Organic materials are emerging candidates for lithium-ion batteries.Unfortunately,limited electrical conductivity and high solubility in organic electrolytes usually cause low capacity and short cycle life,which hinde...Organic materials are emerging candidates for lithium-ion batteries.Unfortunately,limited electrical conductivity and high solubility in organic electrolytes usually cause low capacity and short cycle life,which hinder the utilization of organic materials.Herein,a novel multi-carbonyl naphthalene diimide non-conjugated polymer(NDI-BU)has been readily synthesized through one-step reaction.The designed polymer structure of NDI-BU shows a long and flat discharge platform.The abundant carbonyls provide multiple reaction sites for lithium ions,and resulting in a high specific capacity of 308 mAh·g-1 at 0.2C.An incredibly long cycle life of 20,000 cycles at 5C with 82%capacity retention is achieved.This work may inspire the effective design strategy for high energy density organic cathode materials.展开更多
In this paper,we report the design,synthesis and semiconducting behavior of two conjugated D-A polymers BPDDTE and BPDBDTE which entail BPD,a Pechmann dye framework,as electron accepting moieties and(E)-1,2-di(thiophe...In this paper,we report the design,synthesis and semiconducting behavior of two conjugated D-A polymers BPDDTE and BPDBDTE which entail BPD,a Pechmann dye framework,as electron accepting moieties and(E)-1,2-di(thiophen-2-yl)ethane with and without alkyl chains as electron donating moieties.They both show very narrow bandgaps below 1.3 eV.Based on the characterization of the field-effect transistors,thin film of BPDDT exhibits ambipolar semiconducting properties with hole and electron mobilities reaching 0.245 and 0.095 cm^(2)•V^(−1)•s^(−1),respectively,after thermal annealing.Similarly,BPDBDTE with more alkylchains shows ambipolar semiconducting behavior with hole mobility and electron mobilities reaching 0.109 and 0.081 cm^(2)•V^(−1)•s^(−1).Furthermore,BPDBDTE shows good solubilities in several common organic solvents and thus is easily solution-processible.Thus,BPDBDTE is potentially processible with inkjet printing and roll-to-roll printing techniques.展开更多
基金support from the National Natural Science Foundation of China(Nos.22075255,22375080,and 22175081)Co-working Space Incubation Project of Zhengzhou University of Light Industry(No.2021ZCKJ209)+3 种基金Science and Technology Project of Henan Province(No.242102240007)Key Scientific Research Project of Henan Province(No.25A530007)the Education Department of Henan Province(No.242300420206)the Science and Technology Major Program of Gansu Province of China(Nos.22ZD6FA006,23ZDFA015,and 24ZD13FA017).
文摘Organic materials are emerging candidates for lithium-ion batteries.Unfortunately,limited electrical conductivity and high solubility in organic electrolytes usually cause low capacity and short cycle life,which hinder the utilization of organic materials.Herein,a novel multi-carbonyl naphthalene diimide non-conjugated polymer(NDI-BU)has been readily synthesized through one-step reaction.The designed polymer structure of NDI-BU shows a long and flat discharge platform.The abundant carbonyls provide multiple reaction sites for lithium ions,and resulting in a high specific capacity of 308 mAh·g-1 at 0.2C.An incredibly long cycle life of 20,000 cycles at 5C with 82%capacity retention is achieved.This work may inspire the effective design strategy for high energy density organic cathode materials.
基金The present research was financially supported by Chinese Academy of Sciences,NSFC(No.21372226)and State Key Basic Research Program.
文摘In this paper,we report the design,synthesis and semiconducting behavior of two conjugated D-A polymers BPDDTE and BPDBDTE which entail BPD,a Pechmann dye framework,as electron accepting moieties and(E)-1,2-di(thiophen-2-yl)ethane with and without alkyl chains as electron donating moieties.They both show very narrow bandgaps below 1.3 eV.Based on the characterization of the field-effect transistors,thin film of BPDDT exhibits ambipolar semiconducting properties with hole and electron mobilities reaching 0.245 and 0.095 cm^(2)•V^(−1)•s^(−1),respectively,after thermal annealing.Similarly,BPDBDTE with more alkylchains shows ambipolar semiconducting behavior with hole mobility and electron mobilities reaching 0.109 and 0.081 cm^(2)•V^(−1)•s^(−1).Furthermore,BPDBDTE shows good solubilities in several common organic solvents and thus is easily solution-processible.Thus,BPDBDTE is potentially processible with inkjet printing and roll-to-roll printing techniques.
