partitioning of Re,W and Cr in the g matrix while decreased the concentration of Ta in the matrix. Synchrotron radiation diffraction was adopted to measure the γ/γ’ lattice misfit at room temperature. The results indicated that Mo addition changed the γ/γ’ lattice misfit towards larger negative as well as increased the tetragonal distortion of the γ lattice. Additionally,Mo addition led to microstructural instability and altered the precipitation behavior of topologically close-packed phases during 1100 C exposure. Instead of precipitating directly from the matrix,the μ phase was observed to be converted from the α phase which precipitated preferentially as a metastable intermediate in the alloy with high Mo content.
基金supported by the National Nature Science Foundation of China (Grant Nos. 51372049, 51321061 and U1537206)
文摘Porous Si3N4 was brazed to Invar alloy in this study, and Ag-Cu-Ti/Cu/Ag-Cu multi-layered filler was designed to inhibit the formation of Fe2Ti and Ni3Ti intermetallic compounds. The effects of the brazing temperature and the thickness of Cu interlayer on the microstructure and mechanical properties of brazed joints were investigated. The typical microstructure of the joint brazed with multi-layered filler was porous Si3N4/TiN ＋ Ti5Si3/Ag-Cu eutectic[Cu[Ag-Cu eutectic/Cu-rich layer ＋ diffusion layer/Invar. When the brazing temperature increased, the reaction layer at the ceramic/filler interface grew thicker and the Cu interlayer turned thinner. As the thickness of Cu interlayer increased from 50 to 150 μm, the joint strength first increased and then decreased. In this research, the maximum shear strength （73 MPa） was obtained when being brazed at 1173 K with a 100 μm Cu interlayer applied in the filler, which was 55% higher than that brazed with single Ag-Cu-Ti brazing alloy and had reached 86% of the ceramic. The release of residual stress and the barrier effect of Cu interlayer to inhibit the formation of Fe2Ti and Ni3Ti intermetallics played the major role in the improvement of joint strength.
基金The Hong Kong Polytechnic University through a PhD studentship for the first authorthe Research Grants Council of Hong Kong (PolyU 5319/10E) for the second author
文摘A novel structural damage detection method with a new damage index,i.e.,the statistical moment-based damage detection（SMBDD） method in the frequency domain,has been recently proposed.The aim of this study is to extend the SMBDD method in the frequency domain to the time domain for building structures subjected to non-Gaussian and non-stationary excitations.The applicability and effectiveness of the SMBDD method in the time domainis verified both numerically and experimentally.Shear buildings with various damage scenarios are first numerically investigated in the time domain taking into account the effect of measurement noise.The applicability of the proposed method in the time domain to building structures subjected to non-Gaussian and non-stationary excitations is then experimentally investigated through a series of shaking table tests,in which two three-story shear building models with four damage scenarios aretested.The identified damage locations and severities are then compared with the preset values.The comparative results are found to be satisfactory,and the SMBDD method is shown to be feasible and effective for building structures subjected to non-Gaussian and non-stationary excitations.
基金This work was financially supported by the National Natural Science Foundation of China(No.51401036)the Hunan Provincial Natural Science Foundation of China(No.14JJ3086),the Research Foundation of Education Bureau of Hunan Province(No.12B001)the Key Laboratory of Efficient and Clean Energy Utilization,College of Hunan Province(No.2015NGQ005).
文摘The phase stability,elastic properties and electronic structures of three typical Mg-Y intermetallics including Mg_(24)Y_(5),Mg_(2)Y and MgY are systematically investigated using first-principles calculations based on density functional theory.The optimized structural parameters including lattice constants and atomic coordinates are in good agreement with experimental values.The calculated cohesive energies and formation enthalpies show that either phase stability or alloying ability of the three intermetallics is gradually enhanced with increasing Y content.The single-crystal elastic constants C_(ij) of Mg-Y intermetallics are also calculated,and the bulk modulus B,shear modulus G,Young's modulus E,Poisson ratio v and anisotropy factor A of polycrystalline materials are derived.It is suggested that the resistances to volume and shear deformation as well as the stiffness of the three intermetallics are raised with increasing Y content.Besides,these intermetallics all exhibit ductile characteristics,and they are isotropic in compression but anisotropic to a certain degree in shear and stiffness.Comparatively,Mg_(24)Y_(5) presents a relatively higher ductility,while MgY has a relatively stronger anisotropy in shear and stiffness.Further analysis of electronic structures indicates that the phase stability of Mg-Y intermetallics is closely related with their bonding electrons numbers below Fermi level.Namely,the more bonding electrons number below Fermi level corresponds to the higher structural stability of Mg-Y intermetallics.
基金supported by National Science and Technology Major Project(no.2017-Ⅶ-0008-0102)National Natural Science Foundation of China(no.51975230)Fundamental Research Funds for the Central Universities(nos.2019kfy XMPY020,2020kfy FPZX003,2018KFYYXJJ030,2019kfy XKJC011)。
文摘Silica-based ceramic cores have been widely used to fabricate aero-engine hollow blades due to their moderate high temperature mechanical properties and excellent leachability.In this study,silica-based ceramics with SiC fiber addition were prepared via stereolithography,and the influence of SiC fiber content on mechanical properties of the obtained silica-based ceramics was investigated.With the increase of SiC fiber content,linear shrinkage gradually decreased,while room temperature flexural strength and high temperature flexural strength first increased and then decreased.As SiC fiber content increased to 4.0 wt%,linear shrinkage was reduced to 0.62%resulting from the oxidation of SiC.Furthermore,room temperature flexural strength was improved from 11.79 MPa to 23.83 MPa and high temperature flexural strength was enhanced from 15.64 MPa to 34.62 MPa with 4.0 wt%SiC fiber addition due to the reinforcement of fibers and the enhancedβ-cristobalite content,which meets the need of ceramic cores.Therefore,it demonstrates the capability of fabricating high-performance and high-precision silica-based ceramic cores reinforced by SiC fibers via stereolithography for rapid manufacturing of hollow blades.
基金the Australian Government Research Training Program Scholarship and University of Adelaide Scholarship.
文摘Micaceous soils are common in many tropical countries and regions,and in some locations with moderate climate.The soils are spongy and unstable when loaded and are not considered suitable as construction material in earth structures.To resolve the issue,this work examined performance of micaceous soil reinforced with a combination of jute fibers,hydrated lime or slag-lime.A total of 28 sample sets were prepared at various dosages.Unconfined compression tests were conducted on the samples cured for 7 d and 28 d,respectively.The test results suggested that the unconfined compressive strength(UCS)and material stiffness were increased with the inclusion of up to 1%fiber and decreased if additional fibers were used.The ductility was improved consistently with up to 1.5%fiber content.The inclusions of fibers combined with hydrated lime or slag-lime further enhanced strength and stiffness of micaceous soil,and the improvement depended on the dosages used.For the dosages examined,jute fibers outweighed lime and slag in gaining ductility,and the optimal fiber content was 1%where strength and ductility were considered.
基金financially supported by the National Natural Science Foundation of China (No. 52001120)the Fundamental Research Funds for the Central Universities (No. 531118010450)+10 种基金the Hundred Talent Program of Hunan Provincethe State Key Laboratory of Powder Metallurgy,Central South University,Changshathe State Key Laboratory of Advanced Metals and Materials(No. 2021-Z09)University of Science&Technology Beijing,Chinasupported by the National Natural Science Foundation of China (No. 51801060)supported by the Swedish Research Councilsupported by the National Science Foundation under Contract (No. DMR-1408722)sponsored by the Whiting School of EngineeringJohns Hopkins Universityfunded by the National Key Research and Development Program of China (No. 2016YFB0300801)the National NaturalScience Foundation of China (Nos. 51831004, 11427806, 51671082,51471067)。
文摘Anneal hardening has been one of the approaches to improve mechanical properties of solid solution alloys with the face-centered cubic(FCC) structure,whereby a considerable strengthening can be attained by annealing of cold-worked alloys below the recrystallization temperature(T_(rx)).Microscopically,this hardening effect has been ascribed to several mechanisms,i.e.solute segregation to defects(dislocation and stacking fault) and short-range chemical ordering,etc.However,none of these mechanisms can well explain the anneal hardening recently observed in phase-pure and coarse-grained FCC-structured high-entropy alloys(HEAs).Here we report the observations,using high-resolution electron channeling contrast imaging and transmission electron microscopy,of profuse and stable dislocation substructures in a cold-rolled CoCrFeMnNi HEA subject to an annealing below T_(rx).The dislocation substructures are observed to be thermally stable up to T_(rx),which could arise from the chemical complexity of the high-entropy system where certain elemental diffusion retardation occurs.The microstructure feature is markedly different from that of conventional dilute solid solution alloys,in which dislocation substructures gradually vanish by recovery during annealing,leading to a strength drop.Furthermore,dilute addition of 2 at.% Al leads to a reduction in both microhardness and yield strength of the cold-rolled and subsequently annealed(≤500℃) HEA.This Al induced softening effect,could be associated with the anisotropic formation of dislocation substructure,resulting from enhanced dislocation planar slip due to glide plane softening effect.These findings suggest that the strength of HEAs can be tailored through the anneal hardening effect from dislocation substructure strengthening.
基金financially supported by the National Natural Science Foundation of China (Grant Nos.51772220,51772219,51771095,51422106)Zhejiang Provincial Natural Science Foundation of China (No.D19E010001)the National Basic Research Program of China (Grant No.2014CB643702)
文摘In this work, a direct green solid-phase reduction method for the fabrication of large yield of ordered phase Fe-Pt alloy nanoparticles was reported, in which inorganic salts were used as metal precursors and H_2-containing atmosphere was used as reducer. Utilizing this method, the composition and chemical ordered phase, such as L1_2-Fe_3 Pt, L1_2-FePt_3, and L1_0-FePt phases can be easily achieved by one step reaction. The synthesized nanoparticles have clean surface because no organic precursors, no organic solutions or organic surfactants/ligands were used. Their magnetic performance and the formation mechanism of Fe-Pt alloy nanoparticles were also investigated. This strategy can be applied to synthesize many other types of alloy nanoparticles with desired composition and necessary crystal structure, which can be used for a variety of practical applications, such as in magnetism and catalyst research fields.
基金financially supported by the National Natural Science Foundation of China under Grant Nos.51631008,51101160 and 2010CB631201
文摘The low-cycle fatigue （LCF） properties of DD10 （single-crystal） and DZ53 （columnar-grained） superalloys solidified by liquid-metal cooling （LMC） and high-rate solidification （HRS） processes have been systematically investi- gated. It was found that the LCF life of DZ53 solidified by LMC was obviously better than that solidified by HRS. In contrast, for DD10, LMC showed no remarkable influences on LCF properties at high temperature and only improved LCF properties at intermediate temperature. Microstructure examination showed that the cracks generally initiated at microp- ores in the subsurface at intermediate temperature. However, the cracks occurred on the surface due to oxidation, or persistent slip bands near script-MC at high temperature. Therefore, the benefits of LMC technique can be attributed to both of the reduced casting defects which significantly affect the LCF properties at intermediate temperature and the improved microstructural homogeneity which was strongly correlated to the LCF properties of alloys at high temperature.
基金supported by the Theoretical Research Fund of Sichuan Province(No.03JY029-062-2)the Scientific Research Foundation for the Returned Overseas Chinese Scholars(SRF-ROCS),State Education Ministry of China(No.2003-406-01).
文摘Based on the experimental results of the ratcheting for SS304 stainless steel, a new visco-plastic cyclic constitutive model was established to describe the uniaxial and multiaxial ratcheting of the material at room and elevated temperatures within the framework of unified visco-plasticity. In the model, the temperature dependence of the ratcheting was emphasized, and the dynamic strain aging occurred in the temperature range of 4 00-600℃ for the material was taken into account particularly. Finally, the prediction capability of the developed model was checked by comparing to the corresponding experimental results.
基金This work was supported in part by the National Basic Research Program of China(Grant No.2013CBA01504)the National Natural Science Foundation of China(Grant Nos.11675108,11421064,11405108 and 11374210).
文摘In contrast to ion beams produced by conventional accelerators,ion beams accelerated by ultrashort intense laser pulses have advantages of ultrashort bunch duration and ultrahigh density,which are achieved in compact size.However,it is still challenging to simultaneously enhance their quality and yield for practical applications such as fast ion ignition of inertial confinement fusion.Compared with other mechanisms of laser-driven ion acceleration,the hole-boring radiation pressure acceleration has a special advantage in generating high-fluence ion beams suitable for the creation of high energy density state of matters.In this paper,we present a review on some theoretical and numerical studies of the hole-boring radiation pressure acceleration.First we discuss the typical field structure associated with this mechanism,its intrinsic feature of oscillations,and the underling physics.Then we will review some recently proposed schemes to enhance the beam quality and the efficiency in the hole-boring radiation pressure acceleration,such as matching laser intensity profile with target density profile,and using two-ion-species targets.Based on this,we propose an integrated scheme for efficient high-quality hole-boring radiation pressure acceleration,in which the longitudinal density profile of a composite target as well as the laser transverse intensity profile are tailored according to the matching condition.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA25050100)the National Natural Science Foundation of China(Grant Nos.11975154,11675108,11655002,and 11775144)+3 种基金the Science Challenge Project(Grant No.TZ2018005)the China Scholarship Council,the China and Germany Postdoctoral Exchange Program from the Office of China Postdoctoral Council and the Helmholtz Centre(Grant No.20191016)the China Postdoctoral Science Foundation(Grant No.2018M641993)funding from the European Union Horizon 2020 Research and Innovation Programme under Grant Agreement No.633053.
文摘Sunlight-like lasers that have a continuous broad frequency spectrum,random phase spectrum,and random polarization are formulated theoretically.With a sunlight-like laser beam consisting of a sequence of temporal speckles,the resonant three-wave coupling that underlies parametric instabilities in laser–plasma interactions can be greatly degraded owing to the limited duration of each speckle and the frequency shift between two adjacent speckles.The wave coupling can be further weakened by the random polarization of such beams.Numerical simulations demonstrate that the intensity threshold of stimulated Raman scattering in homogeneous plasmas can be doubled by using a sunlight-like laser beam with a relative bandwidth of∼1%as compared with a monochromatic laser beam.Consequently,the hot-electron generation harmful to inertial confinement fusion can be effectively controlled by using sunlight-like laser drivers.Such drivers may be realized in the next generation of broadband lasers by combining two or more broadband beams with independent phase spectra or by applying polarization smoothing to a single broadband beam.
文摘Micaceous soil is a problematic soil due to its low strength and poor ductility.In this context,the performances of micaceous soils were improved by applying a combination of granulated blast furnace slag,fiber and polymer additive.The dosages examined included 0%e30%mica,3%e15%slag and 0.25%e1.25%fiber by weight,and 0.1e0.5 g/L polymer additive.Most of the combinations were found to increase the material strength and ductility,yet to be optimized.To refine the dosage,response surface method was used to conduct experimental design and develop predictive models for material strength.The developed models formulate the material strength as a nonlinear function of dosages and,by interrogating it,can optimize additive contents in terms of target requirements.The models were verified through trials and can be used to determine dosages to upscale micaceous soils to field conditions.
基金the National Natural Science Foundation of China(Grant No.11921004)the National Key R&D Program of China(Grant Nos.2021YFA1401800 and 2022YFA1402301)+2 种基金Chinese Academy of Sciences(Grant No.XDB33010200)supported by the National Science Foundation Earth Sciences(EAR 1634415)used resources of the Advanced Photon Source,a U.S.Department of Energy(DOE)Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory(Grant No.DEAC02-06CH11357)。
文摘We report experimental discovery of tantalum polyhydride superconductor.It was synthesized under highpressure and high-temperature conditions using diamond anvil cell combined with in situ high-pressure laser heating techniques.The superconductivity was investigated via resistance measurements at pressures.The highest superconducting transition temperature T_(c)was found to be~30 K at 197 GPa in the sample that was synthesized at the same pressure with~2000 K heating.The transitions are shifted to low temperature upon applying magnetic fields that support the superconductivity nature.The upper critical field at zero temperatureμ_0H_(c2)(0)of the superconducting phase is estimated to be~20 T that corresponds to Ginzburg-Landau coherent length~40 A.Our results suggest that the superconductivity may arise from 143d phase of TaH_(3).It is,for the first time to our best knowledge,experimental realization of superconducting hydrides for the VB group of transition metals.
