Owing to the presence of large residual internal stress during cold compaction,it is difficult to optimize the multiple high-frequency magnetic properties of amorphous soft magnetic composites(ASMCs)simultaneously.Her...Owing to the presence of large residual internal stress during cold compaction,it is difficult to optimize the multiple high-frequency magnetic properties of amorphous soft magnetic composites(ASMCs)simultaneously.Here,a surface nanoengineering strategy was proposed to address the above dilemma by constructing a stress buffer layer composed of amorphous nano-particles,between amorphous powder and insulation coating.The amorphous FeSiBCCr@x wt.%FeB(x=0.5,1,3)composite powders with coreshell structures were successfully prepared via an in-situ chemical reduction method.Especially,when the composite ratio of nano-particles is 1 wt.%,the comprehensive properties of the ASMC reach the best balance.Compared with the FeSiBCCr ASMC,the saturation magnetization of the modified ASMC enhances from 153 to 171 emu/g.Meanwhile,the core loss decreases by 28.25%,while the effective permeability increases by 25% and can stabilize to∼20 MHz.Therefore,our work provides a strategy for achieving superior comprehensive soft magnetic properties of ASMCs via surface nanoengineering,which presents enormous application potential in high-frequency electric devices.展开更多
Despite the importance of temperature distribution in spark plasma sintering of metallic glasses,its quantification has been experimentally laborious.This work proposes an experimental strategy to determine the sinteri...Despite the importance of temperature distribution in spark plasma sintering of metallic glasses,its quantification has been experimentally laborious.This work proposes an experimental strategy to determine the sintering temperature by establishing a quantitative relationship between the temperature-thermal signal.We reproduced the thermal profiles of spark plasma sintering by isothermal annealing and found a correlation between annealing temperature and isothermal crystallization time.This strong correlation indicates the temperature-dependent structural evolution of glassy powders.Using isothermal crystallization time as the measuring gauge,we correlated the annealing temperature to the sintering temperature and obtained the sample temperature map.The sample temperature is at least 19C higher than the nominal temperature of 425C measured by the thermocouple.Meanwhile,the sample temperature shows a hump-shaped pattern closely correlated with the current density.The maximum temperature of 453C occurs on the sample/punches contact surfaces.Temperature heterogeneity within the sample induces diverse microstructures and porous structures.We elucidate that the temperature inhomogeneity is intrinsic,given the presence of contact interfaces.Contact resistances affect the current distribution and heat transfer,resulting in a larger temperature gradient than the traditional powder metallurgy process.展开更多
基金financially supported by Guangdong Major Project of Basic and Applied Basic Research,China(No.2019B030302010)the National Natural Science Foundation of China(Nos.52071222,52301212,52101191,52192601,52192602,52192603)+1 种基金the National Key Research and Development Program of China(No.2021YFA0716302)Dongguan Key Research and Development Projects(No.20221200300062).
文摘Owing to the presence of large residual internal stress during cold compaction,it is difficult to optimize the multiple high-frequency magnetic properties of amorphous soft magnetic composites(ASMCs)simultaneously.Here,a surface nanoengineering strategy was proposed to address the above dilemma by constructing a stress buffer layer composed of amorphous nano-particles,between amorphous powder and insulation coating.The amorphous FeSiBCCr@x wt.%FeB(x=0.5,1,3)composite powders with coreshell structures were successfully prepared via an in-situ chemical reduction method.Especially,when the composite ratio of nano-particles is 1 wt.%,the comprehensive properties of the ASMC reach the best balance.Compared with the FeSiBCCr ASMC,the saturation magnetization of the modified ASMC enhances from 153 to 171 emu/g.Meanwhile,the core loss decreases by 28.25%,while the effective permeability increases by 25% and can stabilize to∼20 MHz.Therefore,our work provides a strategy for achieving superior comprehensive soft magnetic properties of ASMCs via surface nanoengineering,which presents enormous application potential in high-frequency electric devices.
基金supported by the National Science Foundation for Distinguished Young Scholars of China(Grant No.51725504)State Key Lab of Advanced Metals and Materials(Grant No.2021-Z01)Knowledge Innovation Program of Wuhan-Basic Research,and the Fundamental Research Funds for the Central Universities,HUST(Grant No.2018KFYRCPT001).
文摘Despite the importance of temperature distribution in spark plasma sintering of metallic glasses,its quantification has been experimentally laborious.This work proposes an experimental strategy to determine the sintering temperature by establishing a quantitative relationship between the temperature-thermal signal.We reproduced the thermal profiles of spark plasma sintering by isothermal annealing and found a correlation between annealing temperature and isothermal crystallization time.This strong correlation indicates the temperature-dependent structural evolution of glassy powders.Using isothermal crystallization time as the measuring gauge,we correlated the annealing temperature to the sintering temperature and obtained the sample temperature map.The sample temperature is at least 19C higher than the nominal temperature of 425C measured by the thermocouple.Meanwhile,the sample temperature shows a hump-shaped pattern closely correlated with the current density.The maximum temperature of 453C occurs on the sample/punches contact surfaces.Temperature heterogeneity within the sample induces diverse microstructures and porous structures.We elucidate that the temperature inhomogeneity is intrinsic,given the presence of contact interfaces.Contact resistances affect the current distribution and heat transfer,resulting in a larger temperature gradient than the traditional powder metallurgy process.
