Tocopherol is the most active vitamin and natural antioxidant existing in the nature known as vitamin E. Lacking of this vitamin makes drastic exchanges on the health of the living organisms. Their active chemical for...Tocopherol is the most active vitamin and natural antioxidant existing in the nature known as vitamin E. Lacking of this vitamin makes drastic exchanges on the health of the living organisms. Their active chemical form is l-α-tocopherol substance. In this article, α-thiotocopherol a tocopherol derivative was synthesized via a precursor like dl-α-tocopherol, which has better antioxidant than natural α-tocopherol. And the last compound after separation and purification via TLC and PC procedures was analyzed by FTIR, GC-MS and elemental analysis, oxidative stability is tested with TGA method in air showing roughly antioxidant effect. Another approach is measurment of redox potential against a reference electrode under inert nitrogen atmosphere.展开更多
A new type of methacrylate monomer, 2-（4-benzoylphenoxy）-2-oxoethyl methylacrylate （BOEMA） was synthesized. The radical homopolymerization of BOEMA was performed at 65℃ in a 1,4-dioxane solution with benzoyl pero...A new type of methacrylate monomer, 2-（4-benzoylphenoxy）-2-oxoethyl methylacrylate （BOEMA） was synthesized. The radical homopolymerization of BOEMA was performed at 65℃ in a 1,4-dioxane solution with benzoyl peroxide as an initiator. The oxime and thiosemicarbazone derivatives of poly[2-（4-benzoylphenoxy）-2-oxoethyl methylacrylate] poly（BOEMA） were prepared with hydroxylamine hydrochloride, and thiosemicarbazone hydrochloride, respectively. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly（BOEMA） and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers was compared. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa and Kissinger methods.展开更多
The synthesis of two new methacrylates such as 2-[(cyclohexylideneamino)oxy]-2-oxoethyl methylacrylate (CHOEMA)and 2-[(cyclopentylideneamino)oxy]-2-oxoethyl methylacrylate(CPOEMA)are described.The monomers produced fr...The synthesis of two new methacrylates such as 2-[(cyclohexylideneamino)oxy]-2-oxoethyl methylacrylate (CHOEMA)and 2-[(cyclopentylideneamino)oxy]-2-oxoethyl methylacrylate(CPOEMA)are described.The monomers produced from the reaction of corresponding cyclohexanone O-(2-chloroacetyl)oxime and cyclopentanone O-(2- chloroacetyl)oxime with sodium methacrylate was polymerized in 1,4-dioxane solution at 65℃using AIBN as an initiator. The monomers and their polymers were characterized by IR,~1H- and ^(13)C-NMR spec...展开更多
文摘Tocopherol is the most active vitamin and natural antioxidant existing in the nature known as vitamin E. Lacking of this vitamin makes drastic exchanges on the health of the living organisms. Their active chemical form is l-α-tocopherol substance. In this article, α-thiotocopherol a tocopherol derivative was synthesized via a precursor like dl-α-tocopherol, which has better antioxidant than natural α-tocopherol. And the last compound after separation and purification via TLC and PC procedures was analyzed by FTIR, GC-MS and elemental analysis, oxidative stability is tested with TGA method in air showing roughly antioxidant effect. Another approach is measurment of redox potential against a reference electrode under inert nitrogen atmosphere.
文摘A new type of methacrylate monomer, 2-（4-benzoylphenoxy）-2-oxoethyl methylacrylate （BOEMA） was synthesized. The radical homopolymerization of BOEMA was performed at 65℃ in a 1,4-dioxane solution with benzoyl peroxide as an initiator. The oxime and thiosemicarbazone derivatives of poly[2-（4-benzoylphenoxy）-2-oxoethyl methylacrylate] poly（BOEMA） were prepared with hydroxylamine hydrochloride, and thiosemicarbazone hydrochloride, respectively. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly（BOEMA） and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers was compared. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa and Kissinger methods.
基金Afyon Kocatepe Universty Research Fund(No.06-FENED-09)
文摘The synthesis of two new methacrylates such as 2-[(cyclohexylideneamino)oxy]-2-oxoethyl methylacrylate (CHOEMA)and 2-[(cyclopentylideneamino)oxy]-2-oxoethyl methylacrylate(CPOEMA)are described.The monomers produced from the reaction of corresponding cyclohexanone O-(2-chloroacetyl)oxime and cyclopentanone O-(2- chloroacetyl)oxime with sodium methacrylate was polymerized in 1,4-dioxane solution at 65℃using AIBN as an initiator. The monomers and their polymers were characterized by IR,~1H- and ^(13)C-NMR spec...
