This review provides a comprehensive summary of biomass-based adsorption,with a particular focus on biochar as an innovative,sustainable,and eco-friendly technique for recovering rare earth elements(REEs) from various...This review provides a comprehensive summary of biomass-based adsorption,with a particular focus on biochar as an innovative,sustainable,and eco-friendly technique for recovering rare earth elements(REEs) from various sources.This study details primary adsorption mechanisms,including physical adsorption,ion exchange,electrostatic attraction,surface complexation,and precipitation,providing a nuanced understanding of how these processes contribute to metal recovery.Additionally,it discusses various biochar modification methods aimed at enhancing surface functionalities,thereby improving adsorption capacity and selectivity.It further addresses the critical challenge of biochar regeneration,outlining methods such as thermal,solvent,microwave irradiation,and supercritical fluid regeneration to sustain biochar's efficacy over multiple cycles.Overall,this comprehensive analysis highlights biochar's versatility and potential in environmental remediation and resource recovery,emphasizing the importance of optimized regeneration techniques to maintain its adsorption efficiency and future research directions for large-scale applications.展开更多
文摘This review provides a comprehensive summary of biomass-based adsorption,with a particular focus on biochar as an innovative,sustainable,and eco-friendly technique for recovering rare earth elements(REEs) from various sources.This study details primary adsorption mechanisms,including physical adsorption,ion exchange,electrostatic attraction,surface complexation,and precipitation,providing a nuanced understanding of how these processes contribute to metal recovery.Additionally,it discusses various biochar modification methods aimed at enhancing surface functionalities,thereby improving adsorption capacity and selectivity.It further addresses the critical challenge of biochar regeneration,outlining methods such as thermal,solvent,microwave irradiation,and supercritical fluid regeneration to sustain biochar's efficacy over multiple cycles.Overall,this comprehensive analysis highlights biochar's versatility and potential in environmental remediation and resource recovery,emphasizing the importance of optimized regeneration techniques to maintain its adsorption efficiency and future research directions for large-scale applications.
