Polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) emissions in flue gas from two types of municipal solid waste incinerators (MSWIs) most commonly used in China were investigated in this study. The selected i...Polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) emissions in flue gas from two types of municipal solid waste incinerators (MSWIs) most commonly used in China were investigated in this study. The selected incinerators include two grate-type MSWIs: MSWI-A (350 t/d) and MSWI-B 050 t/d), and two fluidized bed MSWIs: MSWI-C (400 t/d) and MSWI-D (400 t/d), which are all equipped with semi-dry lime scrubber and bag filter except MSWI-D equipped with cyclone and wet scrubber (WS) as air pollutant control device (APCD). Results indicated that the emission concentration and the international toxic equivalents (I-TEQs) of the PCDD/Fs from the stacks were in the range of 1.210-10.273 ng/Nm^3 and 0.019-0.201 ng I-TEQ/Nm^3, respectively. They were greatly lower than the emission regulation standard of PCDD/Fs in China (1.0 ng I-TEQ/Nm^3). However, only the PCDD/Fs emission level from MSWI-C was below 0.1 ng I-TEQ/Nm^3. Although the homologue profiles were distinct, the contributions of the 2,3,7,8-subsituted congeners to the total I-TEQ were similar among all the investigated MSWIs. Two major 2,3,7,8-substituted congeners, 2,3,4,7,8-PeCDF and 1,2,3,7,8-PeCDD, account for 47% and 9% (average values) of the total I-TEQ values, respectively. The correlation between PCDD/Fs levels and composition of flue gas was also discussed.展开更多
BACKGROUND:Hepatic veno-occlusive disease(VOD)or sinusoidal obstruction syndrome is associated with a high mortality because of its severity.Gymura segetum,a Chinese herbal medicine,is always used to cure injury and b...BACKGROUND:Hepatic veno-occlusive disease(VOD)or sinusoidal obstruction syndrome is associated with a high mortality because of its severity.Gymura segetum,a Chinese herbal medicine,is always used to cure injury and bleeding in rural areas in China.This study was undertaken to better understand VOD and its relations to the effect of Gymura segetum.METHODS:Between 2000 and 2002,two patients were admitted to our department because of VOD.Before admission,both of them had been injured and taken oral decoction of patent drug Gymura segetum.We analyzed the clinical manifestations,diagnosis and therapy of the two patients.RESULTS:Pyrrolizidine in Panax notginseng was proved to induce VOD.The diagnosis of VOD depended on hepatic biopsy.CONCLUSION:Gymura segetum can induce VOD.More attention should be paid to its unsuscepted side effects.展开更多
Based on the Industrial Source Complex Short-Term Version 3 (ISCST3) model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans (PCDD/F...Based on the Industrial Source Complex Short-Term Version 3 (ISCST3) model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans (PCDD/Fs) of agricultural soil, within a radius of 3 kin from a municipal solid waste incinerator (MSWI) plant after its 4-year operation in Hangzhou, China. Comparisons were made between the measured and estimated congener-specific concentrations and the international-toxic equivalent (I-TEQ) values of soil samples with respect to distance from the stack. The results indicate that the predictions of soil PCDD/F concentrations and K-TEQ values were generally lower than their observations, and that the higher the degree of underestimation seems, the greater the further downwind one gets. Nevertheless, most of the predictions were in good agreement with the trend of measured ones and were within a factor of ten for samples located within 1 kin of the plant. Besides, analysis of contributions of various deposition pathways confirms that in addition to wet particle deposition, the dry gaseous deposition is essential for realistic prediction of PCDD/F depositions to soil, especially for tetra- and penta-chlorinated dioxins.展开更多
基金the Natural Science Foundation of Zhejiang Province (No. X206955)Zhejiang Medical and Health Research Fund (No. 2007A047)the Education Bureau of Zhejiang Prov-ince (No. N20080181), China
文摘Polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) emissions in flue gas from two types of municipal solid waste incinerators (MSWIs) most commonly used in China were investigated in this study. The selected incinerators include two grate-type MSWIs: MSWI-A (350 t/d) and MSWI-B 050 t/d), and two fluidized bed MSWIs: MSWI-C (400 t/d) and MSWI-D (400 t/d), which are all equipped with semi-dry lime scrubber and bag filter except MSWI-D equipped with cyclone and wet scrubber (WS) as air pollutant control device (APCD). Results indicated that the emission concentration and the international toxic equivalents (I-TEQs) of the PCDD/Fs from the stacks were in the range of 1.210-10.273 ng/Nm^3 and 0.019-0.201 ng I-TEQ/Nm^3, respectively. They were greatly lower than the emission regulation standard of PCDD/Fs in China (1.0 ng I-TEQ/Nm^3). However, only the PCDD/Fs emission level from MSWI-C was below 0.1 ng I-TEQ/Nm^3. Although the homologue profiles were distinct, the contributions of the 2,3,7,8-subsituted congeners to the total I-TEQ were similar among all the investigated MSWIs. Two major 2,3,7,8-substituted congeners, 2,3,4,7,8-PeCDF and 1,2,3,7,8-PeCDD, account for 47% and 9% (average values) of the total I-TEQ values, respectively. The correlation between PCDD/Fs levels and composition of flue gas was also discussed.
文摘BACKGROUND:Hepatic veno-occlusive disease(VOD)or sinusoidal obstruction syndrome is associated with a high mortality because of its severity.Gymura segetum,a Chinese herbal medicine,is always used to cure injury and bleeding in rural areas in China.This study was undertaken to better understand VOD and its relations to the effect of Gymura segetum.METHODS:Between 2000 and 2002,two patients were admitted to our department because of VOD.Before admission,both of them had been injured and taken oral decoction of patent drug Gymura segetum.We analyzed the clinical manifestations,diagnosis and therapy of the two patients.RESULTS:Pyrrolizidine in Panax notginseng was proved to induce VOD.The diagnosis of VOD depended on hepatic biopsy.CONCLUSION:Gymura segetum can induce VOD.More attention should be paid to its unsuscepted side effects.
基金Project (Nos. X506312 and X206955) supported by the NaturalScience Foundation of Zhejiang Province, China
文摘Based on the Industrial Source Complex Short-Term Version 3 (ISCST3) model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans (PCDD/Fs) of agricultural soil, within a radius of 3 kin from a municipal solid waste incinerator (MSWI) plant after its 4-year operation in Hangzhou, China. Comparisons were made between the measured and estimated congener-specific concentrations and the international-toxic equivalent (I-TEQ) values of soil samples with respect to distance from the stack. The results indicate that the predictions of soil PCDD/F concentrations and K-TEQ values were generally lower than their observations, and that the higher the degree of underestimation seems, the greater the further downwind one gets. Nevertheless, most of the predictions were in good agreement with the trend of measured ones and were within a factor of ten for samples located within 1 kin of the plant. Besides, analysis of contributions of various deposition pathways confirms that in addition to wet particle deposition, the dry gaseous deposition is essential for realistic prediction of PCDD/F depositions to soil, especially for tetra- and penta-chlorinated dioxins.