The South-to-North Water Diversion Project in China aims to address the imbalanced distribution of water resources between the northern and southern regions,a critical safeguard for sustainable socio-economic and ecol...The South-to-North Water Diversion Project in China aims to address the imbalanced distribution of water resources between the northern and southern regions,a critical safeguard for sustainable socio-economic and ecological development.In this study,we investigated the hydroclimatic evolution of the water source area and its driving mechanisms using the inflow runoff data at Danjiangkou Reservoir from 1954 to 2013,along with multiple gridded hydroclimatic datasets.Based on the correlations between instrumental runoff data and gridded hydroclimatic variables,we used linear regression to extend the long-term runoff record to the period of 1902-2019.Our results indicate that climate changes,dominated by regional wet-dry cycles,have significant impacts on runoff variations,while the influence of human activities remains comparatively limited.Danjiangkou Reservoir can maintain a balanced base flow,even during the operation of the water diversion project.Preliminary synoptic climatology analyses reveal that runoff variations are mainly driven by the El Niño-Southern Oscillation(ENSO)and the Pacific Walker Circulation(PWC),which affect runoff by altering large-scale ocean-to-continent water vapor processes.This study advances the field by integrating multi-source data with analytical techniques,which enhances understanding of long-term runoff changes in the Danjiangkou Reservoir and their climatic drivers,ultimately supporting sustainable water resource management.展开更多
Pitch is an excellent precursor for the production of hard carbon,with pre-oxidation crucial process in the fabrication.The structural changes in the different molecular components of pitch during thermochemical treat...Pitch is an excellent precursor for the production of hard carbon,with pre-oxidation crucial process in the fabrication.The structural changes in the different molecular components of pitch during thermochemical treatment are a key factor in determining the sodium-ion storage of pitchbased hard carbon anodes.We investigated the effects of the different molecular structures in the asphaltene precursor,including aromatic rings and aliphatic chains,on the sodiumion storage behavior of the resulting carbon.We found that polar oxygen functional groups limit the steric hindrance caused by the aromatic rings in pitch,and thus facilitate the introduction of cross-linked structures.During high-temperature carbonization,aromatic rings form a rigid carbon framework that prevents the rearrangement of ordered carbon layers,leading to a short-range disordered carbon structure and promotes the production of closed pores.For example,a material prepared from asphaltene,which contains a large number of oxygen-containing functional groups and macromolecular aromatic rings,using pre-oxidation at 300℃ and carbonization at 1200℃ had a reversible capacity of 316.7 mAh g^(−1) when used as the anode for sodium ion batteries.Our research provides a theoretical basis for the selection of raw materials for the development of high-quality pitch-based hard carbons.展开更多
基金supported by the National Natural Science Foundation of China(NSFC Project No.32061123008)the Innovation Training Programme for Undergraduate Students of Yunnan University(Project No.202301051).
文摘The South-to-North Water Diversion Project in China aims to address the imbalanced distribution of water resources between the northern and southern regions,a critical safeguard for sustainable socio-economic and ecological development.In this study,we investigated the hydroclimatic evolution of the water source area and its driving mechanisms using the inflow runoff data at Danjiangkou Reservoir from 1954 to 2013,along with multiple gridded hydroclimatic datasets.Based on the correlations between instrumental runoff data and gridded hydroclimatic variables,we used linear regression to extend the long-term runoff record to the period of 1902-2019.Our results indicate that climate changes,dominated by regional wet-dry cycles,have significant impacts on runoff variations,while the influence of human activities remains comparatively limited.Danjiangkou Reservoir can maintain a balanced base flow,even during the operation of the water diversion project.Preliminary synoptic climatology analyses reveal that runoff variations are mainly driven by the El Niño-Southern Oscillation(ENSO)and the Pacific Walker Circulation(PWC),which affect runoff by altering large-scale ocean-to-continent water vapor processes.This study advances the field by integrating multi-source data with analytical techniques,which enhances understanding of long-term runoff changes in the Danjiangkou Reservoir and their climatic drivers,ultimately supporting sustainable water resource management.
文摘Pitch is an excellent precursor for the production of hard carbon,with pre-oxidation crucial process in the fabrication.The structural changes in the different molecular components of pitch during thermochemical treatment are a key factor in determining the sodium-ion storage of pitchbased hard carbon anodes.We investigated the effects of the different molecular structures in the asphaltene precursor,including aromatic rings and aliphatic chains,on the sodiumion storage behavior of the resulting carbon.We found that polar oxygen functional groups limit the steric hindrance caused by the aromatic rings in pitch,and thus facilitate the introduction of cross-linked structures.During high-temperature carbonization,aromatic rings form a rigid carbon framework that prevents the rearrangement of ordered carbon layers,leading to a short-range disordered carbon structure and promotes the production of closed pores.For example,a material prepared from asphaltene,which contains a large number of oxygen-containing functional groups and macromolecular aromatic rings,using pre-oxidation at 300℃ and carbonization at 1200℃ had a reversible capacity of 316.7 mAh g^(−1) when used as the anode for sodium ion batteries.Our research provides a theoretical basis for the selection of raw materials for the development of high-quality pitch-based hard carbons.
文摘将无人机与频谱共享技术相结合,可建立高质量通信链路,提高频谱资源利用效率。然而,由于主、次用户间交叉链路干扰的存在,实现次用户的高可达速率变得十分困难。为了解决该问题,设计了一种智能反射面(Intelligent Reflective Surface,IRS)辅助的无人机认知中继通信网络。通过联合优化无人机的位置部署、次基站的波束成形和IRS的相移矩阵,最大化频谱共享网络中次用户的加权和速率(Weighted Sum Rate,WSR)。为了解决所建立的非凸问题,将其解耦为3个子问题,然后提出了一种交替优化算法来迭代优化变量。利用连续凸逼近(Successive Convex Approxi‑mation,SCA)法对无人机的位置进行优化;利用直接分式规划(Dire ct Fractional Programming,DFP)法对次基站的波束成形进行优化;利用DFP结合交替方向乘子法(Alternating Direction Method of Multipliers,ADMM)对IRS的相移矩阵进行优化。仿真结果表明,与基准算法相比,所提算法能实现更高的次用户WSR。
