With an excellent power conversion efficiency of 25.7%,closer to the Shockley–Queisser limit,perovskite solar cells(PSCs)have become a strong candidate for a next-generation energy harvester.However,the lack of stabi...With an excellent power conversion efficiency of 25.7%,closer to the Shockley–Queisser limit,perovskite solar cells(PSCs)have become a strong candidate for a next-generation energy harvester.However,the lack of stability and reliability in PSCs remained challenging for commercialization.Strategies,such as interfacial and structural engineering,have a more critical influence on enhanced performance.MXenes,two-dimensional materials,have emerged as promising materials in solar cell applications due to their metallic electrical conductivity,high carrier mobility,excellent optical transparency,wide tunable work function,and superior mechanical properties.Owing to different choices of transition elements and surface-terminating functional groups,MXenes possess the feature of tuning the work function,which is an essential metric for band energy alignment between the absorber layer and the charge transport layers for charge carrier extraction and collection in PSCs.Furthermore,adopting MXenes to their respective components helps reduce the interfacial recombination resistance and provides smooth charge transfer paths,leading to enhanced conductivity and operational stability of PSCs.This review paper aims to provide an overview of the applications of MXenes as components,classified according to their roles as additives(into the perovskite absorber layer,charge transport layers,and electrodes)and themselves alone or as interfacial layers,and their significant importance in PSCs in terms of device performance and stability.Lastly,we discuss the present research status and future directions toward its use in PSCs.展开更多
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(No.2022M3J7A1062940 and 2022033777)supported by Korea Electric Power Corporation(Grant Number:R21XO01-5)+2 种基金supported by the Technology Innovation Program(or Industrial Strategic Technology Development Program)(1415172732/20011410,Development of SPD smart film and service of aftermarket for energy saving in building and automobiles)the Ministry of Trade,Industry&Energy(MOTIE,Korea)supported by Basic Science Research Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(2018R1A6A1A03023788 and 2021R1I1A1A01055790).
文摘With an excellent power conversion efficiency of 25.7%,closer to the Shockley–Queisser limit,perovskite solar cells(PSCs)have become a strong candidate for a next-generation energy harvester.However,the lack of stability and reliability in PSCs remained challenging for commercialization.Strategies,such as interfacial and structural engineering,have a more critical influence on enhanced performance.MXenes,two-dimensional materials,have emerged as promising materials in solar cell applications due to their metallic electrical conductivity,high carrier mobility,excellent optical transparency,wide tunable work function,and superior mechanical properties.Owing to different choices of transition elements and surface-terminating functional groups,MXenes possess the feature of tuning the work function,which is an essential metric for band energy alignment between the absorber layer and the charge transport layers for charge carrier extraction and collection in PSCs.Furthermore,adopting MXenes to their respective components helps reduce the interfacial recombination resistance and provides smooth charge transfer paths,leading to enhanced conductivity and operational stability of PSCs.This review paper aims to provide an overview of the applications of MXenes as components,classified according to their roles as additives(into the perovskite absorber layer,charge transport layers,and electrodes)and themselves alone or as interfacial layers,and their significant importance in PSCs in terms of device performance and stability.Lastly,we discuss the present research status and future directions toward its use in PSCs.
